Boosting Cation Exchange in Self-Assembled Supraparticles through Advanced Electron Tomography Techniques

Projektinformationen

SuprAtom

ID Finanzhilfevereinbarung: 894254

DOI

10.3030/894254

Projekt abgeschlossen

EK-Unterschriftsdatum 25 Februar 2020

Startdatum 1 April 2020

Enddatum 31 März 2022

Finanziert unter

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Gesamtkosten

€ 178 320,00

EU-Beitrag

€ 178 320,00

Koordiniert durch

UNIVERSITEIT ANTWERPEN
Belgium

Periodic Reporting for period 1 - SuprAtom (Boosting Cation Exchange in Self-Assembled Supraparticles through Advanced Electron Tomography Techniques)

Berichtszeitraum: 2020-04-01 bis 2022-03-31

Zusammenfassung vom Kontext und den Gesamtzielen des Projekts

The motivation of the project is to establish a robust route to structuring multicomponent colloidal self-assemblies in a controllable manner. Compared to single component SPs, it is still challenging to design multicomponent SPs as the parameter space to achieve the optimum thermodynamics and kinetic effects is large. Therefore, a new synthesis approach is required. In this project, one of the objectives was to develop methodology, mostly focusing on synthesis multicomponent supraparticles using cation exchange (CE) on already formed colloidal self-assemblies. By controlling the CE reactions, one can synthesize hierarchical superstructures with controllable compositions on multiple length scales. Such structure can eventually have great potential as photocatalysts and photovoltaics due to the ability to control their optoelectronic properties via their tuneable composition and structure. In order to understand why and how the hierarchical multi-component supraparticles form, a robust advanced characterization toolbox needs to be urgently developed. Especially, to track the structure and composition structures in real conditions becomes to be crucial.

Arbeit, die ab Beginn des Projekts bis zum Ende des durch den Bericht erfassten Berichtszeitraums geleistet wurde, und die wichtigsten bis dahin erzielten Ergebnisse

During this project, I developed different types of colloidal self-assemblies by using the slowly drying emulsion droplets method, forming the so-called supraparticles, including CdSe, FeMnZn/CdSe, and FeCoO/CdSe supraparticles containing anisotropic/isotropic building blocks, which are not trivial to realize before. Performing cation exchange on supraparticles lead to even more complex hierarchical superstructure , which otherwise cannot be achieved via conventional self-assembly routines. The emergence of multi-component colloidal supraparticles further expanded the library of hierarchical colloids, but also provided ideal experimental platform for the study of formation and driving forces of soft condense matter. By teaming up the EMAT research team, I developed high-throughput in-situ liquid tomography and fast tomography techniques for supraparticles. Advanced electron tomographic reconstructions procedures have been established. Quantitative and qualitative comparison between conventional and high-throughput tomography validated reliability of new acquisition, alignment, and reconstruction. During this project, I was invited to give talks regarding my research in conference and symposium.

Fortschritte, die über den aktuellen Stand der Technik hinausgehen und voraussichtliche potenzielle Auswirkungen (einschließlich der bis dato erzielten sozioökonomischen Auswirkungen und weiter gefassten gesellschaftlichen Auswirkungen des Projekts)

The abovementioned research progress not only deliver new fundamental understanding on colloidal self-assembly on multiple length scales, but the results are also expected to yield new insights concerning functionalities of colloidal self-assemblies in potential optoelectronic applications. It is envisaged that the success of making multicomponent supraparticles will bring new opportunities to optoelectronic (nano)devices fabrication and catalysis in the future. Moreover, the research progress pushed the development of advanced transmission electron microscopy techniques to a new limit. Specifically, a novel data tomography data acquisition scheme and a reconstruction method for large, compact colloidal self-assemblies has been established. The development of in-situ tomography technique allows to study the structure of colloidal assemblies in their native (real) environment.

An example of cation exchanged binary supraparticle