C-H Activation for Industrial Renewal

Deliverables

Witing of regular reports on dissemination actions M12243648

Preparation of the announcements for the ESR positions and their publication following the conditions specified in CA

Publications

Electrocatalytic Formal C(sp2)−H Alkylations via Nickel‐Catalyzed Cross‐Electrophile Coupling with Versatile Arylsulfonium Salts

Author(s): Takuya Michiyuki, Simon L. Homölle, Neeraj K. Pandit, Lutz Ackermann
Published in: Angewandte Chemie International Edition, Issue 63, 2024, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202401198

Ruthenium-Catalyzed Aminocarbonylation with Isocyanates Through Weak Coordinating Groups

Author(s): Elisa Y. Lai, Binbin Yuan, Prof. Dr. Lutz Ackermann, Dr. Magnus J. Johansson
Published in: Chemistry A European Journal, 2023, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202302023

Gold-Catalyzed 1,2-Aryl Shift and Double Alkyne Benzannulation

Author(s): Gana Sanil, Maciej Krzeszewski, Wojciech Chaładaj, Witold Danikiewicz, Iryna Knysh, Łukasz Dobrzycki, Olga Staszewska-Krajewska, Michał K. Cyrański, Denis Jacquemin and Daniel T. Gryko
Published in: Angewandte Chemie International Edition, Issue e202311123, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202311123

C1‐4 Alkylation of Aryl Bromides with Light Alkanes enabled by Metallaphotocatalysis in Flow

Author(s): Antonio Pulcinella, Prakash Chandra Tiwari, Alberto Luridiana, Ken Yamazaki, Daniele Mazzarella, Akshay K. Sadhoe, Antonella Ilenia Alfano, Eveline H. Tiekink, Trevor A. Hamlin, Timothy Noel
Published in: Angewandte Chemie International Edition, 2024, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202413846

Late-stage peptide labeling with near-infrared fluorogenic nitrobenzodiazoles by manganese-catalyzed C–H activation

Author(s): Tsuyoshi Oyama, Lorena Mendive-Tapia, Verity Cowell, Adelina Kopp, Marc Vendrell and Lutz Ackermann
Published in: Chemical Science, Issue 14, 2023, Page(s) 5728-5733, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc01868g

Fluorescent coumarin-alkynes for labeling of amino acids and peptides via manganese(<scp>i</scp>)-catalyzed C–H alkenylation

Author(s): Adelina Kopp, Tsuyoshi Oyama, Lutz Ackermann
Published in: Chemical Communications, Issue 60, 2024, Page(s) 5423-5426, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4cc00361f

Do we really need ligands in Ir-catalyzed C–H borylation?

Author(s): Janis M. Zakis, Simone L. Kuhn, Joanna Wencel-Delord, Tomas Smejkal
Published in: CHIMIA, Issue 78, 2024, Page(s) 513-517, ISSN 0009-4293
Publisher: Schweizerische Chemische Gedellschaft
DOI: 10.2533/chimia.2024.513

Homogeneous catalytic C(sp 3 )–H functionalization of gaseous alkanes

Author(s): Antonio Pulcinella, Daniele Mazzarella, Timothy Noël
Published in: Chemical Communications, 2021, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc04073a

Micellar catalysis: a green solution to enable undirected and mild C–H activation of (oligo)thiophenes at the challenging β-position

Author(s): Pascal Hauk, Valérie Mazan, Fabrice Gallou and Joanna Wencel-Delord
Published in: Chemical Science, 2023, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc03708h

Manganese(I)-Catalyzed C–H Allylation of Tryptophans and Their Oligopeptides On Water

Author(s): Julia Struwe, Tsuyoshi Oyama, Fabrice Gallou, Lutz Ackermann
Published in: Synlett, Issue 35, 2024, ISSN 0936-5214
Publisher: Georg Thieme Verlag
DOI: 10.1055/a-2268-4678

Cyclometallated complexes as catalysts for C–H activation and functionalization

Author(s): Janis Mikelis Zakis, Tomas Smejkal, Joanna Wencel-Delord
Published in: Chemical Communications, 2021, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc05195d

Air-stable bis-cyclometallated iridium catalysts for ortho-directed C(sp2)–H borylation

Author(s): Janis Zakis, Antonis Messinis, Lutz Ackermann, Tomas Smejkal, Joanna Wencel-Delord
Published in: Advanced Synthesis & Catalysis, 2024, ISSN 1615-4150
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adsc.202301411

Easy access to polyhalogenated biaryls: regioselective (di)halogenation of hypervalent bromines and chlorines

Author(s): Daniel Carter Martos, Maxime de Abreu, Pascal Hauk, Philipp Fackler and Joanna Wencel-Delord
Published in: Chemical Science, Issue 15, 2024, Page(s) 6770-6776, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4sc01234h

The Vinyl Group: Small but Mighty – Transition Metal Catalyzed and Non‐Catalyzed Vinylation Reactions

