Building Precise Molecular Architectures to Unlock Remarkable f-Element Properties

Información del proyecto

F-ELEMENT_ARCHITECT

Identificador del acuerdo de subvención: 816268

DOI

10.3030/816268

Proyecto cerrado

Fecha de la firma de la CE 25 Febrero 2019

Fecha de inicio 1 Septiembre 2019

Fecha de finalización 31 Mayo 2025

Financiado con arreglo a

• EXCELLENT SCIENCE - European Research Council (ERC)

Coste total

€ 1 990 800,93

Aportación de la UE

€ 1 990 800,93

Coordinado por

THE UNIVERSITY OF MANCHESTER
United Kingdom

CORDIS proporciona enlaces a los documentos públicos y las publicaciones de los proyectos de los programas marco HORIZONTE.

Los enlaces a los documentos y las publicaciones de los proyectos del Séptimo Programa Marco, así como los enlaces a algunos tipos de resultados específicos, como conjuntos de datos y «software», se obtienen dinámicamente de OpenAIRE .

Resultado final

Open Research Data Pilot (1)

Data Management Plan (DMP)

Produce Data Management Plan

Publicaciones

Peer reviewed articles (39)

Synthesis and characterization of solvated lanthanide(II) bis(triisopropylsilyl)phosphide complexes

Autores: Jack Baldwin, Adam Brookfield, George Whitehead, Louise Natrajan, Eric McInnes, Meagan Oakley, David Mills
Publicado en: Inorganic Chemistry, Edición 63, 2024, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.26434/chemrxiv-2024-3m17t

Mononuclear Dysprosium Alkoxide and Aryloxide Single-Molecule Magnets.

Autores: Vijay S. Parmar; David P. Mills; Richard E. P. Winpenny
Publicado en: Chemistry A European Journal, Edición 6, 2021, ISSN 1521-3765
Editor: Wiley-VCH
DOI: 10.1002/chem.202100085

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

Autores: Conrad A. P. Goodwin, Benjamin L. L. Réant, Gianni F. Vettese, Jon G. C. Kragskow, Marcus J. Giansiracusa, Ida M. DiMucci, Kyle M. Lancaster, David P. Mills, Stephen Sproules
Publicado en: Inorganic Chemistry, Edición 59/11, 2020, Página(s) 7571-7583, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c00470

Direct characterisation of <i>m</i>_<i>J</i> = ±15/2 ground state in octahedral Dy(<scp>iii</scp>) single-molecule magnets

Autores: Vijay S. Parmar, Gemma K. Gransbury, Sophie C. Corner, Wei-Hao Chou, Stephen Hill, Richard E. P. Winpenny, Nicholas F. Chilton, David P. Mills
Publicado en: Dalton Transactions, Edición 54, 2025, Página(s) 7616-7620, ISSN 1477-9226
Editor: Royal Society of Chemistry
DOI: 10.1039/d5dt00862j

Isolation of a Bent Dysprosium Bis(amide) Single-Molecule Magnet

Autores: Jack Emerson-King; Gemma K. Gransbury; George F. S. Whitehead; Iñigo J. Vitorica-Yrezabal; Mathieu Rouzières; Rodolphe Clérac; Nicholas F. Chilton; David P. Mills
Publicado en: Journal of the American Chemical Society, Edición 10, 2024, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.3c12427

Soft magnetic hysteresis in a dysprosium amide–alkene complex up to 100 kelvin

Autores: Jack Emerson-King, Gemma K. Gransbury, Benjamin E. Atkinson, William J. A. Blackmore, George F. S. Whitehead, Nicholas F. Chilton, David P. Mills
Publicado en: Nature, Edición 643, 2025, Página(s) 125-129, ISSN 0028-0836
Editor: Nature Publishing Group
DOI: 10.1038/s41586-025-09138-0

Measurement of the Quantum Tunneling Gap in a Dysprosocenium Single-Molecule Magnet

Autores: Blackmore, William J. A.; Mattioni, Andrea; Corner, Sophie C.; Evans, Peter; Gransbury, Gemma K.; Mills, David P.; Chilton, Nicholas F.
Publicado en: Journal of Physical Chemistry Letters, Edición 6, 2023, ISSN 1948-7185
Editor: American Chemical Society
DOI: 10.1021/acs.jpclett.3c00034

Trigonal Planar Heteroleptic Lanthanide(III) Bis(silyl)amide Complexes Containing Aminoxyl Radicals and Anions

Autores: Gemma K. Gransbury, Hannah M. Nicholas, Siobhan R. Murphy, Jack Emerson-King, Michele Vonci, Conrad A. P. Goodwin, Richard E. P. Winpenny, Nicholas F. Chilton, Marcus J. Giansiracusa, David P. Mills
Publicado en: Inorganic Chemistry, Edición 63, 2024, Página(s) 22422-22434, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c03281

