Building Precise Molecular Architectures to Unlock Remarkable f-Element Properties

Informazioni relative al progetto

F-ELEMENT_ARCHITECT

ID dell’accordo di sovvenzione: 816268

DOI

10.3030/816268

Progetto chiuso

Data della firma CE 25 Febbraio 2019

Data di avvio 1 Settembre 2019

Data di completamento 31 Maggio 2025

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale

€ 1 990 800,93

Contributo UE

€ 1 990 800,93

Coordinato da

THE UNIVERSITY OF MANCHESTER
United Kingdom

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Risultati finali

Open Research Data Pilot (1)

Data Management Plan (DMP)

Produce Data Management Plan

Pubblicazioni

Peer reviewed articles (39)

Synthesis and characterization of solvated lanthanide(II) bis(triisopropylsilyl)phosphide complexes

Autori: Jack Baldwin, Adam Brookfield, George Whitehead, Louise Natrajan, Eric McInnes, Meagan Oakley, David Mills
Pubblicato in: Inorganic Chemistry, Numero 63, 2024, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.26434/chemrxiv-2024-3m17t

Mononuclear Dysprosium Alkoxide and Aryloxide Single-Molecule Magnets.

Autori: Vijay S. Parmar; David P. Mills; Richard E. P. Winpenny
Pubblicato in: Chemistry A European Journal, Numero 6, 2021, ISSN 1521-3765
Editore: Wiley-VCH
DOI: 10.1002/chem.202100085

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

Autori: Conrad A. P. Goodwin, Benjamin L. L. Réant, Gianni F. Vettese, Jon G. C. Kragskow, Marcus J. Giansiracusa, Ida M. DiMucci, Kyle M. Lancaster, David P. Mills, Stephen Sproules
Pubblicato in: Inorganic Chemistry, Numero 59/11, 2020, Pagina/e 7571-7583, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c00470

Direct characterisation of <i>m</i>_<i>J</i> = ±15/2 ground state in octahedral Dy(<scp>iii</scp>) single-molecule magnets

Autori: Vijay S. Parmar, Gemma K. Gransbury, Sophie C. Corner, Wei-Hao Chou, Stephen Hill, Richard E. P. Winpenny, Nicholas F. Chilton, David P. Mills
Pubblicato in: Dalton Transactions, Numero 54, 2025, Pagina/e 7616-7620, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d5dt00862j

Isolation of a Bent Dysprosium Bis(amide) Single-Molecule Magnet

Autori: Jack Emerson-King; Gemma K. Gransbury; George F. S. Whitehead; Iñigo J. Vitorica-Yrezabal; Mathieu Rouzières; Rodolphe Clérac; Nicholas F. Chilton; David P. Mills
Pubblicato in: Journal of the American Chemical Society, Numero 10, 2024, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.3c12427

Soft magnetic hysteresis in a dysprosium amide–alkene complex up to 100 kelvin

Autori: Jack Emerson-King, Gemma K. Gransbury, Benjamin E. Atkinson, William J. A. Blackmore, George F. S. Whitehead, Nicholas F. Chilton, David P. Mills
Pubblicato in: Nature, Numero 643, 2025, Pagina/e 125-129, ISSN 0028-0836
Editore: Nature Publishing Group
DOI: 10.1038/s41586-025-09138-0

Measurement of the Quantum Tunneling Gap in a Dysprosocenium Single-Molecule Magnet

Autori: Blackmore, William J. A.; Mattioni, Andrea; Corner, Sophie C.; Evans, Peter; Gransbury, Gemma K.; Mills, David P.; Chilton, Nicholas F.
Pubblicato in: Journal of Physical Chemistry Letters, Numero 6, 2023, ISSN 1948-7185
Editore: American Chemical Society
DOI: 10.1021/acs.jpclett.3c00034

Trigonal Planar Heteroleptic Lanthanide(III) Bis(silyl)amide Complexes Containing Aminoxyl Radicals and Anions

Autori: Gemma K. Gransbury, Hannah M. Nicholas, Siobhan R. Murphy, Jack Emerson-King, Michele Vonci, Conrad A. P. Goodwin, Richard E. P. Winpenny, Nicholas F. Chilton, Marcus J. Giansiracusa, David P. Mills
Pubblicato in: Inorganic Chemistry, Numero 63, 2024, Pagina/e 22422-22434, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c03281

Influence of weakly coordinating anions binding to the hexa-<i>tert</i>-butyl dysprosocenium cation

