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CORDIS - Résultats de la recherche de l’UE
CORDIS

Graphene, MXene and ionic liquid-based sustainable supercapacitor

CORDIS fournit des liens vers les livrables publics et les publications des projets HORIZON.

Les liens vers les livrables et les publications des projets du 7e PC, ainsi que les liens vers certains types de résultats spécifiques tels que les jeux de données et les logiciels, sont récupérés dynamiquement sur OpenAIRE .

Livrables

Electrodes for high-energy density SCs (s’ouvre dans une nouvelle fenêtre)

Report on the developed electrodes based on graphene- and MXene-based materials with gravimetric capacitance >200 F/g and volumetric capacitance >150 F/cm3. [T3.2]

Quality control for CRM-free SC materials (s’ouvre dans une nouvelle fenêtre)

The report describes the protocols and specifications for quality control assessment and reproducibility assurance of the SC materials. For the quality control of graphene-based SC materials, the ISO TS 21356-1 is followed. The report also describes the specifications and quality control procedures defined to ensure the material uniformity and reproducibility assurance for the case of MXene and ILs. [T1.4]

Quality Assurance Report (s’ouvre dans une nouvelle fenêtre)

Report identifying quality indicators of the deliverables, internal reviewers, review criteria for each deliverable, and the approval procedure defined to ensure the quality of all technical deliverables and reports. [T7.3]

Hybrids and functionalized EMs characterization (s’ouvre dans une nouvelle fenêtre)

Report on the characterization of hybrid and functionalized EMs, which includes their compositional characterization (XPS), structural/morphological characterizations (AFM, SEM, HRTEM; GIXD), gas physisorption (BET) measurements, spectroscopic characterizations (FTIR, Raman, UV/visible and fluorescence spectroscopy, PES), electrical and other physical characterizations (c-AFM, KPFM, macroscopic Kelvin probe, UPS). [T2.3 and T2.3]

Slurry formulations for high-energy SCs (s’ouvre dans une nouvelle fenêtre)

Report on the formulation and processing of EM pastes/slurries. The report describes the efforts carried out to define the best combination of active materials and additives pastes/slurries, guaranteeing the required electrical sheet resistance < 100Ω/□, SSA (> 2000 m2/g) and processability through printing deposition techniques. [T3.1]

Novel CRM-free EMs and IL-based electrolytes for SCs (s’ouvre dans une nouvelle fenêtre)

Report on the synthesis and characterization of EMs, based on CRM-free graphene-based materials and MXenes), and sustainable IL-based electrolytes . The report describes the morphological/structural and chemical properties SLG/FLG produced through WJM, HPH and electrochemical exfoliation methods using synthetic graphite and replacing toxic and hazardous exfoliating solvents/electrolytes (e.g., NMP) with environmentally friendly alternatives. The report also describes the characteristics of the curved graphene produced using SiC as the precursor material and exploiting a proprietary fluidized bed reactor technology. The report also contains the results obtained by the systematic study on MXenes by varying the elemental composition of the raw MAX phase, starting from Ti- (SOTA and reference materials) and Mo-based MAX phases, but going beyond as the project progresses (exploring Mn and Zr-based phases). [T1.1 and T1.2]

Updated quality control for CRM-free SC materials (s’ouvre dans une nouvelle fenêtre)

Update of D1.1. This document describes the basic information used to define material certification strategies. [T1.4]

Ex-ante environmental and socio-economic impact assessment (s’ouvre dans une nouvelle fenêtre)

Report on the ex-ante assessment of the environmental and socio-economic impacts of the materials and technologies developed, based mainly on expert interviews with the GREENCAP consortium partners. [T5.2 and T5.3]

Multiscale characterization of EMs and electrolytes (s’ouvre dans une nouvelle fenêtre)

Report on advanced multiscale physicochemical and electrochemical characterization of EMs and electrolytes . It describes their compositional, structural/morphological, and (electro)chemical properties relevant for their subsequent application as SC materials. [T1.2]

Electrochemical characterization of electrode/electrolyte interfaces (s’ouvre dans une nouvelle fenêtre)

