The role of peroxo-metal complexes in oxidations related to synthetically, environmentally and biologically relevant processes

Informazioni relative al progetto

ID dell’accordo di sovvenzione: INTAS-94-1515

Progetto chiuso

Data di avvio 1 Febbraio 1995

Data di completamento 31 Gennaio 1997

Finanziato da

• International Association for the promotion of cooperation with scientists from the independent states of the former Soviet Union (INTAS), 1993-

Costo totale

Nessun dato

Contributo UE

€ 50 000,00

Coordinato da

Università degli Studi di Padova
Italy

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Risultati sfruttabili

The role of peroxo-metal complexes in oxidations related to synthetically, environmentally and biologically relevant processes

The main activities of the project carried out have concentrated on : Structure Reactivity Studies of V(V) peroxocomplexes in aqueous solutions. Models for vanadium bromoperoxidases. Enantioselective Titanium-Catalysed Sulphides. (Padova group) Metal-catalysed oxidations by sodium percarbonate and Palladium-catalysed alcohol oxidations. (Reims Group) Ozone formation; Oxidation of the difficult-to-oxidise substrates in Vv/H2O2/CF3COOH system; Singlet dioxygen formation; Oxidation reactions with the Vv/H2O2/AcOH system; Channels of co-ordinated singlet dioxygen consumption; Unexpected acceleration of H2O2 oxidations by BHT additives. (Moscow Group) Spectroscopic characterisation of Titanium(IV) alkylperoxo complexes and ferric hydroperoxo complexes. (Novosibirsk group) The work has been accomplished by using spectroscopic techniques and reactivity studies.