Building Precise Molecular Architectures to Unlock Remarkable f-Element Properties

Project Information

F-ELEMENT_ARCHITECT

Grant agreement ID: 816268

DOI 10.3030/816268

EC signature date 25 February 2019

Start date 1 September 2019

End date 31 May 2025

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 990 800,93

EU contribution € 1 990 800,93

Coordinated by

THE UNIVERSITY OF MANCHESTER
United Kingdom

Deliverables

Open Research Data Pilot (1)

Data Management Plan (DMP)

Produce Data Management Plan

Publications

Peer reviewed articles (25)

Mononuclear Dysprosium Alkoxide and Aryloxide Single-Molecule Magnets.

Author(s): Vijay S. Parmar; David P. Mills; Richard E. P. Winpenny
Published in: Chemistry A European Journal, Issue 6, 2021, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202100085

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

Author(s): Conrad A. P. Goodwin, Benjamin L. L. Réant, Gianni F. Vettese, Jon G. C. Kragskow, Marcus J. Giansiracusa, Ida M. DiMucci, Kyle M. Lancaster, David P. Mills, Stephen Sproules
Published in: Inorganic Chemistry, Issue 59/11, 2020, Page(s) 7571-7583, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c00470

Isolation of a Bent Dysprosium Bis(amide) Single-Molecule Magnet

Author(s): Jack Emerson-King; Gemma K. Gransbury; George F. S. Whitehead; Iñigo J. Vitorica-Yrezabal; Mathieu Rouzières; Rodolphe Clérac; Nicholas F. Chilton; David P. Mills
Published in: Journal of the American Chemical Society, Issue 10, 2024, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c12427

Measurement of the Quantum Tunneling Gap in a Dysprosocenium Single-Molecule Magnet

Author(s): Blackmore, William J. A.; Mattioni, Andrea; Corner, Sophie C.; Evans, Peter; Gransbury, Gemma K.; Mills, David P.; Chilton, Nicholas F.
Published in: Journal of Physical Chemistry Letters, Issue 6, 2023, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.3c00034

Metal–carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy

Author(s): Lydia E. Nodaraki; Jingjing Liu; Ana-Maria Ariciu; Fabrizio Ortu; Meagan S. Oakley; Letitia Birnoschi; Gemma K. Gransbury; Philip J. Cobb; Jack Emerson-King; Nicholas F. Chilton; David P. Mills; Eric J. L. McInnes; Floriana Tuna
Published in: Chemical Science, Issue 10, 2024, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc06175b

Practical and Selective sp3 C−H Bond Chlorination via Aminium Radicals

Author(s): A. J. McMillan, M. Sienkowska, P. Di Lorenzo, G. K. Gransbury, N. F. Chilton, M. Salamone, A. Ruffoni, M. Bietti, D. Leonori
Published in: Angewandte Chemie - International Edition, Issue 60, 2021, Page(s) 7132-7139, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202100030

Characterisation of magnetic relaxation on extremely long timescales

Author(s): William J. A. Blackmore; Gemma K. Gransbury; Peter Evans; Jon G. C. Kragskow; David P. Mills; Nicholas F. Chilton
Published in: Physical Chemistry Chemical Physics, Issue 7, 2023, ISSN 1463-9084
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3cp01278f

Polarised covalent thorium( iv )– and uranium( iv )–silicon bonds

Author(s): Benjamin L. L. Réant, Victoria E. J. Berryman, John A. Seed, Annabel R. Basford, Alasdair Formanuik, Ashley J. Wooles, Nikolas Kaltsoyannis, Stephen T. Liddle, David P. Mills
Published in: Chemical Communications, Issue 56/83, 2020, Page(s) 12620-12623, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc06044e

Isolation and electronic structures of derivatized manganocene, ferrocene and cobaltocene anions

Author(s): Conrad A. P. Goodwin, Marcus J. Giansiracusa, Samuel M. Greer, Hannah M. Nicholas, Peter Evans, Michele Vonci, Stephen Hill, Nicholas F. Chilton, David P. Mills
Published in: Nature Chemistry, Issue 13/3, 2021, Page(s) 243-248, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-020-00595-w

Electronic structure comparisons of isostructural early d- and f-block metal(<scp>iii</scp>) bis(cyclopentadienyl) silanide complexes

Author(s): Gemma K. Gransbury; Benjamin L. L. Réant; Ashley J. Wooles; Jack Emerson-King; Nicholas F. Chilton; Stephen T. Liddle; David P. Mills
Published in: Chemical Science, Issue 9, 2023, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc04526e

Synthesis and Characterization of Yttrium Methanediide Silanide Complexes

Author(s): Benjamin L. L. Réant; Ashley J. Wooles; Stephen T. Liddle; David P. Mills
Published in: Inorganic Chemistry, Issue 6, 2023, ISSN 1521-3765
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.2c03053

Thermally stable Terbium(II) and Dysprosium(II) Bis-Amidinate Single-Molecule Magnets

