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New Directions in Sustainable Catalysis by Metal Complexes

Publications

Manganese Catalyzed Hydrogenation of Carbamates and Urea Derivatives

Author(s): Uttam Kumar Das, Amit Kumar, Yehoshoa Ben-David, Mark A. Iron, David Milstein
Published in: Journal of the American Chemical Society, Issue 141/33, 2019, Page(s) 12962-12966, ISSN 0002-7863
DOI: 10.1021/jacs.9b05591

Dehydrogenative Cross-Coupling of Primary Alcohols To Form Cross-Esters Catalyzed by a Manganese Pincer Complex

Author(s): Uttam Kumar Das, Yehoshoa Ben-David, Gregory Leitus, Yael Diskin-Posner, David Milstein
Published in: ACS Catalysis, Issue 9/1, 2018, Page(s) 479-484, ISSN 2155-5435
DOI: 10.1021/acscatal.8b04585

Oxidation of Alkenes by Water with H 2 Liberation

Author(s): Shan Tang, Yehoshoa Ben-David, David Milstein
Published in: Journal of the American Chemical Society, Issue 142/13, 2020, Page(s) 5980-5984, ISSN 0002-7863
DOI: 10.1021/jacs.0c01592

Metal–Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes

Author(s): Michael Rauch, Sayan Kar, Amit Kumar, Liat Avram, Linda J. W. Shimon, David Milstein
Published in: Journal of the American Chemical Society, Issue 142/34, 2020, Page(s) 14513-14521, ISSN 0002-7863
DOI: 10.1021/jacs.0c05500

Synthesis of oxalamides by acceptorless dehydrogenative coupling of ethylene glycol and amines and the reverse hydrogenation catalyzed by ruthenium

Author(s): You-Quan Zou, Quan-Quan Zhou, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein
Published in: Chemical Science, Issue 11/27, 2020, Page(s) 7188-7193, ISSN 2041-6520
DOI: 10.1039/d0sc02065f

Hydrogenative Depolymerization of Nylons

Author(s): Amit Kumar, Niklas von Wolff, Michael Rauch, You-Quan Zou, Guy Shmul, Yehoshoa Ben-David, Gregory Leitus, Liat Avram, David Milstein
Published in: Journal of the American Chemical Society, Issue 142/33, 2020, Page(s) 14267-14275, ISSN 0002-7863
DOI: 10.1021/jacs.0c05675

Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight

Author(s): Sayan Kar, Michael Rauch, Amit Kumar, Gregory Leitus, Yehoshoa Ben-David, David Milstein
Published in: ACS Catalysis, Issue 10/10, 2020, Page(s) 5511-5515, ISSN 2155-5435
DOI: 10.1021/acscatal.0c01406

Direct Synthesis of Symmetrical Azines from Alcohols and Hydrazine Catalyzed by a Ruthenium Pincer Complex: Effect of Hydrogen Bonding

Author(s): Jonathan O. Bauer, Gregory Leitus, Yehoshoa Ben-David, David Milstein
Published in: ACS Catalysis, Issue 6/12, 2016, Page(s) 8415-8419, ISSN 2155-5435
DOI: 10.1021/acscatal.6b02946

Hydrogenation and Hydrosilylation of Nitrous Oxide Homogeneously Catalyzed by a Metal Complex

Author(s): Rong Zeng, Moran Feller, Yehoshoa Ben-David, David Milstein
Published in: Journal of the American Chemical Society, Issue 139/16, 2017, Page(s) 5720-5723, ISSN 0002-7863
DOI: 10.1021/jacs.7b02124

The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

Author(s): Alexander Dauth, Urs Gellrich, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein
Published in: Journal of the American Chemical Society, Issue 139/7, 2017, Page(s) 2799-2807, ISSN 0002-7863
DOI: 10.1021/jacs.6b13050

Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation

Author(s): You-Quan Zou, Subrata Chakraborty, Alexander Nerush, Dror Oren, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein
Published in: ACS Catalysis, Issue 8/9, 2018, Page(s) 8014-8019, ISSN 2155-5435
DOI: 10.1021/acscatal.8b02902

Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes

Author(s): Arup Mukherjee, David Milstein
Published in: ACS Catalysis, Issue 8/12, 2018, Page(s) 11435-11469, ISSN 2155-5435
DOI: 10.1021/acscatal.8b02869

Metal–Ligand Cooperation as Key in Formation of Dearomatized Ni II –H Pincer Complexes and in Their Reactivity toward CO and CO 2

Author(s): Dror Oren, Yael Diskin-Posner, Liat Avram, Moran Feller, David Milstein
Published in: Organometallics, Issue 37/14, 2018, Page(s) 2217-2221, ISSN 0276-7333
DOI: 10.1021/acs.organomet.8b00160

N-Substituted Hydrazones by Manganese-Catalyzed Coupling of Alcohols with Hydrazine: Borrowing Hydrogen and Acceptorless Dehydrogenation in One System

Author(s): Uttam Kumar Das, Yehoshoa Ben-David, Yael Diskin-Posner, David Milstein
Published in: Angewandte Chemie International Edition, Issue 57/8, 2018, Page(s) 2179-2182, ISSN 1433-7851
DOI: 10.1002/anie.201712593

Direct Synthesis of Benzimidazoles by Dehydrogenative Coupling of Aromatic Diamines and Alcohols Catalyzed by Cobalt

Author(s): Prosenjit Daw, Yehoshoa Ben-David, David Milstein
Published in: ACS Catalysis, Issue 7/11, 2017, Page(s) 7456-7460, ISSN 2155-5435
DOI: 10.1021/acscatal.7b02777

CO 2 activation by metal − ligand-cooperation mediated by iridium pincer complexes

Author(s): Moran Feller, Eyal Ben-Ari, Yael Diskin-Posner, David Milstein
Published in: Journal of Coordination Chemistry, Issue 71/11-13, 2018, Page(s) 1679-1689, ISSN 0095-8972
DOI: 10.1080/00958972.2018.1475662

Formal oxidative addition of a C–H bond by a 16e iridium( i ) complex involves metal–ligand cooperation

Author(s): Amit Kumar, Moran Feller, Yehoshoa Ben-David, Yael Diskin-Posner, David Milstein
Published in: Chemical Communications, Issue 54/42, 2018, Page(s) 5365-5368, ISSN 1359-7345
DOI: 10.1039/c8cc01885e

Imidazole synthesis by transition metal free, base-mediated deaminative coupling of benzylamines and nitriles

Author(s): Uttam Kumar Das, Linda J. W. Shimon, David Milstein
Published in: Chemical Communications, Issue 53/98, 2017, Page(s) 13133-13136, ISSN 1359-7345
DOI: 10.1039/c7cc08322j

Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols

Author(s): Subrata Chakraborty, Uttam Kumar Das, Yehoshoa Ben-David, David Milstein
Published in: Journal of the American Chemical Society, Issue 139/34, 2017, Page(s) 11710-11713, ISSN 0002-7863
DOI: 10.1021/jacs.7b06993

Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols

Author(s): Subrata Chakraborty, Prosenjit Daw, Yehoshoa Ben David, David Milstein
Published in: ACS Catalysis, Issue 8/11, 2018, Page(s) 10300-10305, ISSN 2155-5435
DOI: 10.1021/acscatal.8b03720

Selective Hydrogenation of Nitriles to Secondary Imines Catalyzed by an Iron Pincer Complex

Author(s): Subrata Chakraborty, David Milstein
Published in: ACS Catalysis, Issue 7/6, 2017, Page(s) 3968-3972, ISSN 2155-5435
DOI: 10.1021/acscatal.7b00906

Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier

Author(s): Amit Kumar, Trevor Janes, Noel Angel Espinosa-Jalapa, David Milstein
Published in: Journal of the American Chemical Society, Issue 140/24, 2018, Page(s) 7453-7457, ISSN 0002-7863
DOI: 10.1021/jacs.8b04581

Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex

Author(s): Noel Angel Espinosa-Jalapa, Amit Kumar, Gregory Leitus, Yael Diskin-Posner, David Milstein
Published in: Journal of the American Chemical Society, Issue 139/34, 2017, Page(s) 11722-11725, ISSN 0002-7863
DOI: 10.1021/jacs.7b08341

Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with either Alcohols or Esters: Manganese Pincer Complex as Catalyst

Author(s): Amit Kumar, Noel Angel Espinosa-Jalapa, Gregory Leitus, Yael Diskin-Posner, Liat Avram, David Milstein
Published in: Angewandte Chemie International Edition, Issue 56/47, 2017, Page(s) 14992-14996, ISSN 1433-7851
DOI: 10.1002/anie.201709180

Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols

Author(s): Amit Kumar, Trevor Janes, Noel Angel Espinosa-Jalapa, David Milstein
Published in: Angewandte Chemie International Edition, Issue 57/37, 2018, Page(s) 12076-12080, ISSN 1433-7851
DOI: 10.1002/anie.201806289

Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium

Author(s): Prosenjit Daw, Yehoshoa Ben-David, David Milstein
Published in: Journal of the American Chemical Society, Issue 140/38, 2018, Page(s) 11931-11934, ISSN 0002-7863
DOI: 10.1021/jacs.8b08385

Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese

Author(s): Uttam Kumar Das, Subrata Chakraborty, Yael Diskin-Posner, David Milstein
Published in: Angewandte Chemie International Edition, Issue 57/41, 2018, Page(s) 13444-13448, ISSN 1433-7851
DOI: 10.1002/anie.201807881

Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes

Author(s): Prosenjit Daw, Amit Kumar, Noel Angel Espinosa-Jalapa, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein
Published in: ACS Catalysis, Issue 8/9, 2018, Page(s) 7734-7741, ISSN 2155-5435
DOI: 10.1021/acscatal.8b02208

CO Oxidation by N 2 O Homogeneously Catalyzed by Ruthenium Hydride Pincer Complexes Indicating a New Mechanism

Author(s): Rong Zeng, Moran Feller, Yael Diskin-Posner, Linda J. W. Shimon, Yehoshoa Ben-David, David Milstein
Published in: Journal of the American Chemical Society, Issue 140/23, 2018, Page(s) 7061-7064, ISSN 0002-7863
DOI: 10.1021/jacs.8b03927

Manganese-Catalyzed Direct Deoxygenation of Primary Alcohols

Author(s): Jonathan O. Bauer, Subrata Chakraborty, David Milstein
Published in: ACS Catalysis, Issue 7/7, 2017, Page(s) 4462-4466, ISSN 2155-5435
DOI: 10.1021/acscatal.7b01729

Template catalysis by manganese pincer complexes: oxa- and aza-Michael additions to unsaturated nitriles

Author(s): Shan Tang, David Milstein
Published in: Chemical Science, 2019, ISSN 2041-6520
DOI: 10.1039/c9sc03269j

Ethylene glycol as an efficient and reversible liquid-organic hydrogen carrier

Author(s): You-Quan Zou, Niklas von Wolff, Aviel Anaby, Yinjun Xie, David Milstein
Published in: Nature Catalysis, Issue 2/5, 2019, Page(s) 415-422, ISSN 2520-1158
DOI: 10.1038/s41929-019-0265-z

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides

Author(s): Jie Luo, Michael Rauch, Liat Avram, Yehoshoa Ben-David, David Milstein
Published in: Journal of the American Chemical Society, Issue 142/52, 2020, Page(s) 21628-21633, ISSN 0002-7863
DOI: 10.1021/jacs.0c10884

Catalytic Oxidative Deamination by Water with H 2 Liberation

Author(s): Shan Tang, Michael Rauch, Michael Montag, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein
Published in: Journal of the American Chemical Society, Issue 142/49, 2020, Page(s) 20875-20882, ISSN 0002-7863
DOI: 10.1021/jacs.0c10826