Building Precise Molecular Architectures to Unlock Remarkable f-Element Properties

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Mononuclear Dysprosium Alkoxide and Aryloxide Single-Molecule Magnets.

Autores: Vijay S. Parmar; David P. Mills; Richard E. P. Winpenny
Publicado en: Chemistry A European Journal, Edición 6, 2021, ISSN 1521-3765
Editor: Wiley-VCH
DOI: 10.1002/chem.202100085

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

Autores: Conrad A. P. Goodwin, Benjamin L. L. Réant, Gianni F. Vettese, Jon G. C. Kragskow, Marcus J. Giansiracusa, Ida M. DiMucci, Kyle M. Lancaster, David P. Mills, Stephen Sproules
Publicado en: Inorganic Chemistry, Edición 59/11, 2020, Página(s) 7571-7583, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c00470

Isolation of a Bent Dysprosium Bis(amide) Single-Molecule Magnet

Autores: Jack Emerson-King; Gemma K. Gransbury; George F. S. Whitehead; Iñigo J. Vitorica-Yrezabal; Mathieu Rouzières; Rodolphe Clérac; Nicholas F. Chilton; David P. Mills
Publicado en: Journal of the American Chemical Society, Edición 10, 2024, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.3c12427

Measurement of the Quantum Tunneling Gap in a Dysprosocenium Single-Molecule Magnet

Autores: Blackmore, William J. A.; Mattioni, Andrea; Corner, Sophie C.; Evans, Peter; Gransbury, Gemma K.; Mills, David P.; Chilton, Nicholas F.
Publicado en: Journal of Physical Chemistry Letters, Edición 6, 2023, ISSN 1948-7185
Editor: American Chemical Society
DOI: 10.1021/acs.jpclett.3c00034

Metal–carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy

Autores: Lydia E. Nodaraki; Jingjing Liu; Ana-Maria Ariciu; Fabrizio Ortu; Meagan S. Oakley; Letitia Birnoschi; Gemma K. Gransbury; Philip J. Cobb; Jack Emerson-King; Nicholas F. Chilton; David P. Mills; Eric J. L. McInnes; Floriana Tuna
Publicado en: Chemical Science, Edición 10, 2024, ISSN 2041-6539
Editor: Royal Society of Chemistry
DOI: 10.1039/d3sc06175b

Practical and Selective sp3 C−H Bond Chlorination via Aminium Radicals

Autores: A. J. McMillan, M. Sienkowska, P. Di Lorenzo, G. K. Gransbury, N. F. Chilton, M. Salamone, A. Ruffoni, M. Bietti, D. Leonori
Publicado en: Angewandte Chemie - International Edition, Edición 60, 2021, Página(s) 7132-7139, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202100030

Characterisation of magnetic relaxation on extremely long timescales

Autores: William J. A. Blackmore; Gemma K. Gransbury; Peter Evans; Jon G. C. Kragskow; David P. Mills; Nicholas F. Chilton
Publicado en: Physical Chemistry Chemical Physics, Edición 7, 2023, ISSN 1463-9084
Editor: Royal Society of Chemistry
DOI: 10.1039/d3cp01278f

Polarised covalent thorium( iv )– and uranium( iv )–silicon bonds

Autores: Benjamin L. L. Réant, Victoria E. J. Berryman, John A. Seed, Annabel R. Basford, Alasdair Formanuik, Ashley J. Wooles, Nikolas Kaltsoyannis, Stephen T. Liddle, David P. Mills
Publicado en: Chemical Communications, Edición 56/83, 2020, Página(s) 12620-12623, ISSN 1359-7345
Editor: Royal Society of Chemistry
DOI: 10.1039/d0cc06044e

Isolation and electronic structures of derivatized manganocene, ferrocene and cobaltocene anions

Autores: Conrad A. P. Goodwin, Marcus J. Giansiracusa, Samuel M. Greer, Hannah M. Nicholas, Peter Evans, Michele Vonci, Stephen Hill, Nicholas F. Chilton, David P. Mills
Publicado en: Nature Chemistry, Edición 13/3, 2021, Página(s) 243-248, ISSN 1755-4330
Editor: Nature Publishing Group
DOI: 10.1038/s41557-020-00595-w

Electronic structure comparisons of isostructural early d- and f-block metal(<scp>iii</scp>) bis(cyclopentadienyl) silanide complexes

Autores: Gemma K. Gransbury; Benjamin L. L. Réant; Ashley J. Wooles; Jack Emerson-King; Nicholas F. Chilton; Stephen T. Liddle; David P. Mills
Publicado en: Chemical Science, Edición 9, 2023, ISSN 2041-6539
Editor: Royal Society of Chemistry
DOI: 10.1039/d2sc04526e

Synthesis and Characterization of Yttrium Methanediide Silanide Complexes

Autores: Benjamin L. L. Réant; Ashley J. Wooles; Stephen T. Liddle; David P. Mills
Publicado en: Inorganic Chemistry, Edición 6, 2023, ISSN 1521-3765
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.2c03053

Thermally stable Terbium(II) and Dysprosium(II) Bis-Amidinate Single-Molecule Magnets

Autores: Peng-Bo Jin; Qian-Cheng Luo; Gemma Gransbury; Iñigo Vitorica-Yrezabal; Tomáš Hajdu; Eric McInnes; Richard Winpenny; Nicholas Chilton; David Mills; Yan-Zhen Zheng
Publicado en: Journal of the American Chemical Society, Edición 10, 2023, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.3c07978