Autori: Sophie C. Corner, Gemma K. Gransbury, David P. Mills
Pubblicato in: Dalton Transactions, Numero 54, 2024, Pagina/e 198-206, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d4dt02713b

Metal–carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy

Autori: Lydia E. Nodaraki; Jingjing Liu; Ana-Maria Ariciu; Fabrizio Ortu; Meagan S. Oakley; Letitia Birnoschi; Gemma K. Gransbury; Philip J. Cobb; Jack Emerson-King; Nicholas F. Chilton; David P. Mills; Eric J. L. McInnes; Floriana Tuna
Pubblicato in: Chemical Science, Numero 10, 2024, ISSN 2041-6539
Editore: Royal Society of Chemistry
DOI: 10.1039/d3sc06175b

Practical and Selective sp3 C−H Bond Chlorination via Aminium Radicals

Autori: A. J. McMillan, M. Sienkowska, P. Di Lorenzo, G. K. Gransbury, N. F. Chilton, M. Salamone, A. Ruffoni, M. Bietti, D. Leonori
Pubblicato in: Angewandte Chemie - International Edition, Numero 60, 2021, Pagina/e 7132-7139, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202100030

Rare earth benzene tetraanion-bridged amidinate complexes

Autori: Peng-Bo Jin, Qian-Cheng Luo, Gemma K. Gransbury, Richard E. P. Winpenny, David P. Mills, Yan-Zhen Zheng
Pubblicato in: Chemical Science, Numero 16, 2025, Pagina/e 1907-1924, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d4sc05982d

Characterisation of magnetic relaxation on extremely long timescales

Autori: William J. A. Blackmore; Gemma K. Gransbury; Peter Evans; Jon G. C. Kragskow; David P. Mills; Nicholas F. Chilton
Pubblicato in: Physical Chemistry Chemical Physics, Numero 7, 2023, ISSN 1463-9084
Editore: Royal Society of Chemistry
DOI: 10.1039/d3cp01278f

Polarised covalent thorium( iv )– and uranium( iv )–silicon bonds

Autori: Benjamin L. L. Réant, Victoria E. J. Berryman, John A. Seed, Annabel R. Basford, Alasdair Formanuik, Ashley J. Wooles, Nikolas Kaltsoyannis, Stephen T. Liddle, David P. Mills
Pubblicato in: Chemical Communications, Numero 56/83, 2020, Pagina/e 12620-12623, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/d0cc06044e

Isolation and electronic structures of derivatized manganocene, ferrocene and cobaltocene anions

Autori: Conrad A. P. Goodwin, Marcus J. Giansiracusa, Samuel M. Greer, Hannah M. Nicholas, Peter Evans, Michele Vonci, Stephen Hill, Nicholas F. Chilton, David P. Mills
Pubblicato in: Nature Chemistry, Numero 13/3, 2021, Pagina/e 243-248, ISSN 1755-4330
Editore: Nature Publishing Group
DOI: 10.1038/s41557-020-00595-w

Electronic structure comparisons of isostructural early d- and f-block metal(<scp>iii</scp>) bis(cyclopentadienyl) silanide complexes

Autori: Gemma K. Gransbury; Benjamin L. L. Réant; Ashley J. Wooles; Jack Emerson-King; Nicholas F. Chilton; Stephen T. Liddle; David P. Mills
Pubblicato in: Chemical Science, Numero 9, 2023, ISSN 2041-6539
Editore: Royal Society of Chemistry
DOI: 10.1039/d2sc04526e

Synthesis and Characterization of Yttrium Methanediide Silanide Complexes

Autori: Benjamin L. L. Réant; Ashley J. Wooles; Stephen T. Liddle; David P. Mills
Pubblicato in: Inorganic Chemistry, Numero 6, 2023, ISSN 1521-3765
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.2c03053

Thermally stable Terbium(II) and Dysprosium(II) Bis-Amidinate Single-Molecule Magnets

Autori: Peng-Bo Jin; Qian-Cheng Luo; Gemma Gransbury; Iñigo Vitorica-Yrezabal; Tomáš Hajdu; Eric McInnes; Richard Winpenny; Nicholas Chilton; David Mills; Yan-Zhen Zheng
Pubblicato in: Journal of the American Chemical Society, Numero 10, 2023, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.3c07978

Controlling Spin Crossover in a Family of Dinuclear Fe(III) Complexes via the Bis(catecholate) Bridging Ligand

Autori: Jett T. Janetzki; Maxim G. Chegerev; Gemma K. Gransbury; Robert W. Gable; Jack K. Clegg; Roger J. Mulder; Guy N. L. Jameson; Alyona A. Starikova; Colette Boskovic
Pubblicato in: Inorganic Chemistry, Numero 8, 2023, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c02598

