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Novel Dinuclear Late Transition Metal Catalysts for CO2/Olefin and CO2/Epoxide/Olefin Copolymerization

Objective

Polyolefins are the most produced class of polymers every year (>130 million tons in 2015). Despite intensive research and development in this field over the past 50 years, both in academia and in industry, the synthesis of polar polyolefin copolymers remains challenging. These copolymers are highly desirable, most notably as compatibilizing agent in polymer blends. The COOLEFIN proposal is aiming to develop a sustainable alternative method to synthesise polar polyolefin from CO2/olefin and olefin/CO2/epoxide copolymerization - two challenging reactions still under explored. These new materials will reduce the use of petrochemically derived starting monomers and open a new field of sophisticated materials with unique properties. The COOLEFIN objectives are i) the synthesis and characterization of a new family of dinuclear late transition metal catalysts; ii) testing the series of catalysts for CO2/olefin and olefin/CO2/epoxide copolymerization; iii) physical characterization of the produced polymers; iv) kinetic and mechanistic studies of the polymerization reactions; v) optimization of the reactions conditions and scale up. The COOLEFIN action proposes a multidisciplinary research project on the frontier between inorganic, catalysis and materials chemistry, providing an optimum training experience and transfer of knowledge between all parties during both phases. In addition, the high impact of the study will be both of academic and industrial interest. It will put light to i) mechanism/rate of simple organometallic reactions (CO2/ethylene insertion); ii) the requirements for a good catalyst to perform these two polymerization reactions; iii) the link between the polymer micro/macrostructure and its physical properties to target specific applications. This project is a value added effort to bring two excellent polymerization concepts to the frontier of polymer catalysis research, which has never been given proper attention, despite being extremely promising.

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Keywords

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Programme(s)

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Topic(s)

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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) H2020-MSCA-IF-2017

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Coordinator

UNIVERSITAT KONSTANZ
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 219 844,50
Address
UNIVERSITATSSTRASSE 10
78464 Konstanz
Germany

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Region
Baden-Württemberg Freiburg Konstanz
Activity type
Higher or Secondary Education Establishments
Links
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 219 844,50

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