Developing New 2D Materials and Heterostructures for Printed Digital Devices

Project Information

2D-PRINTABLE

Grant agreement ID: 101135196

DOI

10.3030/101135196

EC signature date 30 October 2023

Start date 1 October 2023

End date 30 September 2026

Funded under

• Digital, Industry and Space

Total cost

€ 4 092 496,25

EU contribution

€ 3 999 996,00

Coordinated by

THE PROVOST, FELLOWS, FOUNDATION SCHOLARS & THE OTHER MEMBERS OF BOARD, OF THE COLLEGE OF THE HOLY & UNDIVIDED TRINITY OF QUEEN ELIZABETH NEAR DUBLIN
Ireland

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Deliverables

Documents, reports (10)

Tuneable functionalization of TMDs

Via defect chemistry (e.g., with thiols or diazonium salts) and with metallic nanoparticles

Characterization of nanosheets, networks and heterostacks built from initially available 2D materials

Combination of SEM, AFM, FIB-SEM and various spectroscopies

Synthesis of bulk materials

Done in closed quartz ampoules and CVT

Electrical characterization of LPE derived novel materials

Vertical and horizontal, 2-, 3- or 4-terminal devices: extraction of µFET, Ion/Ioff, VT, SS

Characterization of new materials identified through theory

Using various standardized characterization methods, e.g., Raman, UV-vis-IR spectroscopies, AFM/TEM microscopies

Functionalization of 2D materials beyond TMDs

Use of strong electrophiles (e.g., diazoniums salts, halides, amines and maleimides) or nucleophiles (e.g., hydroxyls, amines)

Formation of discrete assemblies of 2DMs

Use of bi- or multidentate molecular linkers to form heterostructures

Ink production/printing

Controlled rheological properties

Cross-linking forming networks and heterostructures

Use of bi- or multidentate molecular linkers

Theory-identified novel 2D materials

Van der Waals DFT screening

Websites, patent fillings, videos etc. (1)

Project’s corporate identity

Communication toolbox, incl. project website, templates, newsletter, and diss. database

Data sets, microdata, etc (2)

Database on available materials

Including bulk materials, LPE/EE/CE nanosheets and their specifications (quantity, dimensions, defectiveness)

Band gaps of monolayers and multilayers

Direct/indirect band gaps computed for semiconducting monolayers and multilayers

Demonstrators, pilots, prototypes (1)

Beyond-state-of-the-art all-nanosheet TFTs

Optimization of all interfaces and components to maximize charge injection and transport. Quantification of µFET, Ion/Ioff, VT, SS

Publications

Peer reviewed articles (36)

Low-Temperature Electron Spin Resonance Study of MnPS₃ Antiferromagnetic Single Crystal

Author(s): Moro, Fabrizio; Wu, Bing; Plutnarová, Iva; Plutnar, Jan; Sofer, Zdenek
Published in: The Journal of Physical Chemistry C, 2024, ISSN 1932-7455
Publisher: American Chemical Society (ACS)
DOI: 10.1021/ACS.JPCC.4C06156

Synthesis of Xenes: physical and chemical methods

Author(s): Molle, Alessandro; Junji, Yuhara; Yukiko, Yamada-Takamura; Sofer, Zd
Published in: Chemical Society Reviews, 2025, ISSN 1460-4744
Publisher: Royal Society of Chemistry
DOI: 10.5281/ZENODO.14760360

Alkaline electrochemical deposition of Pt for alkaline electrolyzers

Author(s): Valentina Mastronardi a , Agnese Gamberini a , Marilena Isabella Zappia a , Yong Zuo b c , Matteo Abruzzese a , Ahmad Bagheri a , Hossein Beydaghi a , Luca Gabatel a d , Sanjay Thorat a , Michele Ferri b , Filippo Drago b , Lea Pasquale e , Li
Published in: International Journal of Hydrogen Energy, 2024, ISSN 1879-3487
Publisher: Elsevier Ltd
DOI: 10.1016/J.IJHYDENE.2024.07.086

