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Photoelectrochemical Solar Light Conversion into Fuels on Colloidal Quantum Dots Based Photoanodes

Project description

High-efficiency photoanodes for solar water splitting

Hydrogen is a clean-burning fuel that only produces water when it is burned. One of the biggest hurdles holding back solar water splitting for hydrogen production is finding an efficient semiconductor material for use in the photoanode, and this is exctly what the QuantumSolarFuels project is investigating. The project team is synthesising colloidal quantum dots from solution. Integrating cadmium-based quantum dots into photoanodes is particularly attractive for producing stable photoelectrodes because of their low manufacturing costs and their tuneable band gap. If successful, the project will greatly encourage widespread industry adoption of solar water splitting technologies.

Objective

The efficient use of solar energy is vital for the future of our Planet and to ensure to the next generations our and even
superior welfare standards. Photoelectrochemical water splitting is a promising way to convert solar light into storable fuels,
such as H2. However, an ideal photoanodic material for the oxygen evolution half-reaction has not been identified yet.
Technologies based on solution-processed colloidal quantum dots (CQDs) are promising for producing effective
photoanodes because of their low manufacturing costs and the possibility of controlling the band gap of the material through
the quantum size effect.
The main scientific aim of the QuantumSolarFuels project is the preparation of photoanodes for water splitting based on
CdSe, CdTe and CdSeTe CQDs and their protection against photocorrosion. The CQDs will be assembled in flat electrodes
effectively protected against photocorrosion and activated toward water oxidation through: a) the deposition of amorphous
TiO2 and subsequent coating with metal based oxygen evolution catalysts or b) by direct coating them with the oxygen
evolution catalysts.
Further objectives are: 1) the identification of the optimal CdSeTe composition and CQDs size for the preparation of efficient
photoanodes; 2) the use of Cd-chalcogenide CQDs in solar cells and photo- and electro-catalysis for renewable fuels
production.
Thanks to this action the researcher will become a World expert in these areas, in particular in the innovative use of CQDs
for photoelectrochemical water splitting applications.
Taking full advantage of the complementary competences of the two involved research groups, the one at the beneficiary
institution expert in the fundamental chemical aspects of photocatalysis and the partner group more focused on the
engineering and industrial exploitation of CQD science, the QuantumSolarFuels project will provide crucial achievements for
the future preparation of industrially compelling photoelectrochemical devices.

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Keywords

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Programme(s)

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Topic(s)

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Funding Scheme

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MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) H2020-MSCA-IF-2018

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Coordinator

UNIVERSITA DEGLI STUDI DI MILANO
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 237 768,00
Address
Via Festa Del Perdono 7
20122 Milano
Italy

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Region
Nord-Ovest Lombardia Milano
Activity type
Higher or Secondary Education Establishments
Links
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 237 768,00

Partners (1)

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