Author(s): Peng-Bo Jin; Qian-Cheng Luo; Gemma Gransbury; Iñigo Vitorica-Yrezabal; Tomáš Hajdu; Eric McInnes; Richard Winpenny; Nicholas Chilton; David Mills; Yan-Zhen Zheng
Published in: Journal of the American Chemical Society, Issue 10, 2023, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c07978

Controlling Spin Crossover in a Family of Dinuclear Fe(III) Complexes via the Bis(catecholate) Bridging Ligand

Author(s): Jett T. Janetzki; Maxim G. Chegerev; Gemma K. Gransbury; Robert W. Gable; Jack K. Clegg; Roger J. Mulder; Guy N. L. Jameson; Alyona A. Starikova; Colette Boskovic
Published in: Inorganic Chemistry, Issue 8, 2023, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c02598

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

Author(s): Vijay S. Parmar, David P. Mills, Richard E. P. Winpenny
Published in: Chemistry – A European Journal, 2021, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202100085

Non‐Classical Early Lanthanide(II) Tris(di‐tert‐butylcyclopentadienyl) Complexes**

Author(s): Jingjing Liu; Lydia E. Nodaraki; Daniel O. T. A. Martins; Marcus J. Giansiracusa; Philip J. Cobb; Jack Emerson‐King; Fabrizio Ortu; George F. S. Whitehead; Gemma K. Gransbury; Eric J. L. Mclnnes; Floriana Tuna; David P. Mills
Published in: European Journal of Inorganic Chemistry, Issue 3, 2023, ISSN 1099-0682
Publisher: Wiley-VCH
DOI: 10.1002/ejic.202300552

Influence of pressure on a dysprosocenium single-molecule magnet

Author(s): Vijay S. Parmar; Andreas M. Thiel; Rizwan Nabi; Gemma K. Gransbury; Marie S. Norre; Peter Evans; Sophie C. Corner; Jonathan M. Skelton; Nicholas F. Chilton; David P. Mills; Jacob Overgaard
Published in: Chemical Communications, Issue 6, 2023, ISSN 1521-3765
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc06722f

Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

Author(s): Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Published in: Dalton Transactions, Issue 49/19, 2020, Page(s) 6504-6511, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0dt01241f

Slow magnetic relaxation in distorted tetrahedral Dy(III) aryloxide complexes.

Author(s): Vijay S. Parmar; Gemma K. Gransbury; George F. S. Whitehead; David P. Mills; Richard E. P. Winpenny
Published in: ChemComm, Issue 57, 2021, Page(s) 9208-9211, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc02707g

Comparison of group 4 and thorium M(<scp>iv</scp>) substituted cyclopentadienyl silanide complexes

Author(s): Benjamin L. L. Réant; Dukula De Alwis Jayasinghe; Ashley J. Wooles; Stephen T. Liddle; David P. Mills
Published in: Dalton Transactions, Issue 8, 2023, ISSN 1477-9234
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3dt00987d

Metallocene Anions: From Electrochemical Curiosities to Isolable Complexes

Author(s): Corentin Magnoux; David P. Mills
Published in: European Journal of Inorganic Chemistry, Issue 3, 2022, ISSN 1099-0682
Publisher: Wiley-VCH
DOI: 10.1002/ejic.202101063

f-Block Phospholyl and Arsolyl Chemistry.

Author(s): Mills, David P.; Evans, Peter
Published in: Chemistry A European Journal, Issue 5, 2021, ISSN 1521-3765
Publisher: Wiley-VCH
DOI: 10.1002/chem.202005231

Synthesis of heteroleptic yttrium and dysprosium 1,2,4-tris(trimethylsilyl)cyclopentadienyl complexes

Author(s): S. C. Corner, C. A. P. Goodwin, F. Ortu, P. Evans, H. Zhang, G. K. Gransbury, G. F. S. Whitehead, D. P. Mills
Published in: Australian Journal of Chemistry, 2022, ISSN 0004-9425
Publisher: Commonwealth Scientific and Industrial Research Organization Publishing
DOI: 10.1071/ch21314

f‐Block Phospholyl and Arsolyl Chemistry

Author(s): David P. Mills, Peter Evans
Published in: Chemistry – A European Journal, 2021, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202005231

f-Element silicon and heavy tetrel chemistry

Author(s): Benjamin L. L. Réant, Stephen T. Liddle, David P. Mills
Published in: Chemical Science, Issue 11/40, 2020, Page(s) 10871-10886, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc04655h

AtomAccess: A Predictive Tool for Molecular Design and Its Application to the Targeted Synthesis of Dysprosium Single-Molecule Magnets

Author(s): Gemma K. Gransbury; Sophie C. Corner; Jon G. C. Kragskow; Peter Evans; Hing Man Yeung; William J. A. Blackmore; George F. S. Whitehead; Iñigo J. Vitorica-Yrezabal; Meagan S. Oakley; Nicholas F. Chilton; David P. Mills
Published in: Journal of the American Chemical Society, Issue 8, 2023, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c08841