Developing New 2D Materials and Heterostructures for Printed Digital Devices

Informazioni relative al progetto

2D-PRINTABLE

ID dell’accordo di sovvenzione: 101135196

DOI

10.3030/101135196

Data della firma CE 30 Ottobre 2023

Data di avvio 1 Ottobre 2023

Data di completamento 30 Settembre 2026

Finanziato da

• Digital, Industry and Space

Costo totale

€ 4 092 496,25

Contributo UE

€ 3 999 996,00

Coordinato da

THE PROVOST, FELLOWS, FOUNDATION SCHOLARS & THE OTHER MEMBERS OF BOARD, OF THE COLLEGE OF THE HOLY & UNDIVIDED TRINITY OF QUEEN ELIZABETH NEAR DUBLIN
Ireland

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Risultati finali

Documents, reports (10)

Tuneable functionalization of TMDs

Via defect chemistry (e.g., with thiols or diazonium salts) and with metallic nanoparticles

Characterization of nanosheets, networks and heterostacks built from initially available 2D materials

Combination of SEM, AFM, FIB-SEM and various spectroscopies

Synthesis of bulk materials

Done in closed quartz ampoules and CVT

Electrical characterization of LPE derived novel materials

Vertical and horizontal, 2-, 3- or 4-terminal devices: extraction of µFET, Ion/Ioff, VT, SS

Characterization of new materials identified through theory

Using various standardized characterization methods, e.g., Raman, UV-vis-IR spectroscopies, AFM/TEM microscopies

Functionalization of 2D materials beyond TMDs

Use of strong electrophiles (e.g., diazoniums salts, halides, amines and maleimides) or nucleophiles (e.g., hydroxyls, amines)

Formation of discrete assemblies of 2DMs

Use of bi- or multidentate molecular linkers to form heterostructures

Ink production/printing

Controlled rheological properties

Cross-linking forming networks and heterostructures

Use of bi- or multidentate molecular linkers

Theory-identified novel 2D materials

Van der Waals DFT screening

Websites, patent fillings, videos etc. (1)

Project’s corporate identity

Communication toolbox, incl. project website, templates, newsletter, and diss. database

Data sets, microdata, etc (2)

Database on available materials

Including bulk materials, LPE/EE/CE nanosheets and their specifications (quantity, dimensions, defectiveness)

Band gaps of monolayers and multilayers

Direct/indirect band gaps computed for semiconducting monolayers and multilayers

Demonstrators, pilots, prototypes (1)

Beyond-state-of-the-art all-nanosheet TFTs

Optimization of all interfaces and components to maximize charge injection and transport. Quantification of µFET, Ion/Ioff, VT, SS

Pubblicazioni

Peer reviewed articles (36)

Low-Temperature Electron Spin Resonance Study of MnPS₃ Antiferromagnetic Single Crystal

Autori: Moro, Fabrizio; Wu, Bing; Plutnarová, Iva; Plutnar, Jan; Sofer, Zdenek
Pubblicato in: The Journal of Physical Chemistry C, 2024, ISSN 1932-7455
Editore: American Chemical Society (ACS)
DOI: 10.1021/ACS.JPCC.4C06156

Synthesis of Xenes: physical and chemical methods

Autori: Molle, Alessandro; Junji, Yuhara; Yukiko, Yamada-Takamura; Sofer, Zd
Pubblicato in: Chemical Society Reviews, 2025, ISSN 1460-4744
Editore: Royal Society of Chemistry
DOI: 10.5281/ZENODO.14760360

Alkaline electrochemical deposition of Pt for alkaline electrolyzers

Autori: Valentina Mastronardi a , Agnese Gamberini a , Marilena Isabella Zappia a , Yong Zuo b c , Matteo Abruzzese a , Ahmad Bagheri a , Hossein Beydaghi a , Luca Gabatel a d , Sanjay Thorat a , Michele Ferri b , Filippo Drago b , Lea Pasquale e , Li
Pubblicato in: International Journal of Hydrogen Energy, 2024, ISSN 1879-3487
Editore: Elsevier Ltd
DOI: 10.1016/J.IJHYDENE.2024.07.086

