Development and Application of New NMR Methods for Studying Interphases and Interfaces in Batteries

Pubblicazioni

Probing and Interpreting the Porosity and Tortuosity Evolution of Li-O 2 Cathodes on Discharge through a Combined Experimental and Theoretical Approach

Autori: Amangeldi Torayev, Simon Engelke, Zeliang Su, Lauren E. Marbella, Vincent De Andrade, Arnaud Demortière, Pieter C. M. M. Magusin, Céline Merlet, Alejandro A. Franco, and Clare P. Grey
Pubblicato in: The Journal of Physical Chemistry C, 2021, ISSN 1932-7447
Editore: American Chemical Society
DOI: 10.17863/cam.64888

Local Distortions and Dynamics in Hydrated Y-Doped BaZrO3.

Autori: Amangeldi Torayev; Luke Sperrin; Maria A. Gomez; John A. Kattirtzi; Céline Merlet; Céline Merlet; Céline Merlet; Clare P. Grey
Pubblicato in: Journal of Physical Chemistry C, Numero 1, 2021, ISSN 1932-7447
Editore: American Chemical Society
DOI: 10.17863/cam.54388

Identifying and preventing degradation in flavin mononucleotide-based redox flow batteries via NMR and EPR spectroscopy

Autori: Hey, Dominic; Jethwa, Rajesh B; Farag, Nadia L; Rinkel, Bernardine LD; Zhao, Evan Wenbo; Grey, Clare P
Pubblicato in: Nature Communications, 14, Numero 4, 2023, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-023-40649-4

Probing and Interpreting the Porosity and Tortuosity Evolution of Li-O

Autori: Amangeldi, Torayev; Simon, Engelke; Zeliang, Su; Lauren E, Marbella; Vincent, De Andrade; Arnaud, Demortière; Pieter C M M, Magusin; Céline, Merlet; Alejandro A, Franco; Clare P, Grey
Pubblicato in: The Journal of Physical Chemistry. C, Nanomaterials and Interfaces, Numero 3, 2021, ISSN 1932-7447
Editore: American Chemical Society
DOI: 10.1021/acs.jpcc.0c10417

Selective NMR observation of the SEI–metal interface by dynamic nuclear polarisation from lithium metal

Autori: Michael A. Hope, Bernardine L. D. Rinkel, Anna B. Gunnarsdóttir, Katharina Märker, Svetlana Menkin, Subhradip Paul, Ivan V. Sergeyev, Clare P. Grey
Pubblicato in: Nature Communications, Numero 11/1, 2020, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-020-16114-x

Local Distortions and Dynamics in Hydrated Y-Doped BaZrO 3

Autori: Amangeldi Torayev, Luke Sperrin, Maria A. Gomez, John A. Kattirtzi, Céline Merlet, Clare P. Grey
Pubblicato in: The Journal of Physical Chemistry C, Numero 124/30, 2020, Pagina/e 16689-16701, ISSN 1932-7447
Editore: American Chemical Society
DOI: 10.1021/acs.jpcc.0c04594

Electrolyte oxidation pathways in lithium-ion batteries

Autori: Israel Temprano; Bernardine L. D. Rinkel; Clare P. Grey; David S. Hall
Pubblicato in: Journal of the American Chemical Society, Numero 1, 2020, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.17863/cam.59530

Operando monitoring of single-particle kineticstate-of-charge heterogeneities and cracking inhigh-rate Li-ion anodes

Autori: Merryweather, A. J., Jacquet, Q., Emge, S. P., Schnedermann, C., Rao, A., & Grey, C. P. (2022).
Pubblicato in: Nature Materials, 2022, ISSN 1476-1122
Editore: Nature Publishing Group
DOI: 10.1038/s41563-022-01324-z

Sodium Borates: Expanding the Electrolyte Selection for Sodium-Ion Batteries

Autori: Dr. Darren M. C. Ould, Dr. Svetlana Menkin, Holly E. Smith, Victor Riesgo-Gonzalez, Dr. Erlendur Jónsson, Dr. Christopher A. O'Keefe, Dr. Fazlil Coowar, Dr. Jerry Barker, Dr. Andrew D. Bond, Prof. Clare P. Grey, Prof. Dominic S. Wright
Pubblicato in: Agnew Chem Int. Ed. Engl., 2022, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202202133

Surface reduction in lithium- and manganese-rich layered cathodes for lithium ion batteries drives voltage decay.

