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Design and engineering of porous nitride-based materials as a platform for CO2 photoreduction

Project description

Photocatalysis on the way to CO2 reduction

The European Energy Roadmap 2050 aims to ensure energy security and sustainability in future decarbonised economies. It is necessary to find efficient pathways towards solar power production. The use of CO2 to limit carbonisation requires accurate research on CO2 photoreduction, which still remains unsatisfactorily studied. This is because, although photocatalysis is a potential pathway, the creation of an effective and reliable photocatalyst is still difficult. The EU-funded THEIA project suggests a new class of photocatalysts that emerges from the combination of catalysis, materials science and engineering. The proposal studies the properties of porous boron nitride (BN) to imbue it with key properties for CO2 reduction via photocatalysis.

Objective

CONTEXT: Reshaping our energy portfolio considering the sustainability of global energy resources is central to the European Energy Roadmap 2050. Hence, researchers need to identify efficient routes towards solar fuels production. Unlike H2 evolution, CO2 photoreduction has been poorly studied. Given the scope for CO2 utilisation in a carbon-constrained future, there is an exciting opportunity to devote targeted research towards CO2 photoreduction. Photocatalysis is one route towards CO2 reduction. Yet, the design of a cost-effective, sustainable, efficient and robust photocatalyst remains a highly challenging task.
PROPOSAL: I propose to merge catalysis, materials science and engineering to develop a radically new class of photocatalysts, i.e. porous boron nitride (BN)-based materials for CO2 reduction. My approach is opposite to current research trends which explore non-crystalline and non-porous materials, and aims to compete with the 40-year old benchmark in the field, TiO2. Porous BN combines key attributes for CO2 photoreduction: (i) chemical, structural and optoelectronic tunability, (ii) high porosity, (iii) semi-crystalline to amorphous nature. These features provide unique pathways towards effective sorption of reactants/products, facile band gap engineering, and enhanced surface charge transfer. Their semi-crystalline to amorphous nature may facilitate scale-up.
IMPACT: I will address three major challenges:
1. Creating a porous BN-based material platform with adsorptive and photocatalytic functionalities
2. Adding a new dimension to photocatalyst design via porosity control
3. Creating approaches to molecular- and micro-structure engineering in porous BN
Realization of these advances would lead towards a dream photocatalyst with integrated adsorptive, optoelectronic and catalytic functionalities. The impact will benefit fields for which interfacial phenomena are key: molecular separation, catalysis and drug delivery.

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Keywords

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Programme(s)

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Topic(s)

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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

ERC-STG - Starting Grant

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Call for proposal

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(opens in new window) ERC-2019-STG

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Host institution

IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 1 498 934,00
Address
SOUTH KENSINGTON CAMPUS EXHIBITION ROAD
SW7 2AZ London
United Kingdom

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Region
London Inner London — West Westminster
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 1 498 934,00

Beneficiaries (1)

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