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Silicon/Carbon Nano-Hybrid Lithium-Ion Battery Anode: Green Facile Scalable Synthesis Inspired by Thermosetting Polymers

Objective

The last two decades have witnessed a great commercial success of lithium ion battery (LIB) in portable electronic devices and electric vehicles. However, current LIB technology cannot meet the rapid increasing demand from information technology and vehicle industry, primarily due to limited capacity and serious safety concern of graphite anode. Discovering new anode material with high capacity and good reliability has been a central issue. Because of its high theoretical capacity and excellent operation safety, silicon (Si) has attracted considerable attention as a promising anode to replace graphite. Nevertheless, dramatic volumetric change during lithiation/delithiation process causes severe pulverization and disconnection of electrode from current collector, leading to a fast capacity loss. To tackle these critical problems, a new concept to achieve facile, cost effective, green, and scalable synthesis of Si/carbon nanohybrid anode is proposed. By reducing Si particle size to the range below 10 nm and homogeneous embedding of Si nanoparticles into carbon buffer matrix, the volume change and associated stress can be effectively accommodated to improve the cyclability of the LIBs. Instead of conventional aqueous and/or organic solvents, three industrially widely used thermosetting resin monomer systems including vinyl ester resin, epoxy resin, and phenolic-formaldehyde resin are utilized as both solvent and carbon source. Cost effective silane coupling agents bearing appropriate chemical functional groups act as the precursor of Si and cross-linking agents of the thermosetting polymers. Ultra small Si nanoparticles are in situ formed and homogeneously embedded in the in situ formed porous carbon matrix by sequential photo/thermally induced polymerization, calcination in inert atmosphere, Magnesium thermal reduction, and KOH activation. The mechanism of control over morphology, crystallinity, dispersion, and composition of the Si/C nanohybrid anode and correspondin

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Programme(s)

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

MSCA-IF-EF-ST - Standard EF

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) H2020-MSCA-IF-2014

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Coordinator

THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 195 454,80
Address
WELLINGTON SQUARE UNIVERSITY OFFICES
OX1 2JD Oxford
United Kingdom

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Region
South East (England) Berkshire, Buckinghamshire and Oxfordshire Oxfordshire
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 195 454,80
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