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TRANSITION METAL-NHC COMPLEXES FOR SMALL MOLECULE ACTIVATIONS

Objectif

The coordination chemistry of 3d transition metals with covalently tethered N-heterocyclic carbene (NHC) ligands is almost completely unexplored. In this project, we will develop a completely new and stereo-electronically more versatile type of NHC ligand functionalized with anionic amido or phosphido donor groups. Our ligands will enable the development of a new family of three-coordinate complexes of low-valent chromium, manganese iron, cobalt and nickel, represented by 1 and 2. The three coordinate complexes will possess intrinsically interesting molecular and electronic structures, and we will develop their reactivity towards a range of small-molecule activation reactions.

Champ scientifique (EuroSciVoc)

Programme(s)

Thème(s)

Appel à propositions

FP7-PEOPLE-2012-IIF
Voir d’autres projets de cet appel

Régime de financement

MC-IIF - International Incoming Fellowships (IIF)

Coordinateur

THE UNIVERSITY OF MANCHESTER
Contribution de l’UE
€ 299 558,40
Adresse
OXFORD ROAD
M13 9PL Manchester
Royaume-Uni
Région
North West (England) Greater Manchester Manchester
Type d’activité
Higher or Secondary Education Establishments
Liens
Coût total
Aucune donnée