Report describing the main achievement obtained by the consortium on the electrochemical characterization of electrode/electrolyte interfaces, including advanced in-situ analyses (Raman spectroscopy and TGA measurements). [T2.4]

Industrial chain manufacturing (s’ouvre dans une nouvelle fenêtre)

Preliminary report describing the requirements and necessary actions needed to establish the industrial chain manufacturing of the SCs. The report illustrates the integration of the industrial production of both electrode materials (powders and inks/pastes) and IL-based electrolytes over an industrial SC manufacturing line for cylindrical cells. The protocols established for the production and transport of the materials among the partners is described. In addition, the report assesses the costs related to the industrial manufacturing chain, identifying the most convenient processes for its refining. [T4.2]

Upscaling processes and standardization (s’ouvre dans une nouvelle fenêtre)

Preliminary report on the upscaling and standardization processes for SC materials. The document describes the implementation adopted to reach industrial production rates both for powder (>103 kg/year for SLG/FLG and ~105 kg/year for curved graphene, and ~1 kg/day for MXene) and inks/pastes (>2×103 kg/year). The report also summarizes the established metrics and path of standardization for the quality control of the developed materials and electrodes. [T4.1]

Updated Upscaling processes and standardization (s’ouvre dans une nouvelle fenêtre)

Update of D4.1, describing the upscaling and standardization processes for SC materials. [T4.1]

Risk Management Plan (s’ouvre dans une nouvelle fenêtre)

Plan for project quality and risk management. The report describes contingency plans and risk management protocols including an extended and complete risk analysis. [T7.3]

Ex-post environmental and socio-economic impact assessment (s’ouvre dans une nouvelle fenêtre)

Report on the ex-post assessment of the environmental and socio-economic impacts of the materials and technologies developed, based on a comprehensive expert interview survey across the GREENCAP production value chain. [T5.2 and 5.3]

Functionalization of SC materials (s’ouvre dans une nouvelle fenêtre)

Report on the chemical functionalization strategies pursued for CRM-free graphene-based materials and MXenes. The report contains the outcomes and the optimization paths of both non-covalent and covalent approaches, and the resulting degree of functionalization and methods’ robustness. [T2.1]

Final benchmarking report (s’ouvre dans une nouvelle fenêtre)

Report on the benchmarking of the developed SC technology compared in terms of performance and sustainability. A cost calculation is added to the report with a time horizon (5-10 years after the project) [T5.1]

Updated Industrial chain manufacturing (s’ouvre dans une nouvelle fenêtre)

Update of D4.2, describing the requirements and necessary actions needed to establish the industrial chain manufacturing of the SCs. [T4.2]

Pouch cells (s’ouvre dans une nouvelle fenêtre)

Report on pouch cell demonstrators with an energy density of >20 Wh/kg or >16 Wh/L. The report describes both the manufacturing processes and the electrochemical results, summarizing SC specifications. [T3.3]

Cylindrical prototype cells (s’ouvre dans une nouvelle fenêtre)

Preliminary report on the fabrication and testing of 1-2 cylindrical prototype cells with double-sided coated electrodes based on the newly developed SC materials. The initial tests are based on industrial standards and encompass aging by cycling tests, aging by near operational cycling tests and initial calendar life tests. [T4.3]

Updated Cylindrical prototype cells (s’ouvre dans une nouvelle fenêtre)

Update of D4.3, describing the fabrication and testing of 1-2 cylindrical prototype cells with double-sided coated electrodes based on the newly developed SC materials. [T4.3]

Communication toolbox (s’ouvre dans une nouvelle fenêtre)

Project website, logo, project templates, newsletter, and database for dissemination, all designed in line with the content identity, based on the project key messages. [T6.1]

Data Management Plan (s’ouvre dans une nouvelle fenêtre)

Plan for project quality and risk management. The report describes contingency plans and risk management protocols including an extended and complete risk analysis. [T7.4]

Publications

Surface Engineering of Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXenes via Silanol Functionalization for Improved Electrochemical Performance (s’ouvre dans une nouvelle fenêtre)