Influence of weakly coordinating anions binding to the hexa-<i>tert</i>-butyl dysprosocenium cation

Autores: Sophie C. Corner, Gemma K. Gransbury, David P. Mills
Publicado en: Dalton Transactions, Edición 54, 2024, Página(s) 198-206, ISSN 1477-9226
Editor: Royal Society of Chemistry
DOI: 10.1039/d4dt02713b

Metal–carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy

Autores: Lydia E. Nodaraki; Jingjing Liu; Ana-Maria Ariciu; Fabrizio Ortu; Meagan S. Oakley; Letitia Birnoschi; Gemma K. Gransbury; Philip J. Cobb; Jack Emerson-King; Nicholas F. Chilton; David P. Mills; Eric J. L. McInnes; Floriana Tuna
Publicado en: Chemical Science, Edición 10, 2024, ISSN 2041-6539
Editor: Royal Society of Chemistry
DOI: 10.1039/d3sc06175b

Practical and Selective sp3 C−H Bond Chlorination via Aminium Radicals

Autores: A. J. McMillan, M. Sienkowska, P. Di Lorenzo, G. K. Gransbury, N. F. Chilton, M. Salamone, A. Ruffoni, M. Bietti, D. Leonori
Publicado en: Angewandte Chemie - International Edition, Edición 60, 2021, Página(s) 7132-7139, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202100030

Rare earth benzene tetraanion-bridged amidinate complexes

Autores: Peng-Bo Jin, Qian-Cheng Luo, Gemma K. Gransbury, Richard E. P. Winpenny, David P. Mills, Yan-Zhen Zheng
Publicado en: Chemical Science, Edición 16, 2025, Página(s) 1907-1924, ISSN 2041-6520
Editor: Royal Society of Chemistry
DOI: 10.1039/d4sc05982d

Characterisation of magnetic relaxation on extremely long timescales

Autores: William J. A. Blackmore; Gemma K. Gransbury; Peter Evans; Jon G. C. Kragskow; David P. Mills; Nicholas F. Chilton
Publicado en: Physical Chemistry Chemical Physics, Edición 7, 2023, ISSN 1463-9084
Editor: Royal Society of Chemistry
DOI: 10.1039/d3cp01278f

Polarised covalent thorium( iv )– and uranium( iv )–silicon bonds

Autores: Benjamin L. L. Réant, Victoria E. J. Berryman, John A. Seed, Annabel R. Basford, Alasdair Formanuik, Ashley J. Wooles, Nikolas Kaltsoyannis, Stephen T. Liddle, David P. Mills
Publicado en: Chemical Communications, Edición 56/83, 2020, Página(s) 12620-12623, ISSN 1359-7345
Editor: Royal Society of Chemistry
DOI: 10.1039/d0cc06044e

Isolation and electronic structures of derivatized manganocene, ferrocene and cobaltocene anions

Autores: Conrad A. P. Goodwin, Marcus J. Giansiracusa, Samuel M. Greer, Hannah M. Nicholas, Peter Evans, Michele Vonci, Stephen Hill, Nicholas F. Chilton, David P. Mills
Publicado en: Nature Chemistry, Edición 13/3, 2021, Página(s) 243-248, ISSN 1755-4330
Editor: Nature Publishing Group
DOI: 10.1038/s41557-020-00595-w

Electronic structure comparisons of isostructural early d- and f-block metal(<scp>iii</scp>) bis(cyclopentadienyl) silanide complexes

Autores: Gemma K. Gransbury; Benjamin L. L. Réant; Ashley J. Wooles; Jack Emerson-King; Nicholas F. Chilton; Stephen T. Liddle; David P. Mills
Publicado en: Chemical Science, Edición 9, 2023, ISSN 2041-6539
Editor: Royal Society of Chemistry
DOI: 10.1039/d2sc04526e

Synthesis and Characterization of Yttrium Methanediide Silanide Complexes

Autores: Benjamin L. L. Réant; Ashley J. Wooles; Stephen T. Liddle; David P. Mills
Publicado en: Inorganic Chemistry, Edición 6, 2023, ISSN 1521-3765
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.2c03053

Thermally stable Terbium(II) and Dysprosium(II) Bis-Amidinate Single-Molecule Magnets

Autores: Peng-Bo Jin; Qian-Cheng Luo; Gemma Gransbury; Iñigo Vitorica-Yrezabal; Tomáš Hajdu; Eric McInnes; Richard Winpenny; Nicholas Chilton; David Mills; Yan-Zhen Zheng
Publicado en: Journal of the American Chemical Society, Edición 10, 2023, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.3c07978

Controlling Spin Crossover in a Family of Dinuclear Fe(III) Complexes via the Bis(catecholate) Bridging Ligand

