Unravelling the Mechanism of Phosphine-Borane Dehydrocoupling for the Synthesis to Order of Valuable New Materials

Información del proyecto

DEHYDROCOUPLE

Identificador del acuerdo de subvención: 273235

Proyecto cerrado

Fecha de inicio 1 Julio 2011

Fecha de finalización 30 Junio 2013

Financiado con arreglo a

• Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)

Coste total € 200 049,60

Aportación de la UE € 200 049,60

Coordinado por

THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD
Reino Unido

Objetivo

"This project addresses the fundamental steps behind the transition-metal catalysed dehydrocoupling of phosphine boranes which will lead to the production of new polymeric materials that promise to deliver an exciting set of new main group polymers with potentially unique properties. The complementary expertise of the applicant (Miguel Huetos, MAH) and the host laboratories (Professor A. S. Weller, ASW) will allow for rapid progress to be made, providing a unified picture of all the factors crucial to the delivery of this challenging goal that will have long-lasting impact on materials science and technology, catalytic methodology and main-group chemistry. To this end, well-defined transition metal catalysts, precatalysts, intermediates, main group compounds and model complexes related to phosphine-borane dehydrogenation and dehydrocoupling will be synthesized and studied. This will be followed by the application of these systems in the synthesis to order of new phosphine-borane polymeric materials. These novel and unexplored materials are anticipated to useful properties such as: being elastomeric, flame retardant, etch resistant and preceramic properties. As well as providing outstanding training and career development opportunities for MAH the project will have a significant legacy in the development of low coordinate transition metal chemistry, main-group and new materials synthesis."

Ámbito científico (EuroSciVoc)

CORDIS clasifica los proyectos con EuroSciVoc, una taxonomía plurilingüe de ámbitos científicos, mediante un proceso semiautomático basado en técnicas de procesamiento del lenguaje natural. Véase: https://op.europa.eu/en/web/eu-vocabularies/euroscivoc.

• ciencias naturales › ciencias químicas › ciencia de polímeros
• ciencias naturales › ciencias químicas › catálisis

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Programa(s)

• FP7-PEOPLE - Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)

Tema(s)

• FP7-PEOPLE-2010-IEF - Marie-Curie Action: "Intra-European fellowships for career development"

Convocatoria de propuestas

FP7-PEOPLE-2010-IEF
Consulte otros proyectos de esta convocatoria

Régimen de financiación

MC-IEF -

Coordinador

THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD

• Aportación de la UE: € 200 049,60
• Dirección: WELLINGTON SQUARE UNIVERSITY OFFICES ; OX1 2JD Oxford ; Reino Unido
• Región: South East (England) › Berkshire, Buckinghamshire and Oxfordshire › Oxfordshire
• Tipo de actividad: Institutos de educación secundaria o superior
• Coste total: Sin datos