Liquid-Phase Exfoliation of Arsenic Trisulfide (As2S3) Nanosheets and Their Use as Anodes in Potassium-Ion Batteries

Autori: KAUR, HARNEET
Pubblicato in: ACS nano, 2024, ISSN 1936-086X
Editore: American Chemical Society (ACS)
DOI: 10.1021/ACSNANO.4C03501

Ionogel-Based Electrodes for Non-Flammable High-Temperature Operating Electrochemical Double-Layer Capacitors

Autori: Agnese Gamberini, Tobias Burton, Alix Ladam, Ahmad Bagheri, Matteo Abruzzese, Hossein Beydaghi, Valentina Mastronardi, Elena Calcagno, Samaneh Vaez, Alberto Morenghi, Teresa Gatti, Anais Falgayrat, Francesco Bonaccorso, Sebastien Fantini, Sebastiano Bella
Pubblicato in: ChemSusChem, 2025, ISSN 1864-564X
Editore: Wiley-VCH
DOI: 10.1002/CSSC.202401874

Defect-engineering of liquid-phase exfoliated 2D semiconductors: stepwise covalent growth of electronic lateral hetero-networks

Autori: Antonio Gaetano Ricciardulli, Christopher E. Petoukhoff, Anna Zhuravlova, Adam G. Kelly, Chun Ma, Frédéric Laquai, Jonathan N. Coleman, Paolo Samorì
Pubblicato in: Materials Horizons, Numero 11, 22, 5614-5621, 2024, ISSN 2051-6355
Editore: Royal Society of Chemistry
DOI: 10.1039/D4MH00882K

Molecular Connectors Boosting the Performance of MoS2 Cathodes in Zinc-Ion Batteries

Autori: Haipeng Guo, Verónica Montes-García, Haijun Peng, Paolo Samorì, Artur Ciesielski
Pubblicato in: Small, Numero 20, 29, 2310338, 2024, ISSN 1613-6810
Editore: Wiley-VCH
DOI: 10.1002/SMLL.202310338

Covalent Organic Frameworks and 2D Materials Hybrids: Synthesis Strategies, Properties Enhancements, and Future Directions

Autori: Cataldo Valentini, Verónica Montes-García, Dawid Pakulski, Paolo Samorì, Artur Ciesielski
Pubblicato in: Small, Numero 21, 8, 2410544, 2025, ISSN 1613-6810
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/SMLL.202410544

Piezoresistive Platinum Diselenide Pressure Sensors with Reliable High Sensitivity and Their Integration into Complementary Metal-Oxide-Semiconductor Circuits

Autori: Sebastian LukasNico RademacherSofía CrucesMichael GrossEva DesguéStefan HeisererNikolas DominikMaximilian PrechtlOliver HartwigCormac Ó CoileáinTanja Stimpel-LindnerPierre LegagneuxArto RantalaJuha-Matti SaariMiika SoikkeliGeorg S. DuesbergMax C. Lemme
Pubblicato in: ACS nano, 2025, ISSN 1936-086X
Editore: American Chemical Society
DOI: 10.1021/ACSNANO.4C15098

Dopant-Free Spiro-OMe2 Imidazole-Based Hole-Transporting Material for Stable and Low-Cost Organic–Inorganic Perovskite Solar Cell

Autori: Haji-khan Mirzaei, L., Shahroosvand, H., Farokhi, A., Bayat, E., Bellani, S., Anichini, C., Ameri, M., & Bonaccorso, F
Pubblicato in: ACS Omega, 2024, ISSN 2470-1343
Editore: American Chemical Society
DOI: 10.1021/ACSOMEGA.4C05440

High-κ Wide-Gap Layered Dielectric for Two-Dimensional van der Waals Heterostructures

Autori: Sofer, Zdenek
Pubblicato in: ACS Nano, 2024, ISSN 1936-086X
Editore: American Chemical Society (ACS)
DOI: 10.1021/ACSNANO.3C10411