Liquid-Phase Exfoliation of Arsenic Trisulfide (As2S3) Nanosheets and Their Use as Anodes in Potassium-Ion Batteries

Author(s): KAUR, HARNEET
Published in: ACS nano, 2024, ISSN 1936-086X
Publisher: American Chemical Society (ACS)
DOI: 10.1021/ACSNANO.4C03501

Ionogel-Based Electrodes for Non-Flammable High-Temperature Operating Electrochemical Double-Layer Capacitors

Author(s): Agnese Gamberini, Tobias Burton, Alix Ladam, Ahmad Bagheri, Matteo Abruzzese, Hossein Beydaghi, Valentina Mastronardi, Elena Calcagno, Samaneh Vaez, Alberto Morenghi, Teresa Gatti, Anais Falgayrat, Francesco Bonaccorso, Sebastien Fantini, Sebastiano Bella
Published in: ChemSusChem, 2025, ISSN 1864-564X
Publisher: Wiley-VCH
DOI: 10.1002/CSSC.202401874

Defect-engineering of liquid-phase exfoliated 2D semiconductors: stepwise covalent growth of electronic lateral hetero-networks

Author(s): Antonio Gaetano Ricciardulli, Christopher E. Petoukhoff, Anna Zhuravlova, Adam G. Kelly, Chun Ma, Frédéric Laquai, Jonathan N. Coleman, Paolo Samorì
Published in: Materials Horizons, Issue 11, 22, 5614-5621, 2024, ISSN 2051-6355
Publisher: Royal Society of Chemistry
DOI: 10.1039/D4MH00882K

Molecular Connectors Boosting the Performance of MoS2 Cathodes in Zinc-Ion Batteries

Author(s): Haipeng Guo, Verónica Montes-García, Haijun Peng, Paolo Samorì, Artur Ciesielski
Published in: Small, Issue 20, 29, 2310338, 2024, ISSN 1613-6810
Publisher: Wiley-VCH
DOI: 10.1002/SMLL.202310338

Covalent Organic Frameworks and 2D Materials Hybrids: Synthesis Strategies, Properties Enhancements, and Future Directions

Author(s): Cataldo Valentini, Verónica Montes-García, Dawid Pakulski, Paolo Samorì, Artur Ciesielski
Published in: Small, Issue 21, 8, 2410544, 2025, ISSN 1613-6810
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/SMLL.202410544

Piezoresistive Platinum Diselenide Pressure Sensors with Reliable High Sensitivity and Their Integration into Complementary Metal-Oxide-Semiconductor Circuits

Author(s): Sebastian LukasNico RademacherSofía CrucesMichael GrossEva DesguéStefan HeisererNikolas DominikMaximilian PrechtlOliver HartwigCormac Ó CoileáinTanja Stimpel-LindnerPierre LegagneuxArto RantalaJuha-Matti SaariMiika SoikkeliGeorg S. DuesbergMax C. Lemme
Published in: ACS nano, 2025, ISSN 1936-086X
Publisher: American Chemical Society
DOI: 10.1021/ACSNANO.4C15098

Dopant-Free Spiro-OMe2 Imidazole-Based Hole-Transporting Material for Stable and Low-Cost Organic–Inorganic Perovskite Solar Cell

Author(s): Haji-khan Mirzaei, L., Shahroosvand, H., Farokhi, A., Bayat, E., Bellani, S., Anichini, C., Ameri, M., & Bonaccorso, F
Published in: ACS Omega, 2024, ISSN 2470-1343
Publisher: American Chemical Society
DOI: 10.1021/ACSOMEGA.4C05440

High-κ Wide-Gap Layered Dielectric for Two-Dimensional van der Waals Heterostructures

Author(s): Sofer, Zdenek
Published in: ACS Nano, 2024, ISSN 1936-086X
Publisher: American Chemical Society (ACS)
DOI: 10.1021/ACSNANO.3C10411

