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Building Precise Molecular Architectures to Unlock Remarkable f-Element Properties

Deliverables

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Publications

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

Author(s): Conrad A. P. Goodwin, Benjamin L. L. Réant, Gianni F. Vettese, Jon G. C. Kragskow, Marcus J. Giansiracusa, Ida M. DiMucci, Kyle M. Lancaster, David P. Mills, Stephen Sproules
Published in: Inorganic Chemistry, 59/11, 2020, Page(s) 7571-7583, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c00470

Practical and Selective sp3 C−H Bond Chlorination via Aminium Radicals

Author(s): A. J. McMillan, M. Sienkowska, P. Di Lorenzo, G. K. Gransbury, N. F. Chilton, M. Salamone, A. Ruffoni, M. Bietti, D. Leonori
Published in: Angewandte Chemie - International Edition, 60, 2021, Page(s) 7132-7139, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202100030

Polarised covalent thorium( iv )– and uranium( iv )–silicon bonds

Author(s): Benjamin L. L. Réant, Victoria E. J. Berryman, John A. Seed, Annabel R. Basford, Alasdair Formanuik, Ashley J. Wooles, Nikolas Kaltsoyannis, Stephen T. Liddle, David P. Mills
Published in: Chemical Communications, 56/83, 2020, Page(s) 12620-12623, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc06044e

Isolation and electronic structures of derivatized manganocene, ferrocene and cobaltocene anions

Author(s): Conrad A. P. Goodwin, Marcus J. Giansiracusa, Samuel M. Greer, Hannah M. Nicholas, Peter Evans, Michele Vonci, Stephen Hill, Nicholas F. Chilton, David P. Mills
Published in: Nature Chemistry, 13/3, 2021, Page(s) 243-248, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-020-00595-w

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

Author(s): Vijay S. Parmar, David P. Mills, Richard E. P. Winpenny
Published in: Chemistry – A European Journal, 2021, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202100085

Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

Author(s): Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Published in: Dalton Transactions, 49/19, 2020, Page(s) 6504-6511, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt01241f

Slow magnetic relaxation in distorted tetrahedral Dy(III) aryloxide complexes.

Author(s): Vijay S. Parmar; Gemma K. Gransbury; George F. S. Whitehead; David P. Mills; Richard E. P. Winpenny
Published in: ChemComm, 57, 2021, Page(s) 9208-9211, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc02707g

Synthesis of heteroleptic yttrium and dysprosium 1,2,4-tris(trimethylsilyl)cyclopentadienyl complexes

Author(s): S. C. Corner, C. A. P. Goodwin, F. Ortu, P. Evans, H. Zhang, G. K. Gransbury, G. F. S. Whitehead, D. P. Mills
Published in: Australian Journal of Chemistry, 2022, ISSN 0004-9425
Publisher: Commonwealth Scientific and Industrial Research Organization Publishing
DOI: 10.1071/ch21314

f‐Block Phospholyl and Arsolyl Chemistry

Author(s): David P. Mills, Peter Evans
Published in: Chemistry – A European Journal, 2021, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202005231

f-Element silicon and heavy tetrel chemistry

Author(s): Benjamin L. L. Réant, Stephen T. Liddle, David P. Mills
Published in: Chemical Science, 11/40, 2020, Page(s) 10871-10886, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc04655h