Auteurs: Abelardo Sánchez‐Oliva, Verónica Montes‐García, Ke Li, Kaitlyn Prenger, Xuyun Guo, Iwona Janica, Wojciech Kukułka, Adrián Tamayo, Pilar Prieto, Paolo Samorì, Valeria Nicolosi, Artur Ciesielski
Publié dans: Small, 2025, ISSN 1613-6810
Éditeur: Wiley
DOI: 10.1002/SMLL.202507744

Advanced Energy Materials (s’ouvre dans une nouvelle fenêtre)

Auteurs: Davood Sabaghi; Josef Polčák; Hyejung Yang; Xiaodong Li; Ahiud Morag; Dongqi Li; Ali Shaygan Nia; Saman Khosravi H; Tomáš Šikola; Xinliang Feng; Minghao Yu
Publié dans: Advanced energy materials 14(3), 2302961 (2023). doi:10.1002/aenm.202302961, 2023, ISSN 1614-6832
Éditeur: Wiley-VCH Verlag
DOI: 10.3204/pubdb-2024-00267

Triphasic synthesis of MXenes with uniform and controlled halogen terminations (s’ouvre dans une nouvelle fenêtre)

Auteurs: Dongqi Li, Wenhao Zheng, Mahdi Ghorbani-Asl, Juliane Scheiter, Kamil Sobczak, Silvan Kretschmer, Josef Polčák, Pranjali Hirasing Jadhao, Paweł P. Michałowski, Ruoling Yu, Jiaxu Zhang, Jinxin Liu, Jingwei Du, Quanquan Guo, Ehrenfried Zschech, Tomáš Šikola, Mischa Bonn, Nicolás Pérez, Kornelius Nielsch, Arkady V. Krasheninnikov, Hai I. Wang, Minghao Yu, Xinliang Feng
Publié dans: Nature Synthesis, 2026, ISSN 2731-0582
Éditeur: Springer Science and Business Media LLC
DOI: 10.1038/S44160-025-00970-W

Exotic Photothermal Response in Ti-Based MXene Optoelectronic Devices (s’ouvre dans une nouvelle fenêtre)

Auteurs: Stefano Ippolito, Francesca Urban, Paolo Samorì, Jonathan E. Spanier, Yury Gogotsi
Publié dans: Advanced Electronic Materials, Numéro 11, 13, 2500017, 2025, ISSN 2199-160X
Éditeur: Wiley-VCH
DOI: 10.1002/AELM.202500017

Electrochemical performance of electrochemical double layer capacitors containing pyrrolidinium and ammonium fluorosulfonyl imide in acetonitrile-based electrolytes (s’ouvre dans une nouvelle fenêtre)

Auteurs: Indrajit Mahadev Patil, Tobias Burton, Alix Ladam, Sebastien Fantini, Andrea Balducci
Publié dans: Electrochimica Acta, Numéro 525, 2025, ISSN 0013-4686
Éditeur: Elsevier BV
DOI: 10.1016/J.ELECTACTA.2025.146133

Water-based Supercapacitors with Amino Acid Electrolytes: A Green Perspective for Capacitance Enhancement (s’ouvre dans une nouvelle fenêtre)

Auteurs: Dr. Alessio D'Alessandro, Dr. Sebastiano Bellani, Agnese Gamberini, Dr. Valentina Mastronardi, Dr. Marilena Isabella Zappia, Matteo Abruzzese, Dr. Sanjay Thorat, Elena Calcagno, Dr. Francesco Bonaccorso
Publié dans: Batteries and supercaps, 2023, ISSN 2566-6223
Éditeur: Wiley
DOI: 10.1002/batt.202300458

Hydrogen-Assisted Thermal Treatment of Electrode Materials for Electrochemical Double-Layer Capacitors (s’ouvre dans une nouvelle fenêtre)

