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Contenido archivado el 2024-06-18

TRANSITION METAL-NHC COMPLEXES FOR SMALL MOLECULE ACTIVATIONS

Objetivo

The coordination chemistry of 3d transition metals with covalently tethered N-heterocyclic carbene (NHC) ligands is almost completely unexplored. In this project, we will develop a completely new and stereo-electronically more versatile type of NHC ligand functionalized with anionic amido or phosphido donor groups. Our ligands will enable the development of a new family of three-coordinate complexes of low-valent chromium, manganese iron, cobalt and nickel, represented by 1 and 2. The three coordinate complexes will possess intrinsically interesting molecular and electronic structures, and we will develop their reactivity towards a range of small-molecule activation reactions.

Ámbito científico (EuroSciVoc)

Programa(s)

Tema(s)

Convocatoria de propuestas

FP7-PEOPLE-2012-IIF
Consulte otros proyectos de esta convocatoria

Régimen de financiación

MC-IIF - International Incoming Fellowships (IIF)

Coordinador

THE UNIVERSITY OF MANCHESTER
Aportación de la UE
€ 299 558,40
Dirección
OXFORD ROAD
M13 9PL Manchester
Reino Unido
Región
North West (England) Greater Manchester Manchester
Tipo de actividad
Higher or Secondary Education Establishments
Enlaces
Coste total
Sin datos