Orientation Dependent Interlayer Coupling in Organic–Inorganic Heterostructures

Author(s): al, StCian Bartlam, Nihit Saigefan Heiserer, Hendrik Lambers, Ursula Wurstbauer, Georg S. Duesberg
Published in: Advanced Functional Materials, 2024, ISSN 1616-3028
Publisher: Wiley
DOI: 10.1002/ADFM.202315302

Covalent organic framework-based Li–S batteries: functional separators promoting Li+ transport and polysulfide trapping

Author(s): Sara Gullace, Matteo Abruzzese, Luca Cusin, Gabriele Saleh, Sanjay B. Thorat, Agnese Gamberini, Sebastiano Bellani, Artur Ciesielski, Francesco Bonaccorso, Paolo Samorì
Published in: Journal of Materials Chemistry A, Issue 12, 37, 25359-25370, 2024, ISSN 2050-7496
Publisher: Royal Society of Chemistry
DOI: 10.1039/D4TA03930K

Dressing AgNWs with MXenes Nanosheets: Transparent Printed Electrodes Combining High-Conductivity and Tunable Work Function for High-Performance Opto-Electronics

Author(s): Zhongshi Ju, Yusheng Chen, Peng Li, Jiangang Ma, Haiyang Xu, Yichun Liu, Paolo Samorì
Published in: Advanced Materials, Issue 36, 48, 2412512, 2024, ISSN 0935-9648
Publisher: Wiley-VCH
DOI: 10.1002/ADMA.202412512

How Biorecognition Affects the Electronic Properties of Reduced Graphene Oxide in Electrolyte-Gated Transistor Immunosensors

Author(s): Matteo Sensi, Rafael Furlan de Oliveira, Marcello Berto, Alessandro Paradisi, Pierpaolo Greco, Carlo Augusto Bortolotti, Paolo Samorì, Fabio Biscarini
Published in: Advanced Functional Materials, Issue 34, 19, 2313871, 2024, ISSN 1616-301X
Publisher: Wiley-VCH
DOI: 10.1002/ADFM.202313871

Responsive Molecules for Organic Neuromorphic Devices: Harnessing Memory Diversification

Author(s): Yusheng Chen, Bin Han, Marco Gobbi, Lili Hou, Paolo Samorì
Published in: Advanced Materials, Issue 37, 19, 2418281, 2025, ISSN 0935-9648
Publisher: Wiley-VCH
DOI: 10.1002/ADMA.202418281

Engineering the Interfacing of Molecules with 2D Transition Metal Dichalcogenides: Enhanced Multifunctional Electronics

Author(s): Bin Han, Paolo Samorì
Published in: Accounts of Chemical Research, Issue 57, 17, 2532–2545, 2024, ISSN 0001-4842
Publisher: American Chemical Society
DOI: 10.1021/ACS.ACCOUNTS.4C00338

Hydrogen-Assisted Thermal Treatment of Electrode Materials for Electrochemical Double-Layer Capacitors

Author(s): Matteo GentileSebastiano Bellani*Marilena I. ZappiaAgnese GamberiniValentina MastronardiMatteo AbruzzeseLuca GabatelLea PasqualeSergio MarrasAhmad BagheriHossein BeydaghiEvie L. PapadopoulouGuglielmo LanzaniFrancesco Bonaccorso*
Published in: ACS Applied Materials & Interfaces, 2024, ISSN 1944-8252
Publisher: American Chemical Society
DOI: 10.1021/ACSAMI.3C18629

Decoding Niobium Carbide MXene Dual-Functional Photoactive Cathode in Photoenhanced Hybrid Zinc-Ion Capacitor

Author(s): Jalal Azadmanjiri; Jakub Regner; Jiri Sturala; Zdeněk Sofer
Published in: ACS Materials Letters, 2024, ISSN 2639-4979
Publisher: American Chemical Society (ACS)
DOI: 10.5281/ZENODO.12543987

Highly efficient organic–graphene hybrid photodetectors via molecular peripheral editing

