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Contenuto archiviato il 2024-04-30

Porous inorganic catalytic films and membranes for pollution removal applications

Obiettivo



This project aims the implementation of porous thin films and membranes in the outlet elements of combustion installations to be use as catalysts for the removal of pollutants. Small (e.g. domestic heating installations) and medium plants would be the typical areas of application of the technology developed in the project. The reaction that these porous films had to catalyze is the reduction of NOx with hydrocarbons in the presence of oxygen. These gas components are normal in many burning plants and diesel engines. The objective of these studies is the integration of catalysts in the form of porous thin films in the elements (e.g. heat exchange elements, outlet tubes, etc.) of these installations without a significant modification of their structure or building pieces. Advantages of this strategy are a significant decrease of the implementation costs of the catalysts, low pressure drops, good heat management, low attrition of the active phase, etc. To achieve a good performance of the catalyst films new methods of deposition of these porous films in form of membranes will be developed in the project. These methods involve the deposition by sol/gel techniques, plasma enhanced CVD or magnetron sputtering procedures of single or mixed oxide porous films where active metals will be dispersed.
To achieve a good adherence on the metal support while keeping at the same time an optimal chemical reactivity, a gradient in composition and porosity will be intended for these films.
Preparation, characterization and catalytic tests will be carried out with these porous films in order to improve their performance for the removal of NOx. As a final deliverable of the project it will be constructed a prototype reactor working under the conditions of the exhaust elements of combustion plants. This reactor will be automatically controlled (adjustment of parameters as temperature, concentration of reactants, etc.)through a feed-back system utilizing a gas sensor device for the control of the gas composition. The gas sensing device will consist of commercial sensor elements modified by deposition of thin membranes on their surface. These membranes, of different thickness, composition and microporous structure, will be deposited on the surface of the sensing elements in order to increase their selectivity in respect to a certain molecule (e.g. NOx, hydrocarbons) while, at the same time, preserving the sensor surface from degradation in the drastic conditions existing in the outlet tubes. Deposition and testing of these modified sensor elements will be other tasks to be undertaken during the development of the project.
At he end a self-sustained reactor prototype should be available where NOx abatement is possible by reactions catalyzed by deposited thin films.

Campo scientifico (EuroSciVoc)

CORDIS classifica i progetti con EuroSciVoc, una tassonomia multilingue dei campi scientifici, attraverso un processo semi-automatico basato su tecniche NLP. Cfr.: Il Vocabolario Scientifico Europeo.

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Coordinatore

Consejo Superior de Investigaciones Cientòficas
Contributo UE
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Indirizzo
Avenida Américo Vespucio
41092 Sevilla
Spagna

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Costo totale

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