Synthesis and Magnetic Properties of Bis-Halobenzene Decamethyldysprosocenium Cations

Autori: S. C. Corner, G. K. Gransbury, I. J. Vitorica-Yrezabal, G. F. S. Whitehead, N. F. Chilton, D. P. Mills
Pubblicato in: Inorganic Chemistry, 2024, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c04106

³¹P NMR Chemical Shift Anisotropy in Paramagnetic Lanthanide Phosphide Complexes

Autori: Jack Baldwin, Katherine L. Bonham, Toby R. C. Thompson, Gemma K. Gransbury, George F. S. Whitehead, Iñigo J. Vitorica-Yrezabal, Daniel Lee, Nicholas F. Chilton, David P. Mills
Pubblicato in: JACS Au, Numero 5, 2025, Pagina/e 1196-1212, ISSN 2691-3704
Editore: American Chemical Society (ACS)
DOI: 10.1021/jacsau.4c01018

Non‐Classical Early Lanthanide(II) Tris(di‐tert‐butylcyclopentadienyl) Complexes**

Autori: Jingjing Liu; Lydia E. Nodaraki; Daniel O. T. A. Martins; Marcus J. Giansiracusa; Philip J. Cobb; Jack Emerson‐King; Fabrizio Ortu; George F. S. Whitehead; Gemma K. Gransbury; Eric J. L. Mclnnes; Floriana Tuna; David P. Mills
Pubblicato in: European Journal of Inorganic Chemistry, Numero 3, 2023, ISSN 1099-0682
Editore: Wiley-VCH
DOI: 10.1002/ejic.202300552

Influence of pressure on a dysprosocenium single-molecule magnet

Autori: Vijay S. Parmar; Andreas M. Thiel; Rizwan Nabi; Gemma K. Gransbury; Marie S. Norre; Peter Evans; Sophie C. Corner; Jonathan M. Skelton; Nicholas F. Chilton; David P. Mills; Jacob Overgaard
Pubblicato in: Chemical Communications, Numero 6, 2023, ISSN 1521-3765
Editore: Royal Society of Chemistry
DOI: 10.1039/d2cc06722f

Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

Autori: Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Pubblicato in: Dalton Transactions, Numero 49/19, 2020, Pagina/e 6504-6511, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d0dt01241f

Bis(trimethylsilyl)phosphide chemistry: a half-century of advances across the periodic table

Autori: Jack Baldwin, David P. Mills
Pubblicato in: Chemical Society Reviews, Numero 54, 2025, Pagina/e 3819-3847, ISSN 0306-0012
Editore: Royal Society of Chemistry
DOI: 10.1039/d4cs01141d

Slow magnetic relaxation in distorted tetrahedral Dy(III) aryloxide complexes.

Autori: Vijay S. Parmar; Gemma K. Gransbury; George F. S. Whitehead; David P. Mills; Richard E. P. Winpenny
Pubblicato in: ChemComm, Numero 57, 2021, Pagina/e 9208-9211, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/d1cc02707g

<i>Tris</i>-Silanide f-Block Complexes: Insights into Paramagnetic Influence on NMR Chemical Shifts

Autori: Benjamin L. L. Réant, Fraser J. Mackintosh, Gemma K. Gransbury, Carlo Andrea Mattei, Barak Alnami, Benjamin E. Atkinson, Katherine L. Bonham, Jack Baldwin, Ashley J. Wooles, Iñigo J. Vitorica-Yrezabal, Daniel Lee, Nicholas F. Chilton, Stephen T. Liddle, David P. Mills
Pubblicato in: JACS Au, Numero 4, 2024, Pagina/e 2695-2711, ISSN 2691-3704
Editore: American Chemical Society (ACS)
DOI: 10.1021/jacsau.4c00466

Halobenzene Adducts of a Dysprosocenium Single-Molecule Magnet

Autori: S. C. Corner, G. K. Gransbury, I. J. Vitorica-Yrezabal, G. F. S. Whitehead, N. F. Chilton, D. P. Mills
Pubblicato in: Inorganic Chemistry, 2024, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c04105

Isolation and electronic structures of lanthanide(II) bis(trimethylsilyl)phosphide complexes