Autori: Bo Wen; Farheen N. Sayed; Wesley M. Dose; Jędrzej K. Morzy; Yeonguk Son; Supreeth Nagendran; Caterina Ducati; Clare P. Grey; Michael F. L. De Volder
Pubblicato in: Journal of Materials Chemistry A, 2022, ISSN 2050-7488
Editore: Royal Society of Chemistry
DOI: 10.17863/cam.88809

Insights into soft short circuit-based degradation of lithium metal batteries

Autori: Svetlana Menkin; Jana B. Fritzke; Rebecca Larner; Cas de Leeuw; Yoonseong Choi; Anna B. Gunnarsdóttir; Clare P. Grey
Pubblicato in: Crossref, Numero 2, 2023, ISSN 1359-6640
Editore: Royal Society of Chemistry
DOI: 10.1039/d3fd00101f

Engineering considerations for practical lithium–air electrolytes

Autori: Ellison, James HJ; Grey, Clare P
Pubblicato in: Crossref, Numero 2, 2024, ISSN 1359-6640
Editore: Royal Society of Chemistry
DOI: 10.1039/d3fd00091e

On the Solvation of Redox Mediators and Implications for their Reactivity in Li-Air Batteries

Autori: Erlendur Jónsson, James H. J. Ellison, Evelyna Wang, Vera Kunz, Tao Liu, Israel Temprano, Clare P. Grey
Pubblicato in: Journal of The Electrochemical Society, Numero 168/3, 2021, Pagina/e 030529, ISSN 0013-4651
Editore: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/abeb26

A solution-processable near-infrared thermally activated delayed fluorescent dye with a fused aromatic acceptor and aggregation induced emission behavior

Autori: Daniel G. Congrave, Bluebell H. Drummond, Qinying Gu, Stephanie Montanaro, Haydn Francis, Víctor Riesgo-González, Weixuan Zeng, Campbell S. B. Matthews, Simon Dowland, Iain A. Wright, Clare P. Grey, Richard H. Friend and Hugo Bronstein
Pubblicato in: Journal of Materials Chemistry C, 2022, ISSN 2050-7526
Editore: Royal Society of Chemistry
DOI: 10.1039/d1tc04753a

Graphite Anodes for Li-Ion Batteries: An Electron Paramagnetic Resonance Investigation

Autori: Insinna, Teresa; Bassey, Euan N; Märker, Katharina; Collauto, Alberto; Barra, Anne-Laure; Grey, Clare P
Pubblicato in: "Chemistry of Materials, 2023, 35 (14), pp.5497-5511. ⟨10.1021/acs.chemmater.3c00860⟩", Numero 3, 2023, ISSN 0897-4756
Editore: American Chemical Society
DOI: 10.1021/acs.chemmater.3c00860

Lithium Diffusion in Niobium Tungsten Oxide Shear Structures

Autori: Can P. Koçer, Kent J. Griffith, Clare P. Grey, Andrew J. Morris
Pubblicato in: Chemistry of Materials, Numero 32/9, 2020, Pagina/e 3980-3989, ISSN 0897-4756
Editore: American Chemical Society
DOI: 10.1021/acs.chemmater.0c00483

Stabilized tilted-octahedra halide perovskites inhibit local formation of performance-limiting phases

Autori: By:Doherty, TAS (Doherty, Tiarnan A. S.) [1] ; Nagane, S (Nagane, Satyawan) [1] ; Kubicki, DJ (Kubicki, Dominik J.) [1] , [2] ; Jung, YK (Jung, Young-Kwang) [3] ; Johnstone, DN (Johnstone, Duncan N.) [4] ; Iqbal, AN (Iqbal, Affan N.) [1] , [5] ; Guo, DY (Guo, Dengyang) [1] , [5] ; Frohna, K (Frohna, Kyle) [1] ; Danaie, M (Danaie, Mohsen) [6] , [7] ; Tennyson, EM (Tennyson, Elizabeth M.) [1] ; Macp
Pubblicato in: Science, 2021, ISSN 0036-8075
Editore: American Association for the Advancement of Science
DOI: 10.1126/science.abl4890

Two electrolyte decomposition pathways at nickel-rich cathode surfaces in lithium-ion batteries.

