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Efficient Structures and Processes for Reliable Perovskite Solar Modules

Deliverables

Final press release and public project report

A press release and public project report will be produced at the end of the project to disseminate research results raising broader public and governmental awareness

Project identity set and website created

A Project Identity Set will be created including the creation of a logo, a brochure, a slide template. A public project website will be used to communicate up-to-date information relating to the project, updated on a regular basis and at least every 3 months.

Public day event organised

Public day event will be organised as part of the project workshop. Leading organisations and persons of market analysts, standardization committees, process developer and equipment manufacturers, architects and designers will be invited. Current ESPResSo results and prototypes will be presented and discussed with these experts

Model of perovskite growth from solution

Hybrid DFT calculations including spin-orbit coupling (SOC) will be used to describe how defects ensuing from the perovskite growth will impact the optoelectronic quality of the ensuing materials

Outdoor testing protocols of PSC modules described and validated, available to broader scientific community

Outdoor testing protocols of PSC modules described and validated available to broader scientific community

Demonstration of PSC technology in a BIPV façade element

PSC technology in a BIPV faade element is available for demonstration at outdoor location and inuse performance data gathering can be started

2nd workshop organized

Workshop to let the scientific community know about advances within our project as side event of main conference to maximize the visibility of the project outcomes

1st workshop organized

Workshop to let the scientific community know about advances within our project, as side event of main conference to maximize the visibility of the project outcomes

PCE of 12% for hexagonal and leaf-shaped flexible perovskite photovoltaic module on substrate area of 10x10 cm²

PCE of 12 for hexagonal and leafshaped flexible perovskite photovoltaic module on substrate area of 10x10 cm

Large area (35x35cm²) PSC module fabricated with OSI process, with full loss analysis compared with conventionally interconnected modules

Large area 35x35cm PSC module fabricated with OSI process with full loss analysiscompared with conventionally interconnected modules

Large area (35x35cm²) PSC module fabricated with efficiency >17% on aperture area

Large area 35x35cm PSC module fabricated with efficiency 17 on aperture area

Optimization of the mechanical assembly of semi-transparent PSC module on top of cSi cell to ensure higher PCE is obtained for this assembly compared with cSi cell alone

Optimization of the mechanical assembly of semitransparent PSC module on top of cSi cell to ensure higher PCE is obtained for this assembly compared with cSi cell alone

Cell with PCE ≥24% (1cm²), with hysteresis ≤10%

Cell with PCE 24 1cm with hysteresis 10

Device operation modelled of highest potential device architecture to yield PCE ≥24% (1cm²), with hysteresis ≤10%

Device operation modelled of highest potential device architecture to yield PCE 24 1cm with hysteresis 10

Model of defects at HTL/ETL for new perovskites at novel contacts

Model of defects at HTLETL as developed in D15 updated for new perovskites at novelContacts

Publications

Improving the Morphology Stability of Spiro-OMeTAD Films for Enhanced Thermal Stability of Perovskite Solar Cells

Author(s): Wenya Song1,2*, Lucija Rakocevic1,2, Raghavendran Thiruvallur Eachambadi3, Weiming Qiu2,4, João P. Bastos4, Robert Gehlhaar4, Yinghuan Kuang1, Afshin Hadipour1, Tom Aernouts1, Jef Poortmans
Published in: ACS Appl. Mater. Interfaces, 2019, ISSN 1944-8252
Publisher: ACS
DOI: 10.1021/acsami.1c11227

An integrated bulk and surface modification strategy for gas-quenched inverted perovskite solar cells with efficiencies exceeding 22%

Author(s): Xin Zhang, Weiming Qiu*, Wenya Song, Zafer Hawash, Yaxin Wang, Bapi Pradhan, Yiyue Zhang, Denys Naumenko, Heinz Amenitsch, Ellen Moons, Tamara Merckx, Aranzazu Aguirre, Yaser Abdulraheem, Tom Aernouts, Yiqiang Zhan*, Yinghuan Kuang*, Johan Hofkens, Jef Poortmans*
Published in: Solar RRL, 2022, ISSN 2367-198X
Publisher: Wiley
DOI: 10.1002/solr.202200053

Loss Analysis in Perovskite Photovoltaic Modules

Author(s): Lucija Rakocevic, Laura E. Mundt, Robert Gehlhaar, Tamara Merckx, Tom Aernouts, Martin C. Schubert, Stefan W. Glunz, Jef Poortmans
Published in: Solar RRL, 2019, Page(s) 1900338, ISSN 2367-198X
Publisher: Wiley
DOI: 10.1002/solr.201900338

Environmental Profile of the Manufacturing Process of Perovskite Photovoltaics: Harmonization of Life Cycle Assessment Studies

