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Zawartość zarchiwizowana w dniu 2024-06-18

Unravelling the Mechanism of Phosphine-Borane Dehydrocoupling for the Synthesis to Order of Valuable New Materials

Cel

"This project addresses the fundamental steps behind the transition-metal catalysed dehydrocoupling of phosphine boranes which will lead to the production of new polymeric materials that promise to deliver an exciting set of new main group polymers with potentially unique properties. The complementary expertise of the applicant (Miguel Huetos, MAH) and the host laboratories (Professor A. S. Weller, ASW) will allow for rapid progress to be made, providing a unified picture of all the factors crucial to the delivery of this challenging goal that will have long-lasting impact on materials science and technology, catalytic methodology and main-group chemistry. To this end, well-defined transition metal catalysts, precatalysts, intermediates, main group compounds and model complexes related to phosphine-borane dehydrogenation and dehydrocoupling will be synthesized and studied. This will be followed by the application of these systems in the synthesis to order of new phosphine-borane polymeric materials. These novel and unexplored materials are anticipated to useful properties such as: being elastomeric, flame retardant, etch resistant and preceramic properties. As well as providing outstanding training and career development opportunities for MAH the project will have a significant legacy in the development of low coordinate transition metal chemistry, main-group and new materials synthesis."

Zaproszenie do składania wniosków

FP7-PEOPLE-2010-IEF
Zobacz inne projekty w ramach tego zaproszenia

Koordynator

THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD
Wkład UE
€ 200 049,60
Adres
WELLINGTON SQUARE UNIVERSITY OFFICES
OX1 2JD Oxford
Zjednoczone Królestwo

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Region
South East (England) Berkshire, Buckinghamshire and Oxfordshire Oxfordshire
Rodzaj działalności
Higher or Secondary Education Establishments
Kontakt administracyjny
Stephen Conway (Dr.)
Linki
Koszt całkowity
Brak danych