Orientation Dependent Interlayer Coupling in Organic–Inorganic Heterostructures

Autori: al, StCian Bartlam, Nihit Saigefan Heiserer, Hendrik Lambers, Ursula Wurstbauer, Georg S. Duesberg
Pubblicato in: Advanced Functional Materials, 2024, ISSN 1616-3028
Editore: Wiley
DOI: 10.1002/ADFM.202315302

Covalent organic framework-based Li–S batteries: functional separators promoting Li+ transport and polysulfide trapping

Autori: Sara Gullace, Matteo Abruzzese, Luca Cusin, Gabriele Saleh, Sanjay B. Thorat, Agnese Gamberini, Sebastiano Bellani, Artur Ciesielski, Francesco Bonaccorso, Paolo Samorì
Pubblicato in: Journal of Materials Chemistry A, Numero 12, 37, 25359-25370, 2024, ISSN 2050-7496
Editore: Royal Society of Chemistry
DOI: 10.1039/D4TA03930K

Dressing AgNWs with MXenes Nanosheets: Transparent Printed Electrodes Combining High-Conductivity and Tunable Work Function for High-Performance Opto-Electronics

Autori: Zhongshi Ju, Yusheng Chen, Peng Li, Jiangang Ma, Haiyang Xu, Yichun Liu, Paolo Samorì
Pubblicato in: Advanced Materials, Numero 36, 48, 2412512, 2024, ISSN 0935-9648
Editore: Wiley-VCH
DOI: 10.1002/ADMA.202412512

How Biorecognition Affects the Electronic Properties of Reduced Graphene Oxide in Electrolyte-Gated Transistor Immunosensors

Autori: Matteo Sensi, Rafael Furlan de Oliveira, Marcello Berto, Alessandro Paradisi, Pierpaolo Greco, Carlo Augusto Bortolotti, Paolo Samorì, Fabio Biscarini
Pubblicato in: Advanced Functional Materials, Numero 34, 19, 2313871, 2024, ISSN 1616-301X
Editore: Wiley-VCH
DOI: 10.1002/ADFM.202313871

Responsive Molecules for Organic Neuromorphic Devices: Harnessing Memory Diversification

Autori: Yusheng Chen, Bin Han, Marco Gobbi, Lili Hou, Paolo Samorì
Pubblicato in: Advanced Materials, Numero 37, 19, 2418281, 2025, ISSN 0935-9648
Editore: Wiley-VCH
DOI: 10.1002/ADMA.202418281

Engineering the Interfacing of Molecules with 2D Transition Metal Dichalcogenides: Enhanced Multifunctional Electronics

Autori: Bin Han, Paolo Samorì
Pubblicato in: Accounts of Chemical Research, Numero 57, 17, 2532–2545, 2024, ISSN 0001-4842
Editore: American Chemical Society
DOI: 10.1021/ACS.ACCOUNTS.4C00338

Hydrogen-Assisted Thermal Treatment of Electrode Materials for Electrochemical Double-Layer Capacitors

Autori: Matteo GentileSebastiano Bellani*Marilena I. ZappiaAgnese GamberiniValentina MastronardiMatteo AbruzzeseLuca GabatelLea PasqualeSergio MarrasAhmad BagheriHossein BeydaghiEvie L. PapadopoulouGuglielmo LanzaniFrancesco Bonaccorso*
Pubblicato in: ACS Applied Materials & Interfaces, 2024, ISSN 1944-8252
Editore: American Chemical Society
DOI: 10.1021/ACSAMI.3C18629

Decoding Niobium Carbide MXene Dual-Functional Photoactive Cathode in Photoenhanced Hybrid Zinc-Ion Capacitor

Autori: Jalal Azadmanjiri; Jakub Regner; Jiri Sturala; Zdeněk Sofer
Pubblicato in: ACS Materials Letters, 2024, ISSN 2639-4979
Editore: American Chemical Society (ACS)
DOI: 10.5281/ZENODO.12543987

Highly efficient organic–graphene hybrid photodetectors via molecular peripheral editing