Controlling Spin Crossover in a Family of Dinuclear Fe(III) Complexes via the Bis(catecholate) Bridging Ligand

Autores: Jett T. Janetzki; Maxim G. Chegerev; Gemma K. Gransbury; Robert W. Gable; Jack K. Clegg; Roger J. Mulder; Guy N. L. Jameson; Alyona A. Starikova; Colette Boskovic
Publicado en: Inorganic Chemistry, Edición 8, 2023, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c02598

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

Autores: Vijay S. Parmar, David P. Mills, Richard E. P. Winpenny
Publicado en: Chemistry – A European Journal, 2021, ISSN 0947-6539
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202100085

Non‐Classical Early Lanthanide(II) Tris(di‐tert‐butylcyclopentadienyl) Complexes**

Autores: Jingjing Liu; Lydia E. Nodaraki; Daniel O. T. A. Martins; Marcus J. Giansiracusa; Philip J. Cobb; Jack Emerson‐King; Fabrizio Ortu; George F. S. Whitehead; Gemma K. Gransbury; Eric J. L. Mclnnes; Floriana Tuna; David P. Mills
Publicado en: European Journal of Inorganic Chemistry, Edición 3, 2023, ISSN 1099-0682
Editor: Wiley-VCH
DOI: 10.1002/ejic.202300552

Influence of pressure on a dysprosocenium single-molecule magnet

Autores: Vijay S. Parmar; Andreas M. Thiel; Rizwan Nabi; Gemma K. Gransbury; Marie S. Norre; Peter Evans; Sophie C. Corner; Jonathan M. Skelton; Nicholas F. Chilton; David P. Mills; Jacob Overgaard
Publicado en: Chemical Communications, Edición 6, 2023, ISSN 1521-3765
Editor: Royal Society of Chemistry
DOI: 10.1039/d2cc06722f

Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

Autores: Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Publicado en: Dalton Transactions, Edición 49/19, 2020, Página(s) 6504-6511, ISSN 1477-9226
Editor: Royal Society of Chemistry
DOI: 10.1039/d0dt01241f

Slow magnetic relaxation in distorted tetrahedral Dy(III) aryloxide complexes.

Autores: Vijay S. Parmar; Gemma K. Gransbury; George F. S. Whitehead; David P. Mills; Richard E. P. Winpenny
Publicado en: ChemComm, Edición 57, 2021, Página(s) 9208-9211, ISSN 1359-7345
Editor: Royal Society of Chemistry
DOI: 10.1039/d1cc02707g

Comparison of group 4 and thorium M(<scp>iv</scp>) substituted cyclopentadienyl silanide complexes

Autores: Benjamin L. L. Réant; Dukula De Alwis Jayasinghe; Ashley J. Wooles; Stephen T. Liddle; David P. Mills
Publicado en: Dalton Transactions, Edición 8, 2023, ISSN 1477-9234
Editor: Royal Society of Chemistry
DOI: 10.1039/d3dt00987d

Metallocene Anions: From Electrochemical Curiosities to Isolable Complexes

Autores: Corentin Magnoux; David P. Mills
Publicado en: European Journal of Inorganic Chemistry, Edición 3, 2022, ISSN 1099-0682
Editor: Wiley-VCH
DOI: 10.1002/ejic.202101063

f-Block Phospholyl and Arsolyl Chemistry.

Autores: Mills, David P.; Evans, Peter
Publicado en: Chemistry A European Journal, Edición 5, 2021, ISSN 1521-3765
Editor: Wiley-VCH
DOI: 10.1002/chem.202005231

Synthesis of heteroleptic yttrium and dysprosium 1,2,4-tris(trimethylsilyl)cyclopentadienyl complexes

Autores: S. C. Corner, C. A. P. Goodwin, F. Ortu, P. Evans, H. Zhang, G. K. Gransbury, G. F. S. Whitehead, D. P. Mills
Publicado en: Australian Journal of Chemistry, 2022, ISSN 0004-9425
Editor: Commonwealth Scientific and Industrial Research Organization Publishing
DOI: 10.1071/ch21314

f‐Block Phospholyl and Arsolyl Chemistry

Autores: David P. Mills, Peter Evans
Publicado en: Chemistry – A European Journal, 2021, ISSN 0947-6539
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202005231

f-Element silicon and heavy tetrel chemistry

Autores: Benjamin L. L. Réant, Stephen T. Liddle, David P. Mills
Publicado en: Chemical Science, Edición 11/40, 2020, Página(s) 10871-10886, ISSN 2041-6520
Editor: Royal Society of Chemistry
DOI: 10.1039/d0sc04655h

AtomAccess: A Predictive Tool for Molecular Design and Its Application to the Targeted Synthesis of Dysprosium Single-Molecule Magnets

Autores: Gemma K. Gransbury; Sophie C. Corner; Jon G. C. Kragskow; Peter Evans; Hing Man Yeung; William J. A. Blackmore; George F. S. Whitehead; Iñigo J. Vitorica-Yrezabal; Meagan S. Oakley; Nicholas F. Chilton; David P. Mills
Publicado en: Journal of the American Chemical Society, Edición 8, 2023, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.3c08841

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