Author(s): Simone Maranghi, Maria Laura Parisi, Riccardo Basosi, Adalgisa Sinicropi
Published in: Energies, Issue 12/19, 2019, Page(s) 3746, ISSN 1996-1073
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/en12193746

Energy Level Tuning at the MAPbI 3 Perovskite/Contact Interface Using Chemical Treatment

Author(s): Daniele Meggiolaro, Edoardo Mosconi, Andrew H. Proppe, Rafael Quintero-Bermudez, Shana O. Kelley, Edward H. Sargent, Filippo De Angelis
Published in: ACS Energy Letters, Issue 4/9, 2019, Page(s) 2181-2184, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/acsenergylett.9b01584

Understanding the Solution Chemistry of Lead Halide Perovskites Precursors

Author(s): Eros Radicchi, Edoardo Mosconi, Fausto Elisei, Francesca Nunzi, Filippo De Angelis
Published in: ACS Applied Energy Materials, Issue 2/5, 2019, Page(s) 3400-3409, ISSN 2574-0962
Publisher: American Chemical Society
DOI: 10.1021/acsaem.9b00206

Charge Localization, Stabilization, and Hopping in Lead Halide Perovskites: Competition between Polaron Stabilization and Cation Disorder

Author(s): Francesco Ambrosio, Daniele Meggiolaro, Edoardo Mosconi, Filippo De Angelis
Published in: ACS Energy Letters, Issue 4/8, 2019, Page(s) 2013-2020, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/acsenergylett.9b01353

Rationalizing the Molecular Design of Hole‐Selective Contacts to Improve Charge Extraction in Perovskite Solar Cells

Author(s): Qiong Wang, Edoardo Mosconi, Christian Wolff, Junming Li, Dieter Neher, Filippo De Angelis, Gian Paolo Suranna, Roberto Grisorio, Antonio Abate
Published in: Advanced Energy Materials, Issue 9/28, 2019, Page(s) 1900990, ISSN 1614-6832
Publisher: Wiley-VCH Verlag
DOI: 10.1002/aenm.201900990

Stabilizing halide perovskite surfaces for solar cell operation with wide-bandgap lead oxysalts

Author(s): Shuang Yang, Shangshang Chen, Edoardo Mosconi, Yanjun Fang, Xun Xiao, Congcong Wang, Yu Zhou, Zhenhua Yu, Jingjing Zhao, Yongli Gao, Filippo De Angelis, Jinsong Huang
Published in: Science, Issue 365/6452, 2019, Page(s) 473-478, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.aax3294

Charge Carriers Are Not Affected by the Relatively Slow-Rotating Methylammonium Cations in Lead Halide Perovskite Thin Films

Author(s): Valentina M. Caselli, Mathias Fischer, Daniele Meggiolaro, Edoardo Mosconi, Filippo De Angelis, Samuel D. Stranks, Andreas Baumann, Vladimir Dyakonov, Eline M. Hutter, Tom J. Savenije
Published in: The Journal of Physical Chemistry Letters, Issue 10/17, 2019, Page(s) 5128-5134, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.9b02160

Electrochemical Hole Injection Selectively Expels Iodide from Mixed Halide Perovskite Films

Author(s): Gergely F. Samu, Ádám Balog, Filippo De Angelis, Daniele Meggiolaro, Prashant V. Kamat, Csaba Janáky
Published in: Journal of the American Chemical Society, Issue 141/27, 2019, Page(s) 10812-10820, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b04568

The nature of the lead-iodine bond in PbI2: A case study for the modelling of lead halide perovskites

Author(s): Costanza Borghesi, Eros Radicchi, Leonardo Belpassi, Daniele Meggiolaro, Filippo De Angelis, Francesca Nunzi
Published in: Computational and Theoretical Chemistry, Issue 1164, 2019, Page(s) 112558, ISSN 2210-271X
Publisher: Elsevier BV
DOI: 10.1016/j.comptc.2019.112558

Formation of Surface Defects Dominates Ion Migration in Lead-Halide Perovskites

Author(s): Daniele Meggiolaro, Edoardo Mosconi, Filippo De Angelis
Published in: ACS Energy Letters, Issue 4/3, 2019, Page(s) 779-785, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/acsenergylett.9b00247

Ligand-Induced Surface Charge Density Modulation Generates Local Type-II Band Alignment in Reduced-Dimensional Perovskites

Author(s): Rafael Quintero-Bermudez, Andrew H. Proppe, Arup Mahata, Petar Todorović́, Shana O. Kelley, Filippo De Angelis, Edward H. Sargent
Published in: Journal of the American Chemical Society, Issue 141/34, 2019, Page(s) 13459-13467, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b04801

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