Author(s): Shuting Dai, Miao Xie, Can Wang, Yuying Wang, Bin Han, Shunqi Xu, Kexin Wang, Anna Zhuravlova, Bin Xu, Lifeng Chi, Wenjing Tian, Paolo Samorì
Published in: Journal of Materials Chemistry C, Issue 12, 36, 14667-14674, 2024, ISSN 2050-7534
Publisher: Royal Society of Chemistry
DOI: 10.1039/D4TC02010C

Exotic Photothermal Response in Ti-Based MXene Optoelectronic Devices

Author(s): Stefano Ippolito, Francesca Urban, Paolo Samorì, Jonathan E. Spanier, Yury Gogotsi
Published in: Advanced Electronic Materials, Issue 11, 13, 2500017, 2025, ISSN 2199-160X
Publisher: Wiley-VCH
DOI: 10.1002/AELM.202500017

Interface-Tailored Secondary Excitation and Ultrafast Charge/Energy Transfer in Ti3C2Tx-MoS2 Heterostructure Films

Author(s): Jiaxu ZhangRafael Muñoz-MármolShuai FuXiaodong LiWenhao ZhengAndrea VillaGiuseppe M. PaternòDarius PohlAlexander TahnMike HambschStefan C. B. MannsfeldDongqi LiHao XuQuanquan GuoHai I. Wang*Francesco Scotognella*Minghao Yu*Xinliang Feng*
Published in: Journal of the American Chemical Society, 2025, ISSN 1520-5126
Publisher: American Chemical Society
DOI: 10.1021/JACS.5C01826

Production of Ultrathin and High-Quality Nanosheet Networks via Layer-by-Layer Assembly at Liquid–Liquid Interfaces

Author(s): Joseph Neilson; Eoin Caffrey; Oran Cassidy; Cian Gabbett; Kevin Synnatschke; Eileen Schneider; Jose Maria Munuera; Tian Carey; Max Rimmer; Zdeněk Sofer; Janina Maultzsch; Sarah J. Haigh; Jonathan N. Coleman
Published in: ACS Nano, 2024, ISSN 1936-086X
Publisher: American Chemical Society (ACS)
DOI: 10.1021/ACSNANO.4C09745

Knot Architecture for Biocompatible and Semiconducting 2D Electronic Fiber Transistors

Author(s): Tian Carey, Jack Maughan, Luke Doolan, Eoin Caffrey, James Garcia, Shixin Liu, Harneet Kaur, Cansu Ilhan, Shayan Seyedin, Jonathan N. Coleman
Published in: Small methods, 2024, ISSN 2366-9608
Publisher: Wiley-VCH
DOI: 10.1002/SMTD.202301654

Inert Liquid Exfoliation and Langmuir-Type Thin Film Deposition of Semimetallic Metal Diborides

Author(s): Synnatschke, Kevin
Published in: ACS Nano, 2024, ISSN 1936-086X
Publisher: American Chemical Society (ACS)
DOI: 10.1021/ACSNANO.4C04626

Algorithm for Reproducible Analysis of Semiconducting 2D Nanomaterials based on UV/VIS Spectroscopy

Author(s): Backes, Claudia
Published in: Advanced Materials Interfaces, 2024, ISSN 2196-7350
Publisher: Wiley
DOI: 10.1002/ADMI.202400311

Solution-Processable Electronic-Grade 2D WTe2 Enabled by Synergistic Dual Ammonium Intercalation

Author(s): Hyejung YangKevin SynnatschkeJiho YoonHossein MirhosseiniIlka M. HermesXiaodong LiChristof NeumannAhiud MoragAndrey TurchaninThomas D. KühneStuart S. P. ParkinSheng Yang*Ali Shaygan Nia*Xinliang Feng*
Published in: ACS Nano, 2025, ISSN 1936-086X
Publisher: American Chemical Society (United States)
DOI: 10.1021/ACSNANO.5C01224

Boosting Zinc Hybrid Supercapacitor Performance via Thiol Functionalization of Graphene-Based Cathodes