Autori: Bernardine L. D. Rinkel; J. Padmanabhan Vivek; Nuria Garcia-Araez; Clare P. Grey
Pubblicato in: Energy and Environmental Sciences, Numero 1, 2022, ISSN 1754-5692
Editore: Royal Society of Chemistry
DOI: 10.17863/cam.86241

NMR Methodology for Measuring Dissolved O<sub>2</sub> and Transport in Lithium–Air Batteries

Autori: Wang, Evelyna; Jónsson, Erlendur; Grey, Clare P
Pubblicato in: Crossref, Numero 3, 2023, ISSN 1932-7447
Editore: American Chemical Society
DOI: 10.1021/acs.jpcc.3c00991

Clarifying the Dopant Local Structure and Effect on Ionic Conductivity in Garnet Solid-State Electrolytes for Lithium-Ion Batteries

Autori: Vema, Sundeep; Berge, Astrid H; Nagendran, Supreeth; Grey, Clare P
Pubblicato in: Crossref, Numero 2, 2023, ISSN 0897-4756
Editore: American Chemical Society
DOI: 10.1021/acs.chemmater.3c01831

Noninvasive In Situ NMR Study of “Dead Lithium” Formation and Lithium Corrosion in Full-Cell Lithium Metal Batteries

Autori: Anna B. Gunnarsdóttir, Chibueze V. Amanchukwu, Svetlana Menkin, Clare P. Grey
Pubblicato in: Journal of the American Chemical Society, Numero 142/49, 2020, Pagina/e 20814-20827, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.0c10258

3D Nanocomposite Thin Film Cathodes for Micro‐Batteries with Enhanced High‐Rate Electrochemical Performance over Planar Films

Autori: Lovett, Adam J.; Daramalla, Venkateswarlu; Nayak, Debasis; Sayed, Farheen N.; Mahadevegowda, Amoghavarsha; Ducati, Caterina; Spencer, Ben F.; Dutton, Siân E.; Grey, Clare P.; MacManus‐Driscoll, Judith L.
Pubblicato in: Advanced Energy Materials, Numero 3, 2023, ISSN 1614-6832
Editore: Wiley-VCH Verlag
DOI: 10.1002/aenm.202302053

Sodium Tetrakis(hexafluoroisopropyloxy)aluminates: Synthesis and Electrochemical Characterisation of a Room‐Temperature Solvated Ionic Liquid

Autori: Darren M. C. Ould; Svetlana Menkin; Holly E. Smith; Víctor Riesgo‐González; Thomas H. Smith; Melissa N. B. Chinn; Erlendur Jónsson; Andrew D. Bond; Clare P. Grey; Dominic S. Wright
Pubblicato in: ChemElectroChem, Vol 11, Iss 2, Pp n/a-n/a (2024), Numero 3, 2024, ISSN 2196-0216
Editore: Wiley-VCH GmbH
DOI: 10.1002/celc.202300381

Spiers Memorial Lecture: Lithium air batteries – tracking function and failure

Autori: Fritzke, Jana B; Ellison, James HJ; Brazel, Laurence; Horwitz, Gabriela; Menkin, Svetlana; Grey, Clare P
Pubblicato in: Crossref, Numero 3, 2024, ISSN 1359-6640
Editore: Royal Society of Chemistry
DOI: 10.1039/d3fd00154g

Understanding the Surface Regeneration and Reactivity of Garnet Solid-State Electrolytes

Autori: Vema, Sundeep; Sayed, Farheen N; Nagendran, Supreeth; Karagoz, Burcu; Sternemann, Christian; Paulus, Michael; Held, Georg; Grey, Clare P
Pubblicato in: Crossref, Numero 2, 2023, ISSN 2380-8195
Editore: American Chemical Society
DOI: 10.1021/acsenergylett.3c01042

Interactions of Oxide Surfaces with Water Revealed with Solid-State NMR Spectroscopy

