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Content archived on 2024-06-18

Unravelling the Mechanism of Phosphine-Borane Dehydrocoupling for the Synthesis to Order of Valuable New Materials

Objective

"This project addresses the fundamental steps behind the transition-metal catalysed dehydrocoupling of phosphine boranes which will lead to the production of new polymeric materials that promise to deliver an exciting set of new main group polymers with potentially unique properties. The complementary expertise of the applicant (Miguel Huetos, MAH) and the host laboratories (Professor A. S. Weller, ASW) will allow for rapid progress to be made, providing a unified picture of all the factors crucial to the delivery of this challenging goal that will have long-lasting impact on materials science and technology, catalytic methodology and main-group chemistry. To this end, well-defined transition metal catalysts, precatalysts, intermediates, main group compounds and model complexes related to phosphine-borane dehydrogenation and dehydrocoupling will be synthesized and studied. This will be followed by the application of these systems in the synthesis to order of new phosphine-borane polymeric materials. These novel and unexplored materials are anticipated to useful properties such as: being elastomeric, flame retardant, etch resistant and preceramic properties. As well as providing outstanding training and career development opportunities for MAH the project will have a significant legacy in the development of low coordinate transition metal chemistry, main-group and new materials synthesis."

Fields of science (EuroSciVoc)

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

FP7-PEOPLE-2010-IEF
See other projects for this call

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

MC-IEF - Intra-European Fellowships (IEF)

Coordinator

THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD
EU contribution
€ 200 049,60
Address
WELLINGTON SQUARE UNIVERSITY OFFICES
OX1 2JD Oxford
United Kingdom

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Region
South East (England) Berkshire, Buckinghamshire and Oxfordshire Oxfordshire
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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