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Reprogramming Conformation by Fluorination: Exploring New Areas of Chemical Space

Publications

Expanding organofluorine chemical space: the design of chiral fluorinated isosteres enabled by I( i )/I( iii ) catalysis

Author(s): Stephanie Meyer, Joel Häfliger, Ryan Gilmour
Published in: Chemical Science, Issue 12/32, 2021, Page(s) 10686-10695, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc02880d

A Chiral Pentafluorinated Isopropyl Group via Iodine(I)/(III) Catalysis

Author(s): Stephanie Meyer, Joel Häfliger, Michael Schäfer, John J. Molloy, Constantin G. Daniliuc, Ryan Gilmour
Published in: Angewandte Chemie International Edition, Issue 60/12, 2021, Page(s) 6430-6434, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015946

Inverting Small Molecule–Protein Recognition by the Fluorine Gauche Effect: Selectivity Regulated by Multiple H→F Bioisosterism

Author(s): Patrick Bentler, Klaus Bergander, Constantin G. Daniliuc, Christian Mück‐Lichtenfeld, Ravindra P. Jumde, Anna K. H. Hirsch, Ryan Gilmour
Published in: Angewandte Chemie International Edition, Issue 58/32, 2019, Page(s) 10990-10994, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201905452

Difluorination of α-(bromomethyl)styrenes via I(I)/I(III) catalysis: facile access to electrophilic linchpins for drug discovery

Author(s): Joel Häfliger, Keith Livingstone, Constantin G. Daniliuc, Ryan Gilmour
Published in: Chemical Science, Issue 12/17, 2021, Page(s) 6148-6152, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc01132d

Enhancing glycan stability via site-selective fluorination: modulating substrate orientation by molecular design

Author(s): Alexander Axer, Ravindra P. Jumde, Sebastian Adam, Andreas Faust, Michael Schäfers, Manfred Fobker, Jesko Koehnke, Anna K. H. Hirsch, Ryan Gilmour
Published in: Chemical Science, Issue 12/4, 2021, Page(s) 1286-1294, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc04297h

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