Author(s): Eleni Papaplioura, Maëva Mercier, Soufyan Jerhaoui, Michael Schnürch
Published in: ChemCatChem, 2024, ISSN 1867-3880
Publisher: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.202400513

Photocatalytic Functionalization of Dehydroalanine-Derived Peptides in Batch and Flow

Author(s): Nikolaos Kaplaneris, Merve Akdeniz, Méritxell Fillols, Francesca Arrighi, Fabian Raymenants, Gana Sanil, Daniel T. Gryko, Timothy Noel
Published in: Angewandte Chemie International Edition, 2024, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202403271

Organic synthesis in Aqueous Multiphase Systems — Challenges and opportunities ahead of us

Author(s): Pascal Hauk, Joanna Wencel-Delord, Lutz Ackermann, Peter Walde, Fabrice Gallou
Published in: Current Opinion in Colloid & Interface Science, Issue 56, 2021, Page(s) 101506, ISSN 1359-0294
Publisher: Pergamon Press
DOI: 10.1016/j.cocis.2021.101506

Photocatalytic Alkylation of C(sp 3 )−H Bonds Using Sulfonylhydrazones**

Author(s): Antonio Pulcinella; Stefano Bonciolini; Florian Lukas; Andrea Sorato; Timothy Noël
Published in: Angewandte Chemie, 135(3):e202215374., Issue 1, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202215374

Modular allylation of C(sp3)−H bonds by combining decatungstate photocatalysis and HWE olefination in flow

Author(s): Luca Capaldo, Stefano Bonciolini, Antonio Pulcinella, Manuel Nuno and Timothy Noel
Published in: Chemical Science, 2022, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc01581a

Tetraethylammonium Salts as Solid, Easy to Handle Ethylene Precursors and Their Application in Mizoroki–Heck Coupling

Author(s): Eleni Papaplioura, Maëva Mercier, Michael E. Muratore, Tobias Biberger, Soufyan Jerhaoui, and Michael Schnürch
Published in: The Journal of Organic Chemistry, 2024, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.3c02867

Rapid and Direct Photocatalytic C(sp3)‒H Acylation and Arylation in Flow

Author(s): Daniele Mazzarella, Antonio Pulcinella, Loic Bovy, Remy Broersma, Timothy Noel
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202108987

Photo‐Induced Ruthenium‐Catalyzed C−H Arylation Polymerization at Ambient Temperature

Author(s): Takuya Michiyuki, Isaac Maksso, Lutz Ackermann
Published in: Angewandte Chemie International Edition, Issue 63, 2024, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202400845

2-(o-Tolyl) Pyridine as Ligand Improves the Efficiency in Ketone Directed ortho-Arylation

Author(s): Nanditha Kattukudiyil Narayanan, Prof. Dr. Ernst Pittenauer, Prof. Dr. Michael Schnürch
Published in: European Journal of Organic Chemistry, 2023, ISSN 1434-193X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.202300759

Metal-free photocatalytic cross-electrophile coupling enables C1 homologation and alkylation of carboxylic acids with aldehydes

Author(s): Stefano Bonciolini, Antonio Pulcinella, Matteo Leone, Debora Schiroli, Adrián Luguera Ruiz, Andrea Sorato, Maryne A. J. Dubois, Ranganath Gopalakrishnan, Geraldine Masson, Nicola Della Ca’, Stefano Protti, Maurizio Fagnoni, Eli Zysman-Colman, Magnus Johansson, Timothy Noël
Published in: Nature Communications, 2024, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-024-45804-z

Efficient synthesis of 2‐arylpropionitriles via selective monomethylation of aryl acetonitriles using an easy to handle methylation agent

Author(s): Eleni Papaplioura, Johanna Templ, Nina Wildhack, Michael Schnürch
Published in: European Journal of Organic Chemistry, 2024, ISSN 1434-193X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.202400693

Remote C−H Glycosylation by Ruthenium(II) Catalysis: Modular Assembly of meta-C-Aryl Glycosides

Author(s): Jun Wu, Dr. Nikolaos Kaplaneris, Julia Pöhlmann, Takuya Michiyuki, Binbin Yuan, Prof. Dr. Lutz Ackermann
Published in: Angew Chem. Int. Ed., 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202208620

Pd-Catalyzed C(sp2)–H/C(sp2)–H Coupling of Limonene

Author(s): Marco Di Matteo, Anna Gagliardi, Alexandre Pradal, Luis F. Veiros, Fabrice Gallou, Giovanni Poli
Published in: The Journal of Organic Chemistry, Issue 89, 2024, Page(s) 10451-10461, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.4c00501

The chemistry of 1,4-dihydropyrrolo[3,2-b]pyrroles

Author(s): Gana Sanil, Beata Koszarna, Yevgen M.Poronik, Olena Vakuliuk, Bartosz Szymański, Damian Kusy, Daniel T. Gryko
Published in: Advances in Heterocyclic Chemistry, 2022, Page(s) 335-409
Publisher: Elsevier
DOI: 10.1016/bs.aihch.2022.04.002

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