Auteurs: Matteo Gentile, Sebastiano Bellani*, Marilena I. Zappia, Agnese Gamberini, Valentina Mastronardi, Matteo Abruzzese, Luca Gabatel, Lea Pasquale, Sergio Marras, Ahmad Bagheri, Hossein Beydaghi, Evie L. Papadopoulou, Guglielmo Lanzani, and Francesco Bonaccor
Publié dans: ACS Appl. Mater. Interfaces, Numéro 16, 2024, ISSN 1944-8244
Éditeur: American Chemical Society
DOI: 10.1021/acsami.3c18629

A comparative study on cytotoxicity of different types of commercial single- and few-layer graphenes on human monocytes and macrophages (s’ouvre dans une nouvelle fenêtre)

Auteurs: Zhengmei Song, Luna Boulbet-Friedelmeyer, Marvin Motay, Antonio Esau del Rio Castillo, Housseinou Ba, Rym Soltani, Carlos Drummond, Yannick Lafue, Alain Penicaud, Francesco Bonaccorso, Alberto Bianco
Publié dans: Carbon, Numéro 244, 2025, ISSN 0008-6223
Éditeur: Elsevier BV
DOI: 10.1016/J.CARBON.2025.120685

MXenes with ordered triatomic-layer borate polyanion terminations (s’ouvre dans une nouvelle fenêtre)

Auteurs: Dongqi Li, Wenhao Zheng, Sai Manoj Gali, Kamil Sobczak, Michal Horák, Josef Polčák, Nikolaj Lopatik, Zichao Li, Jiaxu Zhang, Davood Sabaghi, Shengqiang Zhou, Paweł P. Michałowski, Ehrenfried Zschech, Eike Brunner, Mikołaj Donten, Tomáš Šikola, Mischa Bonn
Publié dans: Nature Materials, Numéro 23, 2024, ISSN 1476-1122
Éditeur: Nature Publishing Group
DOI: 10.1038/s41563-024-01911-2

Covalent Organic Frameworks and 2D Materials Hybrids: Synthesis Strategies, Properties Enhancements, and Future Directions (s’ouvre dans une nouvelle fenêtre)

Auteurs: Cataldo Valentini, Verónica Montes-García, Dawid Pakulski, Paolo Samorì, Artur Ciesielski
Publié dans: Small, Numéro 21, 8, 2410544, 2025, ISSN 1613-6810
Éditeur: Wiley-VCH
DOI: 10.1002/SMLL.202410544

Influence of Disorder on the Electronic Properties and Magnetotransport of Ti <sub>3</sub> C <sub>2</sub> T <sub> <i>x</i> </sub> Single-Flake Devices (s’ouvre dans une nouvelle fenêtre)

Auteurs: Francesca Urban, Stefano Ippolito, Jane Frostad, José D. Gouveia, José R. B. Gomes, Paweł P. Michałowski, Steven J. May, Paolo Samorì, Yury Gogotsi
Publié dans: ACS Applied Electronic Materials, Numéro 8, 2026, ISSN 2637-6113
Éditeur: American Chemical Society (ACS)
DOI: 10.1021/ACSAELM.5C01847

Dressing AgNWs with MXenes Nanosheets: Transparent Printed Electrodes Combining High-Conductivity and Tunable Work Function for High-Performance Opto-Electronics (s’ouvre dans une nouvelle fenêtre)

Auteurs: Zhongshi Ju, Yusheng Chen, Peng Li, Jiangang Ma, Haiyang Xu, Yichun Liu, Paolo Samorì
Publié dans: Advanced Materials, Numéro 36, 48, 2412512, 2024, ISSN 0935-9648
Éditeur: Wiley-VCH
DOI: 10.1002/ADMA.202412512

Covalent organic framework-based Li–S batteries: functional separators promoting Li+ transport and polysulfide trapping (s’ouvre dans une nouvelle fenêtre)

Auteurs: Sara Gullace, Matteo Abruzzese, Luca Cusin, Gabriele Saleh, Sanjay B. Thorat, Agnese Gamberini, Sebastiano Bellani, Artur Ciesielski, Francesco Bonaccorso, Paolo Samorì
Publié dans: Journal of Materials Chemistry A, Numéro 12, 37, 25359-25370, 2024, ISSN 2050-7496
Éditeur: Royal Society of Chemistry
DOI: 10.1039/D4TA03930K

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