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Conjugated polymers with interchain aromaticity

Objective

INTERCHAIN aims to develop and investigate a ground-breaking new molecular design concept for conjugated polymers. The concept is expected to enable the occurrence of stacked-ring aromaticity between polymer chains, drastically advancing our fundamental understanding of stacked-ring aromaticity and introducing a route to exploit this effect for the development of conjugated polymers with excellent charge transport properties.

For conjugated polymers with excellent charge transport properties, strong intermolecular interactions are needed, which is difficult to achieve without compromising processability. However, as an emerging class of organic molecules, conjugated macrocycles provide an exciting playing field for the discovery of effects and properties that cannot usually be achieved. In contrast to other molecules, conjugated macrocycles can sustain global aromatic or antiaromatic ring currents, offering exciting prospects to enhance the properties of conjugated materials by enabling exceptionally strong intermolecular interactions. If the macrocycles used are antiaromatic, the interactions between two macrocycles can even result in stacked-ring aromaticity. Integrated into the backbone of conjugated polymers, such macrocycles may enable interchain stacked-ring aromaticity and interchain π‐electron delocalisation, in addition to intrachain π‐electron delocalisation. However, the inherent instability of the required antiaromatic molecules poses a tremendous challenge for the investigation of stacked-ring aromaticity and prevents the development of polymers that exploit this effect.

INTERCHAIN proposes a ground-breaking new molecular design concept that overcomes this challenge by eliminating the need for antiaromatic molecules to achieve stacked-ring aromaticity. The project will drastically advance our fundamental understanding of stacked-ring aromaticity, but it will also yield highly stable conjugated polymers with excellent properties for applications.

Fields of science (EuroSciVoc)

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Keywords

Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)

Programme(s)

Multi-annual funding programmes that define the EU’s priorities for research and innovation.

Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) ERC-2024-STG

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Host institution

TECHNISCHE UNIVERSITAET WIEN
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 1 499 103,00
Address
KARLSPLATZ 13
1040 Wien
Austria

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Region
Ostösterreich Wien Wien
Activity type
Higher or Secondary Education Establishments
Links
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 1 499 103,00

Beneficiaries (1)

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