Autores: Jett T. Janetzki; Maxim G. Chegerev; Gemma K. Gransbury; Robert W. Gable; Jack K. Clegg; Roger J. Mulder; Guy N. L. Jameson; Alyona A. Starikova; Colette Boskovic
Publicado en: Inorganic Chemistry, Edición 8, 2023, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c02598

Synthesis and Magnetic Properties of Bis-Halobenzene Decamethyldysprosocenium Cations

Autores: S. C. Corner, G. K. Gransbury, I. J. Vitorica-Yrezabal, G. F. S. Whitehead, N. F. Chilton, D. P. Mills
Publicado en: Inorganic Chemistry, 2024, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c04106

³¹P NMR Chemical Shift Anisotropy in Paramagnetic Lanthanide Phosphide Complexes

Autores: Jack Baldwin, Katherine L. Bonham, Toby R. C. Thompson, Gemma K. Gransbury, George F. S. Whitehead, Iñigo J. Vitorica-Yrezabal, Daniel Lee, Nicholas F. Chilton, David P. Mills
Publicado en: JACS Au, Edición 5, 2025, Página(s) 1196-1212, ISSN 2691-3704
Editor: American Chemical Society (ACS)
DOI: 10.1021/jacsau.4c01018

Non‐Classical Early Lanthanide(II) Tris(di‐tert‐butylcyclopentadienyl) Complexes**

Autores: Jingjing Liu; Lydia E. Nodaraki; Daniel O. T. A. Martins; Marcus J. Giansiracusa; Philip J. Cobb; Jack Emerson‐King; Fabrizio Ortu; George F. S. Whitehead; Gemma K. Gransbury; Eric J. L. Mclnnes; Floriana Tuna; David P. Mills
Publicado en: European Journal of Inorganic Chemistry, Edición 3, 2023, ISSN 1099-0682
Editor: Wiley-VCH
DOI: 10.1002/ejic.202300552

Influence of pressure on a dysprosocenium single-molecule magnet

Autores: Vijay S. Parmar; Andreas M. Thiel; Rizwan Nabi; Gemma K. Gransbury; Marie S. Norre; Peter Evans; Sophie C. Corner; Jonathan M. Skelton; Nicholas F. Chilton; David P. Mills; Jacob Overgaard
Publicado en: Chemical Communications, Edición 6, 2023, ISSN 1521-3765
Editor: Royal Society of Chemistry
DOI: 10.1039/d2cc06722f

Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

Autores: Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Publicado en: Dalton Transactions, Edición 49/19, 2020, Página(s) 6504-6511, ISSN 1477-9226
Editor: Royal Society of Chemistry
DOI: 10.1039/d0dt01241f

Bis(trimethylsilyl)phosphide chemistry: a half-century of advances across the periodic table

Autores: Jack Baldwin, David P. Mills
Publicado en: Chemical Society Reviews, Edición 54, 2025, Página(s) 3819-3847, ISSN 0306-0012
Editor: Royal Society of Chemistry
DOI: 10.1039/d4cs01141d

Slow magnetic relaxation in distorted tetrahedral Dy(III) aryloxide complexes.

Autores: Vijay S. Parmar; Gemma K. Gransbury; George F. S. Whitehead; David P. Mills; Richard E. P. Winpenny
Publicado en: ChemComm, Edición 57, 2021, Página(s) 9208-9211, ISSN 1359-7345
Editor: Royal Society of Chemistry
DOI: 10.1039/d1cc02707g

<i>Tris</i>-Silanide f-Block Complexes: Insights into Paramagnetic Influence on NMR Chemical Shifts

Autores: Benjamin L. L. Réant, Fraser J. Mackintosh, Gemma K. Gransbury, Carlo Andrea Mattei, Barak Alnami, Benjamin E. Atkinson, Katherine L. Bonham, Jack Baldwin, Ashley J. Wooles, Iñigo J. Vitorica-Yrezabal, Daniel Lee, Nicholas F. Chilton, Stephen T. Liddle, David P. Mills
Publicado en: JACS Au, Edición 4, 2024, Página(s) 2695-2711, ISSN 2691-3704
Editor: American Chemical Society (ACS)
DOI: 10.1021/jacsau.4c00466

Halobenzene Adducts of a Dysprosocenium Single-Molecule Magnet

Autores: S. C. Corner, G. K. Gransbury, I. J. Vitorica-Yrezabal, G. F. S. Whitehead, N. F. Chilton, D. P. Mills
Publicado en: Inorganic Chemistry, 2024, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c04105

Isolation and electronic structures of lanthanide(II) bis(trimethylsilyl)phosphide complexes