Autori: Shuting Dai, Miao Xie, Can Wang, Yuying Wang, Bin Han, Shunqi Xu, Kexin Wang, Anna Zhuravlova, Bin Xu, Lifeng Chi, Wenjing Tian, Paolo Samorì
Pubblicato in: Journal of Materials Chemistry C, Numero 12, 36, 14667-14674, 2024, ISSN 2050-7534
Editore: Royal Society of Chemistry
DOI: 10.1039/D4TC02010C

Exotic Photothermal Response in Ti-Based MXene Optoelectronic Devices

Autori: Stefano Ippolito, Francesca Urban, Paolo Samorì, Jonathan E. Spanier, Yury Gogotsi
Pubblicato in: Advanced Electronic Materials, Numero 11, 13, 2500017, 2025, ISSN 2199-160X
Editore: Wiley-VCH
DOI: 10.1002/AELM.202500017

Interface-Tailored Secondary Excitation and Ultrafast Charge/Energy Transfer in Ti3C2Tx-MoS2 Heterostructure Films

Autori: Jiaxu ZhangRafael Muñoz-MármolShuai FuXiaodong LiWenhao ZhengAndrea VillaGiuseppe M. PaternòDarius PohlAlexander TahnMike HambschStefan C. B. MannsfeldDongqi LiHao XuQuanquan GuoHai I. Wang*Francesco Scotognella*Minghao Yu*Xinliang Feng*
Pubblicato in: Journal of the American Chemical Society, 2025, ISSN 1520-5126
Editore: American Chemical Society
DOI: 10.1021/JACS.5C01826

Production of Ultrathin and High-Quality Nanosheet Networks via Layer-by-Layer Assembly at Liquid–Liquid Interfaces

Autori: Joseph Neilson; Eoin Caffrey; Oran Cassidy; Cian Gabbett; Kevin Synnatschke; Eileen Schneider; Jose Maria Munuera; Tian Carey; Max Rimmer; Zdeněk Sofer; Janina Maultzsch; Sarah J. Haigh; Jonathan N. Coleman
Pubblicato in: ACS Nano, 2024, ISSN 1936-086X
Editore: American Chemical Society (ACS)
DOI: 10.1021/ACSNANO.4C09745

Knot Architecture for Biocompatible and Semiconducting 2D Electronic Fiber Transistors

Autori: Tian Carey, Jack Maughan, Luke Doolan, Eoin Caffrey, James Garcia, Shixin Liu, Harneet Kaur, Cansu Ilhan, Shayan Seyedin, Jonathan N. Coleman
Pubblicato in: Small methods, 2024, ISSN 2366-9608
Editore: Wiley-VCH
DOI: 10.1002/SMTD.202301654

Inert Liquid Exfoliation and Langmuir-Type Thin Film Deposition of Semimetallic Metal Diborides

Autori: Synnatschke, Kevin
Pubblicato in: ACS Nano, 2024, ISSN 1936-086X
Editore: American Chemical Society (ACS)
DOI: 10.1021/ACSNANO.4C04626

Algorithm for Reproducible Analysis of Semiconducting 2D Nanomaterials based on UV/VIS Spectroscopy

Autori: Backes, Claudia
Pubblicato in: Advanced Materials Interfaces, 2024, ISSN 2196-7350
Editore: Wiley
DOI: 10.1002/ADMI.202400311

Solution-Processable Electronic-Grade 2D WTe2 Enabled by Synergistic Dual Ammonium Intercalation

Autori: Hyejung YangKevin SynnatschkeJiho YoonHossein MirhosseiniIlka M. HermesXiaodong LiChristof NeumannAhiud MoragAndrey TurchaninThomas D. KühneStuart S. P. ParkinSheng Yang*Ali Shaygan Nia*Xinliang Feng*
Pubblicato in: ACS Nano, 2025, ISSN 1936-086X
Editore: American Chemical Society (United States)
DOI: 10.1021/ACSNANO.5C01224

Boosting Zinc Hybrid Supercapacitor Performance via Thiol Functionalization of Graphene-Based Cathodes