Autori: Jack Baldwin, Adam Brookfield, George Whitehead, Louise Natrajan, Eric McInnes, Meagan Oakley, David Mills
Pubblicato in: Inorganic Chemistry, Numero 63, 2024, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.26434/chemrxiv-2024-bl9lf

f-Element heavy pnictogen chemistry

Autori: J. Du, P. J. Cobb, J. Ding, D. P. Mills, S. T. Liddle
Pubblicato in: Chemical Science, 2023, ISSN 2041-6539
Editore: Royal Society of Chemistry
DOI: 10.1039/d3sc05056d

Comparison of group 4 and thorium M(<scp>iv</scp>) substituted cyclopentadienyl silanide complexes

Autori: Benjamin L. L. Réant; Dukula De Alwis Jayasinghe; Ashley J. Wooles; Stephen T. Liddle; David P. Mills
Pubblicato in: Dalton Transactions, Numero 8, 2023, ISSN 1477-9234
Editore: Royal Society of Chemistry
DOI: 10.1039/d3dt00987d

Tuning Valence Tautomerism in Dinuclear Cobalt Complexes by Modulating Communication in the Bridging Ligand

Autori: Jett T. Janetzki, Gemma K. Gransbury, Robert W. Gable, Marcus J. Giansiracusa, Alyona A. Starikova, Colette Boskovic
Pubblicato in: European Journal of Inorganic Chemistry, Numero 27, 2024, ISSN 1434-1948
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202400227

In-Field and Zero-Field Relaxation Dynamics of Dysprosocenium in Solution

Autori: William J. A. Blackmore, Sophie C. Corner, Peter Evans, Gemma K. Gransbury, David P. Mills, Nicholas F. Chilton
Pubblicato in: The Journal of Physical Chemistry A, Numero 129, 2025, Pagina/e 2144-2150, ISSN 1089-5639
Editore: American Chemical Society
DOI: 10.1021/acs.jpca.4c06678

Metallocene Anions: From Electrochemical Curiosities to Isolable Complexes

Autori: Corentin Magnoux; David P. Mills
Pubblicato in: European Journal of Inorganic Chemistry, Numero 3, 2022, ISSN 1099-0682
Editore: Wiley-VCH
DOI: 10.1002/ejic.202101063

f-Block Phospholyl and Arsolyl Chemistry.

Autori: Mills, David P.; Evans, Peter
Pubblicato in: Chemistry A European Journal, Numero 5, 2021, ISSN 1521-3765
Editore: Wiley-VCH
DOI: 10.1002/chem.202005231

A fluorobenzene-bound dysprosium half-sandwich dication single-molecule magnet

Autori: Sophie C. Corner, William J. A. Blackmore, Gemma K. Gransbury, Andrea Mattioni, George F. S. Whitehead, Nicholas F. Chilton, David P. Mills
Pubblicato in: Chemical Science, Numero 16, 2025, Pagina/e 610-620, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d4sc06661h

Synthesis of heteroleptic yttrium and dysprosium 1,2,4-tris(trimethylsilyl)cyclopentadienyl complexes

Autori: S. C. Corner, C. A. P. Goodwin, F. Ortu, P. Evans, H. Zhang, G. K. Gransbury, G. F. S. Whitehead, D. P. Mills
Pubblicato in: Australian Journal of Chemistry, 2022, ISSN 0004-9425
Editore: Commonwealth Scientific and Industrial Research Organization Publishing
DOI: 10.1071/ch21314

f-Element silicon and heavy tetrel chemistry

Autori: Benjamin L. L. Réant, Stephen T. Liddle, David P. Mills
Pubblicato in: Chemical Science, Numero 11/40, 2020, Pagina/e 10871-10886, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d0sc04655h

AtomAccess: A Predictive Tool for Molecular Design and Its Application to the Targeted Synthesis of Dysprosium Single-Molecule Magnets

Autori: Gemma K. Gransbury; Sophie C. Corner; Jon G. C. Kragskow; Peter Evans; Hing Man Yeung; William J. A. Blackmore; George F. S. Whitehead; Iñigo J. Vitorica-Yrezabal; Meagan S. Oakley; Nicholas F. Chilton; David P. Mills
Pubblicato in: Journal of the American Chemical Society, Numero 8, 2023, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.3c08841

Other (1)

Magnetic hysteresis up to 73 K in a dysprosium cyclopentadienyl-amide single-molecule magnet

Autori: Jack Emerson-King, Jack Baldwin, Sophie Corner, William Blackmore, Nicholas Chilton, David Mills
Pubblicato in: ChemRxiv, Numero 1, 2025, Pagina/e 1, ISSN 2573-2293
Editore: American Chemical Society (ACS)
DOI: 10.26434/chemrxiv-2025-31n16