REnewable SOLVEnts with high performance in application and improved toxicity profile

Risultati finali

Report of regulatory human- and environmental safety requirements of solvents in relation to their production volume and use
Report on innovative, cost-effective integrated testing strategy to evaluate toxicological safety issues of candidate solvents established
Report, replacement of NMP and other dipolar aprotic solvents in laboratory scale applications
Report, replacement of toluene in laboratory scale applications
Stakeholder workshop

Stakeholder workshop hosted and corresponding summary document shared with ReSolve partners

Report on labelling requirements for hazard communication and eco-labelling possibilities

Leaflet on the project available
Website up and running

Pubblicazioni

Designing Renewable, High-Performance Solvents with Improved Toxicity Profiles

Autori: James Sherwood, Harrie E. Buist, Bart van der Burg, Fergal P. Byrne, Jason E. Camp, Thomas J. Farmer, E. Dinant Kroese, Marie Y. Meima, David Méndez Sevillano, Ángel Puente, Barbara M. A. van Vugt-Lussenburg, and James H. Clark.
Pubblicato in: Aldrichimica Acta, Numero Vol. 53, No. 2, 2020, Pagina/e 57-63, ISSN 0002-5100
Editore: Aldrich Chemical Co.

Simple and modestly scalable synthesis of iso-Cyrene from levoglucosenone and its comparison to the bio-derived and polar aprotic solvent Cyrene®

Autori: Xin Liu, Brett Pollard, Martin G. Banwell, Li-Juan Yu, Michelle L. Coote, Michael G. Gardiner, Barbara M. A. van Vugt-Lussenburg, Bart van der Burg, Fabien L. Grasset, Elisabeth Campillo, James Sherwood, Fergal Byrne and Thomas J. Farmer
Pubblicato in: Australian Journal of Chemistry, 2022, ISSN 0004-9425
Editore: Commonwealth Scientific and Industrial Research Organization Publishing
DOI: 10.1071/ch22046

Greenness Assessment and Synthesis for the Bio-Based Production of the Solvent 2,2,5,5-Tetramethyloxolane (TMO)

Autori: Fergal P. Byrne, James H. Clark, Carlo Angelici, Ed de Jong, Thomas J. Farmer
Pubblicato in: Sustainable Chemistry, Numero 2/3, 2021, Pagina/e 392-406, ISSN 2673-4079
Editore: MDPI
DOI: 10.3390/suschem2030023

A methodical selection process for the development of ketones and esters as bio-based replacements for traditional hydrocarbon solvents

Autori: Fergal P. Byrne, Bart Forier, Greet Bossaert, Charly Hoebers, Thomas J. Farmer, Andrew J. Hunt
Pubblicato in: Green Chemistry, 2018, ISSN 1463-9262
Editore: Royal Society of Chemistry
DOI: 10.1039/C8GC01132J

Safer bio-based solvents to replace toluene and tetrahydrofuran for the biocatalyzed synthesis of polyesters

Autori: Alessandro Pellis, Fergal P. Byrne, James Sherwood, Marco Vastano, James W. Comerford, Thomas J. Farmer
Pubblicato in: Green Chemistry, 2019, ISSN 1463-9262
Editore: Royal Society of Chemistry
DOI: 10.1039/c8gc03567a

A Method of Calculating the Kamlet–Abboud–Taft Solvatochromic Parameters Using COSMO-RS

Autori: James Sherwood, Joe Granelli, Con R. McElroy, James H. Clark
Pubblicato in: Molecules, Numero 24/12, 2019, Pagina/e 2209, ISSN 1420-3049
Editore: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules24122209

A comparison of the solvation power of the green solvent 2,2,5,5-tetramethyloxolane versus toluene via partition coefficients

Autori: Fergal P. Byrne, William M. Hodds, Seishi Shimizu, Thomas J. Farmer, Andrew J. Hunt
Pubblicato in: Journal of Cleaner Production, Numero 240, 2019, Pagina/e 118175, ISSN 0959-6526
Editore: Elsevier BV
DOI: 10.1016/j.jclepro.2019.118175

Suzuki–Miyaura cross coupling is not an informative reaction to demonstrate the performance of new solvents

Autori: James Sherwood
Pubblicato in: Beilstein Journal of Organic Chemistry, Numero 16, 2020, Pagina/e 1001-1005, ISSN 1860-5397
Editore: Beilstein-Institut
DOI: 10.3762/bjoc.16.89

A Family of Water‐Immiscible, Dipolar Aprotic, Diamide Solvents from Succinic Acid

Autori: Fergal P. Byrne, Clara M. Nussbaumer, Elise J. Savin, Roxana A. Milescu, Con R. McElroy, James H. Clark, Barbara M. A. Vugt‐Lussenburg, Bart Burg, Marie Y. Meima, Harrie E. Buist, E. Dinant Kroese, Andrew J. Hunt, Thomas J. Farmer
Pubblicato in: ChemSusChem, Numero 13/12, 2020, Pagina/e 3212-3221, ISSN 1864-5631
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202000462

Catalyst: Possible Consequences of the N-Methyl Pyrrolidone REACH Restriction

Autori: James Sherwood, Thomas J. Farmer, James H. Clark
Pubblicato in: Chem, Numero 4/9, 2018, Pagina/e 2010-2012, ISSN 2451-9294
Editore: Cell Press
DOI: 10.1016/j.chempr.2018.08.035

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