Nanoscale Chemical Imaging of MXene Electrochemical Storage by Operando Scanning X-ray Microscopy

Projektinformationen

NANOMXM

ID Finanzhilfevereinbarung: 947852

DOI

10.3030/947852

EK-Unterschriftsdatum 8 Oktober 2020

Startdatum 1 Februar 2021

Enddatum 30 November 2026

Finanziert unter

• EXCELLENT SCIENCE - European Research Council (ERC)

Gesamtkosten

€ 1 500 000,00

EU-Beitrag

€ 1 500 000,00

Koordiniert durch

HELMHOLTZ-ZENTRUM BERLIN FUR MATERIALIEN UND ENERGIE GMBH
Germany

Periodic Reporting for period 3 - NANOMXM (Nanoscale Chemical Imaging of MXene Electrochemical Storage by Operando Scanning X-ray Microscopy)

Berichtszeitraum: 2024-02-01 bis 2025-07-31

Zusammenfassung vom Kontext und den Gesamtzielen des Projekts

Finding efficient ways to store and deliver electrical energy is urgently needed for the large-scale development of renewable energy sources. The use of pseudocapacitive materials, such as 2D transition metal carbides and nitrides, so-called MXenes, is an extremely promising solution to achieve electrochemical energy storage with high power and energy densities, benefiting from fast redox reactions on transition metal oxides. Such materials may allow the development of new electrical devices with reduced charging times despite keeping a high amount of stored energy. Nevertheless, local electrochemical processes occurring at the solid-liquid interface of pseudocapacitors are currently largely unexplored. The goal of this project is to image for the first time electrochemical processes occurring during pseudocapacitive electrochemical storage on MXenes at the nanoscale with operando Scanning Transmission X-ray microscopy (STXM). This will allow a better understanding of pseudocapacitive electrochemical energy storage that will enable the discovery of new 2D materials enabling ultrafast electrochemical energy storage devices.

Arbeit, die ab Beginn des Projekts bis zum Ende des durch den Bericht erfassten Berichtszeitraums geleistet wurde, und die wichtigsten bis dahin erzielten Ergebnisse

First operando experiments performed by infrared spectroscopy have evidenced that the confinement of the electrolyte between the MXene layers may play a significant role in the superior electrochemical performances of Ti3C2Tx MXenes in acidic environment and water-in-salt electrolytes. Furthermore, first MXenes materials were images using STXM at the synchrotron BESSY II. We also developed a custom electrochemical flow cell enabling STXM characterization of MXene in aqueous environment. Change of the titanium electronic structure in Ti3C2Tx MXenes single few-layered flakes was evidenced upon cation intercalation for the first time.

Fortschritte, die über den aktuellen Stand der Technik hinausgehen und voraussichtliche potenzielle Auswirkungen (einschließlich der bis dato erzielten sozioökonomischen Auswirkungen und weiter gefassten gesellschaftlichen Auswirkungen des Projekts)

Using both infrared spectroscopy and STXM, we have achieved spectroscopic identification of changes of both MXenes and the electrolyte during electrochemical cycling. These results have especially enabled to prove that the confined electrolyte within the MXene interlayer have a different structure than bulk electrolyte, which may play a significant role in pseudocapacitive energy storage. Furthermore, we have achieved major breakthroughs in operando STXM by being able to image single MXene layers directly in acidic and neutral aqueous electrolytes. I anticipate that by the end of the project, we will have unravelled how intercalated ion do interact with the MXene surface chemistry. We may also discover how defects in MXene facilitate hydrolysis and other MXene degradation mechanisms in aqueous environment.