Autori: Junchao Chen, Michael A. Hope, Zhiye Lin, Meng Wang, Tao Liu, David M. Halat, Yujie Wen, Teng Chen, Xiaokang Ke, Pieter C. M. M. Magusin, Weiping Ding, Xifeng Xia, Xin-Ping Wu, Xue-Qing Gong, Clare P. Grey, Luming Peng
Pubblicato in: Journal of the American Chemical Society, Numero 142/25, 2020, Pagina/e 11173-11182, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.0c03760

Investigating the effect of a fluoroethylene carbonate additive on lithium deposition and the solid electrolyte interphase spectroscopy

Autori: Gunnarsdóttir, A., Vema, S., Menkin, S., Marbella, L., & Grey, C.
Pubblicato in: Journal of Materials Chemistry A, 2020, ISSN 2050-7488
Editore: Royal Society of Chemistry
DOI: 10.17863/cam.54707

Stable Hexylphosphonate-Capped Blue-Emitting Quantum-Confined CsPbBr 3 Nanoplatelets

Autori: Javad Shamsi, Dominik Kubicki, Miguel Anaya, Yun Liu, Kangyu Ji, Kyle Frohna, Clare P. Grey, Richard H. Friend, Samuel D. Stranks
Pubblicato in: ACS Energy Letters, Numero 5/6, 2020, Pagina/e 1900-1907, ISSN 2380-8195
Editore: American Chemical Society
DOI: 10.1021/acsenergylett.0c00935

Solvent-dependent iodide interactions in LiO<sub>2</sub> electrolytes – a molecular dynamics study

Autori: Erlendur Jónsson; Astrid H. Berge; Clare P. Grey; Israel Temprano
Pubblicato in: Crossref, Numero 2, 2024, ISSN 1359-6640
Editore: Royal Society of Chemistry
DOI: 10.1039/d3fd00090g

Designing for conjugate addition: an amine functionalised quinone anolyte for redox flow batteries

Autori: Jethwa, RB (Jethwa, Rajesh B.); Zhao, EW (Zhao, Evan Wenbo); Kerber, RN (Kerber, Rachel N.); Jonsson, E (Jonsson, Erlendur); Wright, DS (Wright, Dominic S.); Grey, CP (Grey, Clare P.)
Pubblicato in: Journal of Materials Chemistry A, 2021, ISSN 2050-7488
Editore: Royal Society of Chemistry
DOI: 10.1039/d1ta02870g

Enhanced visible light absorption in layered Cs3Bi2Br9 through mixed-valence Sn(ii)/Sn(iv) doping.

Autori: Chantalle J Krajewska; Seán R. Kavanagh; Seán R. Kavanagh; Lina Zhang; Dominik J. Kubicki; Krishanu Dey; Krzysztof Galkowski; Krzysztof Galkowski; Krzysztof Galkowski; Clare P. Grey; Samuel D. Stranks; Aron Walsh; Aron Walsh; David O. Scanlon; Robert G. Palgrave
Pubblicato in: Chemical Science, Numero 3, 2021, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d1sc03775g

Potentiometric MRI of a Superconcentrated Lithium Electrolyte: Testing the Irreversible Thermodynamics Approach.

Autori: Andrew Wang; Anna B. Gunnarsdóttir; Jack Fawdon; Mauro Pasta; Clare P. Grey; Charles W. Monroe
Pubblicato in: ACS Energy Letters, Numero 1, 2021, ISSN 2380-8195
Editore: American Chemical Society
DOI: 10.17863/cam.77359

Mesoscopic simulations of the in situ NMR spectra of porous carbon based supercapacitors: electronic structure and adsorbent reorganisation effects.

Autori: Anagha Sasikumar; Anouar Belhboub; Camille Bacon; Alexander C. Forse; John M. Griffin; Clare P. Grey; Patrice Simon; Céline Merlet
Pubblicato in: Phys Chem Chem Phys, Numero 2, 2021, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.1039/d1cp02130c

Triarylamines as Catholytes in Aqueous Organic Redox Flow Batteries

Autori: Nadia L. Farag; Rajesh B. Jethwa; Alice E. Beardmore; Teresa Insinna; Christopher A. O'Keefe; Peter A. A. Klusener; Clare P. Grey; Dominic S. Wright
Pubblicato in: Crossref, Numero 2, 2023, ISSN 1864-5631
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202300128

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