Metal-Organic Cages for Catalysis Applications

Informazioni relative al progetto

MOCCA

ID dell’accordo di sovvenzione: 798103

DOI

10.3030/798103

Progetto chiuso

Data della firma CE 28 Marzo 2018

Data di avvio 1 Maggio 2018

Data di completamento 30 Aprile 2020

Finanziato da

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Costo totale

€ 171 460,80

Contributo UE

€ 171 460,80

Coordinato da

TECHNISCHE UNIVERSITAT DORTMUND
Germany

Periodic Reporting for period 1 - MOCCA (Metal-Organic Cages for Catalysis Applications)

Periodo di rendicontazione: 2018-05-01 al 2020-04-30

Sintesi del contesto e degli obiettivi generali del progetto

The main focus of this project was the design, synthesis and characterization of metal-organic cages (MOCs) containing photosensitizing units and catalysts. These systems should be used as photocatalysts for light-driven reactions such as CO2-reduction.

The design of novel catalysts that are powered by light is of high importance for the society. Light is a clean reactant that is highly abundant and can be applied selectively by choosing the specific wavelength needed for the activation of a chemical bond. Metal-mediated assembly of coordination cages allows the construction supramolecular objects with multiple different functional building blocks. This way, the two components needed for photochemical conversions (photosensitizer + catalyst) are brought together, enabling more efficient cooperation between them.

The main objectives of MOCCA were:
- Synthesis of suitable organic and transition-metal-based building blocks
- Assembly of coordination cages with Pd(II) cations or other metals as mediators
- Testing the feasibility of the resulting systems as catalysts in photochemical reactions

In the section below it will be described what the project has contributed so far to these issues.

Lavoro eseguito dall’inizio del progetto fino alla fine del periodo coperto dalla relazione e principali risultati finora ottenuti

In a perspective article with the title: “Mixed-Ligand Metal–Organic Frameworks and Heteroleptic Coordination Cages as Multifunctional Scaffolds - A Comparison”, synthetic strategies to obtain heteroleptic coordination cages were compared with the preparation of multifunctional metal-organic frameworks. This article forms the basis for the experimental studies performed in MOCCA, where the preparation of coordination cages with photosensitizers and catalysts as ligands was tested. This perspective article was published here:

Pullen and G. H. Clever, Acc. Chem. Res., 2018, 51, 3052

In addition to this perspective, an review article as well a book chapter on similar topics have been produced and are currently under review.

A first experimental study has been published: An interpenetrated coordination cage of the formula [Pd4L8] containing organic photosensitizers as ligands (= L) that are assembled with Pd(II) cations was prepared. Its ability to photosensitize the generation of singlet oxygen was demonstrated. Singlet oxygen is used as a reagent in i.e. drug synthesis. This study has been published here:

S. Pullen, S. Löffler, A. Platzek, J. J. Holstein and G. H. Clever, Dalton Trans., 2020, DOI:10.1039/d0dt01674h

The main focus of MOCCA was the synthesis and assembly of ligands containing catalysts and photosensitizers that can be used for photochemical CO2 reduction.
Several of such ligands and cages have been prepared and functional studies are currently ongoing. We expect to be able to publish these results in near future.

Progressi oltre lo stato dell’arte e potenziale impatto previsto (incluso l’impatto socioeconomico e le implicazioni sociali più ampie del progetto fino ad ora)

So far MOCCA has resulted in two publications. In addition to this, a book chapter and a review article have been written and will be published soon.
Furthermore, several unpublished results have been produced. These studies will be continued and ultimately lead to at least two more publications.

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