Objective
The future of energy supply depends on innovative breakthroughs regarding the design of efficient systems for the conversion and storage of solar energy. The production of H2 through direct light-driven water-splitting in a Photo-Electro-Chemical (PEC) cell, appears as a promising solution. However such cells need to respond to three main characteristics: sustainability, cost-effectiveness and stability. Fulfilling these requirements raise important scientific questions regarding the elaboration and combination of the best materials able to harvest light and catalyse H2 and O2 evolution.
The objective of this project is to design an operating photocathode based on Earth abundant elements for PEC H2 production, answering therefore the sustainability and cost issues. The novelty relies on the approach gathering organic and hybrid photovoltaics with artificial photosynthesis to design new materials and architectures: I will combine and immobilize molecular photosensitizers with bioinspired catalysts on an electrode thanks to electronic junctions. This will allow (i) optimizing light-driven charge separation, (ii) driving electrons from the electrode to the catalyst, (iii) and limiting charge recombination processes.
The project is divided into four tasks. The two first tasks are focused on the elaboration of new photoelectrode architectures: In task 1, I propose to engineer a H2-evolving electrode thanks to donor-acceptor dyes immobilized on p-type semi-conductors. In task 2, I propose to implement organic photovoltaics materials in a H2-evolving electrode. The third task focuses on the elaboration of new catalysts, incorporating redox-active (non-innocent) ligands in order to systematically bias electron transfer towards the catalyst. These new catalysts will be implemented on the new photoelectrode architectures.
The last task focuses on the ultimate assembly of a PEC cell and on the performance assessments at all steps of the project (photocathodes and full cell).
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences physical sciences electromagnetism and electronics semiconductivity
- natural sciences chemical sciences catalysis
- natural sciences biological sciences botany
- engineering and technology environmental engineering energy and fuels renewable energy solar energy photovoltaic
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Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
ERC-2012-StG_20111012
See other projects for this call
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Host institution
75015 PARIS 15
France
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.