Author(s): Cataldo Valentini, Verónica Montes-García, Artur Ciesielski, Paolo Samorì
Published in: Advanced Science, Issue 11, 22, 2309041, 2024, ISSN 2198-3844
Publisher: Wiley-VCH
DOI: 10.1002/ADVS.202309041

Enhanced Photothermal Conversion through 2D/0D Nano-Heterojunction Engineering for Highly Efficient Solar Desalination

Author(s): Honglei Wang, Yifan Bo, Hongguang Wang, Malte Klingenhof, Zhehao Tao, Dong Wang, Bing Wu, Adrián Tamayo, Bin Han, Pengfei Cheng, Peter A. van Aken, Zdenek Sofer, Runfeng Chen, Peter Strasser, Peter Schaaf, Dirk M. Guldi, Paolo Samorì
Published in: Journal of the American Chemical Society, Issue 147, 29, 25750-25760, 2025, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/JACS.5C07491

Nature Communications

Author(s): Laura Gambini; Cian Gabbett; Luke Doolan; Lewys Jones; Jonathan N. Coleman; Paddy Gilligan; Stefano Sanvito
Published in: Nature Communications, 2024, ISSN 2041-1723
Publisher: Nature Portfolio
DOI: 10.1038/S41467-024-52260-2

Liquid Processed Nano As₄S₄/SWCNTs Composite Electrodes for High-Performance Li-Ion and Na-Ion Battery Anodes

Author(s): Mark McCrystall; Cian Gabbett; Harneet Kaur; Tian Carey; Jose Munera; Lee Gannon; Cormac Mc Guinness; Valeria Nicolosi; Jonathan N. Coleman; Bharathi Konkena
Published in: ACS Nano, 2024, ISSN 1936-086X
Publisher: American Chemical Society (ACS)
DOI: 10.1021/ACS.ENERGYFUELS.4C03525

Light-Modulated Humidity Sensing in Spiropyran Functionalized MoS2 Transistors

Author(s): Adrián Tamayo, Wojciech Danowski, Bin Han, Yeonsu Jeong, Paolo Samorì
Published in: Small, 2024, ISSN 1613-6829
Publisher: Wiley
DOI: 10.1002/SMLL.202404633

Entropy Engineering of 2D Materials

Author(s): Hao Mei, Yuxuan Zhang, Panpan Zhang, Antonio Gaetano Ricciardulli, Paolo Samorì, Sheng Yang
Published in: Advanced Science, Issue 11, 46, 2409404, 2024, ISSN 2198-3844
Publisher: Wiley-VCH
DOI: 10.1002/ADVS.202409404

Tailoring electrochemically exfoliated graphene electroactive pathways in cementitious composites for structural health monitoring of constructions

Author(s): Małgorzata Safuta, Cataldo Valentini, Artur Ciesielski, Paolo Samorì
Published in: Nanoscale, Issue 16, 33, 15824-15833, 2024, ISSN 2040-3372
Publisher: Royal Society of Chemistry
DOI: 10.1039/D4NR01764A

Venice's macroalgae-derived active material for aqueous, organic, and solid-state supercapacitors

Author(s): bonaccorso, francesco; Bagheri, Ahmad; Mastronardi, Valentina; Bellani, Sebastiano
Published in: Chemical Engineering Journal, 2024, ISSN 1873-3212
Publisher: Elsevier
DOI: 10.5281/ZENODO.14960903

Graphene Nanodots as Substrates for SEIRAS and SERS Studies on Membrane Proteins

Author(s): Ariadna Murillo-Bello, Antonio Gaetano Ricciardulli, Abdul Rehman Umar, Tatjana Gerasimova, Thorsten Friedrich, Nicolas Javahiraly, Paolo Samorì, Petra Hellwig
Published in: Langmuir, Issue 41, 25, 16468–16476, 2025, ISSN 0743-7463
Publisher: American Chemical Society
DOI: 10.1021/ACS.LANGMUIR.5C01808