Autores: Jack Baldwin, Adam Brookfield, George Whitehead, Louise Natrajan, Eric McInnes, Meagan Oakley, David Mills
Publicado en: Inorganic Chemistry, Edición 63, 2024, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.26434/chemrxiv-2024-bl9lf

f-Element heavy pnictogen chemistry

Autores: J. Du, P. J. Cobb, J. Ding, D. P. Mills, S. T. Liddle
Publicado en: Chemical Science, 2023, ISSN 2041-6539
Editor: Royal Society of Chemistry
DOI: 10.1039/d3sc05056d

Comparison of group 4 and thorium M(<scp>iv</scp>) substituted cyclopentadienyl silanide complexes

Autores: Benjamin L. L. Réant; Dukula De Alwis Jayasinghe; Ashley J. Wooles; Stephen T. Liddle; David P. Mills
Publicado en: Dalton Transactions, Edición 8, 2023, ISSN 1477-9234
Editor: Royal Society of Chemistry
DOI: 10.1039/d3dt00987d

Tuning Valence Tautomerism in Dinuclear Cobalt Complexes by Modulating Communication in the Bridging Ligand

Autores: Jett T. Janetzki, Gemma K. Gransbury, Robert W. Gable, Marcus J. Giansiracusa, Alyona A. Starikova, Colette Boskovic
Publicado en: European Journal of Inorganic Chemistry, Edición 27, 2024, ISSN 1434-1948
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202400227

In-Field and Zero-Field Relaxation Dynamics of Dysprosocenium in Solution

Autores: William J. A. Blackmore, Sophie C. Corner, Peter Evans, Gemma K. Gransbury, David P. Mills, Nicholas F. Chilton
Publicado en: The Journal of Physical Chemistry A, Edición 129, 2025, Página(s) 2144-2150, ISSN 1089-5639
Editor: American Chemical Society
DOI: 10.1021/acs.jpca.4c06678

Metallocene Anions: From Electrochemical Curiosities to Isolable Complexes

Autores: Corentin Magnoux; David P. Mills
Publicado en: European Journal of Inorganic Chemistry, Edición 3, 2022, ISSN 1099-0682
Editor: Wiley-VCH
DOI: 10.1002/ejic.202101063

f-Block Phospholyl and Arsolyl Chemistry.

Autores: Mills, David P.; Evans, Peter
Publicado en: Chemistry A European Journal, Edición 5, 2021, ISSN 1521-3765
Editor: Wiley-VCH
DOI: 10.1002/chem.202005231

A fluorobenzene-bound dysprosium half-sandwich dication single-molecule magnet

Autores: Sophie C. Corner, William J. A. Blackmore, Gemma K. Gransbury, Andrea Mattioni, George F. S. Whitehead, Nicholas F. Chilton, David P. Mills
Publicado en: Chemical Science, Edición 16, 2025, Página(s) 610-620, ISSN 2041-6520
Editor: Royal Society of Chemistry
DOI: 10.1039/d4sc06661h

Synthesis of heteroleptic yttrium and dysprosium 1,2,4-tris(trimethylsilyl)cyclopentadienyl complexes

Autores: S. C. Corner, C. A. P. Goodwin, F. Ortu, P. Evans, H. Zhang, G. K. Gransbury, G. F. S. Whitehead, D. P. Mills
Publicado en: Australian Journal of Chemistry, 2022, ISSN 0004-9425
Editor: Commonwealth Scientific and Industrial Research Organization Publishing
DOI: 10.1071/ch21314

f-Element silicon and heavy tetrel chemistry

Autores: Benjamin L. L. Réant, Stephen T. Liddle, David P. Mills
Publicado en: Chemical Science, Edición 11/40, 2020, Página(s) 10871-10886, ISSN 2041-6520
Editor: Royal Society of Chemistry
DOI: 10.1039/d0sc04655h

AtomAccess: A Predictive Tool for Molecular Design and Its Application to the Targeted Synthesis of Dysprosium Single-Molecule Magnets

Autores: Gemma K. Gransbury; Sophie C. Corner; Jon G. C. Kragskow; Peter Evans; Hing Man Yeung; William J. A. Blackmore; George F. S. Whitehead; Iñigo J. Vitorica-Yrezabal; Meagan S. Oakley; Nicholas F. Chilton; David P. Mills
Publicado en: Journal of the American Chemical Society, Edición 8, 2023, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.3c08841

Other (1)

Magnetic hysteresis up to 73 K in a dysprosium cyclopentadienyl-amide single-molecule magnet

Autores: Jack Emerson-King, Jack Baldwin, Sophie Corner, William Blackmore, Nicholas Chilton, David Mills
Publicado en: ChemRxiv, Edición 1, 2025, Página(s) 1, ISSN 2573-2293
Editor: American Chemical Society (ACS)
DOI: 10.26434/chemrxiv-2025-31n16