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Contenuto archiviato il 2024-06-18

TRANSITION METAL-NHC COMPLEXES FOR SMALL MOLECULE ACTIVATIONS

Obiettivo

The coordination chemistry of 3d transition metals with covalently tethered N-heterocyclic carbene (NHC) ligands is almost completely unexplored. In this project, we will develop a completely new and stereo-electronically more versatile type of NHC ligand functionalized with anionic amido or phosphido donor groups. Our ligands will enable the development of a new family of three-coordinate complexes of low-valent chromium, manganese iron, cobalt and nickel, represented by 1 and 2. The three coordinate complexes will possess intrinsically interesting molecular and electronic structures, and we will develop their reactivity towards a range of small-molecule activation reactions.

Campo scientifico (EuroSciVoc)

Argomento(i)

Invito a presentare proposte

FP7-PEOPLE-2012-IIF
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Meccanismo di finanziamento

MC-IIF - International Incoming Fellowships (IIF)

Coordinatore

THE UNIVERSITY OF MANCHESTER
Contributo UE
€ 299 558,40
Indirizzo
OXFORD ROAD
M13 9PL Manchester
Regno Unito
Regione
North West (England) Greater Manchester Manchester
Tipo di attività
Higher or Secondary Education Establishments
Collegamenti
Costo totale
Nessun dato