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Molecular 'Click-tronics': Surface-based synthesis of single-molecule electronic components

Objective

How can single-molecules be best utilized in electronics? Feature sizes of integrated circuits will reach this scale in 10-20 years (Moore’s Law). Typical molecular studies involve surface self-assembled components first synthesised elsewhere (ex situ). Yet surface-based (in situ) preparations offer several distinct synthetic advantages – also simplifying the construction of otherwise difficult to prepare asymmetrical surface-bound motifs.

In this project I will (i) explore unconventional in situ syntheses of single-molecule electronic components, and (ii) develop scanning tunnelling microscopy (STM) techniques to assess the success of chemical reactions at the single-molecule scale. High yielding and versatile (e.g. ‘Click’ ) reactions will prove invaluable in this context. My largely unexplored approach will be used to rapidly screen novel single-molecule diodes and wires, improving rectification ratios and conductance. It will also be applied to produce complex molecular ‘test-beds’, allowing electron transport to be probed through single-molecules orientated parallel to the surface (enabling studies of mechanically weak analytes). This research has broad application and far-reaching impact in data storage and computation (‘wiring-up’ molecules in circuits), and will open up exciting possibilities in sensing and catalysis.

Project results, and nano-science in general, will be actively promoted through a series of Outreach workshops, lectures (implemented in Europe) and a new internet blog, ‘Nanotechnology, Translated’ (contributing to the growing international science blogosphere). A planned secondment to the microelectronics industry will provide commercial and technical insights useful for securing funding and developing future technologies over the next two decades. The new collaborations and enhanced international profile, networks and training provided by this Fellowship will ultimately prove pivotal in helping me establish my independent academic career.

Coordinator

UNIVERSITE DE RENNES I
Net EU contribution
€ 246 668,40
Address
Rue Du Thabor 2
35065 Rennes Cedex
France

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Region
Bretagne Bretagne Ille-et-Vilaine
Activity type
Higher or Secondary Education Establishments
Non-EU contribution
€ 0,00

Partners (1)

Partner

Partner organisations contribute to the implementation of the action, but do not sign the Grant Agreement.

TRUSTEES OF COLUMBIA UNIVERSITY IN THE CITY OF NEW YORK
United States
Net EU contribution
€ 0,00
Address
Amsterdam Avenue 1210 Room
10027 7003 New York

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Activity type
Higher or Secondary Education Establishments
Non-EU contribution
€ 160 130,40