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Reductive Transformations of Carbon Oxides

Objective

The development of new approaches to the activation and functionalisation of carbon monoxide and carbon dioxide is a highly topical and significant challenge for chemistry. The use of biomass and coal derived carbon monoxide as a fundamental building block for simple organic molecules is a key objective in energy research, and the latter, coupled with global warming considerations, dictate that new ways to both activate and derivatise carbon dioxide must also be found. The programme of work described in this proposal tackles these problems through experience and excellence in organometallic chemistry and small molecule activation. It is centred around three closely integrated and synergistic strands. The synthetic work in Strand 1 focuses on reductive assembly of carbon monoxide and carbon dioxide on low oxidation state metal centres to build simple organic molecules and rings stoichiometrically. The work in this strand will also be driven by developing a detailed understanding of the mechanisms of these reactions through experiment. A key feature of this proposal is the computational work, which is the subject of Strand 2, in which theory and modelling will be used in an iterative way to predict and inform the experimental synthetic and mechanistic work in Strand 1. Strand 3 will establish the underlying redox properties of these systems using electrochemical techniques, in order to ultimately to generate systems which will catalytically generate organic molecules from carbon monoxide and carbon dioxide. The program of work described in this proposal, which will deliver stoichiometric and catalytic recycling of carbon oxides, is at the frontier of future sustainable chemical technology. It is therefore of high risk, but ultimately extremely high reward.

Field of science

  • /natural sciences/chemical sciences/inorganic chemistry/inorganic compounds
  • /engineering and technology/environmental engineering/energy and fuels/fossil energy/coal
  • /engineering and technology/environmental engineering/waste management/recycling
  • /natural sciences/chemical sciences/electrochemistry/electrolysis
  • /natural sciences/chemical sciences/organic chemistry/organometallic chemistry
  • /agricultural sciences/agricultural biotechnology/biomass

Call for proposal

ERC-2009-AdG
See other projects for this call

Funding Scheme

ERC-AG - ERC Advanced Grant

Host institution

THE UNIVERSITY OF SUSSEX
Address
Sussex House Falmer
BN1 9RH Brighton
United Kingdom
Activity type
Higher or Secondary Education Establishments
EU contribution
€ 1 396 927,20
Principal investigator
Frederick Geoffrey Nethersole Cloke (Prof.)
Administrative Contact
Katherine Lennon (Ms.)

Beneficiaries (2)

THE UNIVERSITY OF SUSSEX
United Kingdom
EU contribution
€ 1 396 927,20
Address
Sussex House Falmer
BN1 9RH Brighton
Activity type
Higher or Secondary Education Establishments
Principal investigator
Frederick Geoffrey Nethersole Cloke (Prof.)
Administrative Contact
Katherine Lennon (Ms.)
INSTITUT NATIONAL DES SCIENCES APPLIQUEES DE TOULOUSE
France
EU contribution
€ 378 295,20
Address
Avenue De Rangueil 135
31077 Toulouse
Activity type
Higher or Secondary Education Establishments
Administrative Contact
Alain Guibert (Mr.)