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Biocatalysis for Sustainable Chemistry – Understanding Oxidation/Reduction of Small Molecules by Redox Metalloenzymes via a Suite of Steady State and Transient Infrared Electrochemical Methods

Publications

The 2022 solar fuels roadmap

Author(s): Gideon Segev; Jakob Kibsgaard; Christopher Hahn; Zhichuan J Xu; Wen-Hui (Sophia) Cheng; Todd G Deutsch; Chengxiang Xiang; Jenny Z Zhang; Leif Hammarström; Daniel G Nocera; Adam Z Weber; Peter Agbo; Takashi Hisatomi; Frank E Osterloh; Kazunari Domen; Fatwa F Abdi; Sophia Haussener; Daniel J Miller; Shane Ardo; Paul C McIntyre; Thomas Hannappel; Shu Hu; Harry Atwater; John M Gregoire; Mehmed Z Erte
Published in: Journal of Physics D: Applied Physics, Issue Vol 55, Iss 32, 2022, Page(s) 323003, ISSN 1361-6463
Publisher: IOPScience
DOI: 10.1088/1361-6463/ac6f97

H2-Driven Reduction of Flavin by Hydrogenase Enables Cleaner Operation of Nitroreductases for Nitro-Group to Amine Reductions

Author(s): Miguel A. Ramirez, Shiny Joseph Srinivasan, Sarah E. Cleary, Peter M. T. Todd, Holly A. Reeve, Kylie A. Vincent
Published in: Frontiers in Catalysis, Issue Vol 2, 2022, Page(s) https://doi.org/10.3389/fctls.2022.906694, ISSN 2673-7841
Publisher: Frontiers
DOI: 10.3389/fctls.2022.906694

E. coli Nickel‐Iron Hydrogenase 1 Catalyses Non‐native Reduction of Flavins: Demonstration for Alkene Hydrogenation by Old Yellow Enzyme Ene‐reductases**

Author(s): Shiny Joseph Srinivasan; Sarah E. Cleary; Miguel A. Ramirez; Holly A. Reeve; Caroline E. Paul; Kylie A. Vincent
Published in: Angewandte Chemie (International Ed. in English), Issue Vol 60, 2021, Page(s) 13824-13828, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202101186

The crystalline state as a dynamic system: IR microspectroscopy under electrochemical control for a [NiFe] hydrogenase

Author(s): Philip A. Ash; Sophie E. T. Kendall-Price; Rhiannon M. Evans; Stephen B. Carr; Amelia R. Brasnett; Simone Morra; Jack S. Rowbotham; Ricardo Hidalgo; Adam J. Healy; Gianfelice Cinque; Mark D. Frogley; Fraser A. Armstrong; Kylie A. Vincent
Published in: Chemical Science, Issue Vol 12, 2021, Page(s) 12959-12970, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc01734a

Stability of the H-cluster under whole-cell conditions—formation of an Htrans-like state and its reactivity towards oxygen

Author(s): Marco Lorenzi; Pierre Ceccaldi; Patricia Rodríguez-Maciá; Holly Jayne Redman; Afridi Zamader; James A. Birrell; Livia S. Mészáros; Gustav Berggren
Published in: Journal of Biological Inorganic Chemistry, Issue 1, 2022, ISSN 0949-8257
Publisher: Springer Verlag
DOI: 10.1007/s00775-022-01928-5

The Nonphysiological Reductant Sodium Dithionite and [FeFe] Hydrogenase: Influence on the Enzyme Mechanism.

Author(s): Maria Alessandra Martini; Olaf Rüdiger; Nina Breuer; Birgit Nöring; Serena DeBeer; Patricia Rodríguez-Maciá; James A. Birrell
Published in: Journal of the American Chemical Society, Issue 1, 2021, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c07322

Electrochemical experiments define potentials associated with binding of substrates and inhibitors to nitrogenase MoFe protein

Author(s): Ting Chen; Philip A. Ash; Lance C. Seefeldt; Kylie A. Vincent
Published in: Faraday Discussions, Issue 243, 2023, Page(s) 270-286, ISSN 1364-5498
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2fd00170e

Electrochemical control of [FeFe]-hydrogenase single crystals reveals complex redox populations at the catalytic site

Author(s): Simone Morra; Jifu Duan; Martin Winkler; Philip A. Ash; Thomas Happe; Kylie A. Vincent
Published in: Dalton Transactions, Issue Vol 50, 2021, Page(s) 12655-12663, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt02219a

A Beginner’s Guide to Thermodynamic Modelling of [FeFe] Hydrogenase

Author(s): James A. Birrell; Patricia Rodríguez-Maciá; Adrian Hery-Barranco
Published in: Catalysts, Issue Vol 11, 2021, Page(s) 238, ISSN 2073-4344
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/catal11020238

E. coli Nickel-Iron Hydrogenase 1 Catalyses Non-native Reduction of Flavins: Demonstration for Alkene Hydrogenation by Old Yellow Enzyme

Author(s): Joseph Srinivasan, Shiny; Cleary, Sarah; Paul, Caroline; Ramirez, Miguel A.; Vincent, Kylie
Published in: ChemRxiv. Preprint., 2020
Publisher: ChemRxiv
DOI: 10.26434/chemrxiv.12213398.v2

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