Autori: Cataldo Valentini, Verónica Montes-García, Artur Ciesielski, Paolo Samorì
Pubblicato in: Advanced Science, Numero 11, 22, 2309041, 2024, ISSN 2198-3844
Editore: Wiley-VCH
DOI: 10.1002/ADVS.202309041

Enhanced Photothermal Conversion through 2D/0D Nano-Heterojunction Engineering for Highly Efficient Solar Desalination

Autori: Honglei Wang, Yifan Bo, Hongguang Wang, Malte Klingenhof, Zhehao Tao, Dong Wang, Bing Wu, Adrián Tamayo, Bin Han, Pengfei Cheng, Peter A. van Aken, Zdenek Sofer, Runfeng Chen, Peter Strasser, Peter Schaaf, Dirk M. Guldi, Paolo Samorì
Pubblicato in: Journal of the American Chemical Society, Numero 147, 29, 25750-25760, 2025, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/JACS.5C07491

Nature Communications

Autori: Laura Gambini; Cian Gabbett; Luke Doolan; Lewys Jones; Jonathan N. Coleman; Paddy Gilligan; Stefano Sanvito
Pubblicato in: Nature Communications, 2024, ISSN 2041-1723
Editore: Nature Portfolio
DOI: 10.1038/S41467-024-52260-2

Liquid Processed Nano As₄S₄/SWCNTs Composite Electrodes for High-Performance Li-Ion and Na-Ion Battery Anodes

Autori: Mark McCrystall; Cian Gabbett; Harneet Kaur; Tian Carey; Jose Munera; Lee Gannon; Cormac Mc Guinness; Valeria Nicolosi; Jonathan N. Coleman; Bharathi Konkena
Pubblicato in: ACS Nano, 2024, ISSN 1936-086X
Editore: American Chemical Society (ACS)
DOI: 10.1021/ACS.ENERGYFUELS.4C03525

Light-Modulated Humidity Sensing in Spiropyran Functionalized MoS2 Transistors

Autori: Adrián Tamayo, Wojciech Danowski, Bin Han, Yeonsu Jeong, Paolo Samorì
Pubblicato in: Small, 2024, ISSN 1613-6829
Editore: Wiley
DOI: 10.1002/SMLL.202404633

Entropy Engineering of 2D Materials

Autori: Hao Mei, Yuxuan Zhang, Panpan Zhang, Antonio Gaetano Ricciardulli, Paolo Samorì, Sheng Yang
Pubblicato in: Advanced Science, Numero 11, 46, 2409404, 2024, ISSN 2198-3844
Editore: Wiley-VCH
DOI: 10.1002/ADVS.202409404

Tailoring electrochemically exfoliated graphene electroactive pathways in cementitious composites for structural health monitoring of constructions

Autori: Małgorzata Safuta, Cataldo Valentini, Artur Ciesielski, Paolo Samorì
Pubblicato in: Nanoscale, Numero 16, 33, 15824-15833, 2024, ISSN 2040-3372
Editore: Royal Society of Chemistry
DOI: 10.1039/D4NR01764A

Venice's macroalgae-derived active material for aqueous, organic, and solid-state supercapacitors

Autori: bonaccorso, francesco; Bagheri, Ahmad; Mastronardi, Valentina; Bellani, Sebastiano
Pubblicato in: Chemical Engineering Journal, 2024, ISSN 1873-3212
Editore: Elsevier
DOI: 10.5281/ZENODO.14960903

Graphene Nanodots as Substrates for SEIRAS and SERS Studies on Membrane Proteins

Autori: Ariadna Murillo-Bello, Antonio Gaetano Ricciardulli, Abdul Rehman Umar, Tatjana Gerasimova, Thorsten Friedrich, Nicolas Javahiraly, Paolo Samorì, Petra Hellwig
Pubblicato in: Langmuir, Numero 41, 25, 16468–16476, 2025, ISSN 0743-7463
Editore: American Chemical Society
DOI: 10.1021/ACS.LANGMUIR.5C01808