Simultaneous transformation of ambient heat and undesired vibrations into electricity via nanotriboelectrification during non-wetting liquid intrusion-extrusion into-from nanopores

Projektinformationen

Electro-Intrusion

ID Finanzhilfevereinbarung: 101017858

DOI

10.3030/101017858

Projekt abgeschlossen

EK-Unterschriftsdatum 2 Dezember 2020

Startdatum 1 Januar 2021

Enddatum 31 Dezember 2025

Finanziert unter

• EXCELLENT SCIENCE - Future and Emerging Technologies (FET)

Gesamtkosten

€ 3 651 381,25

EU-Beitrag

€ 3 651 381,25

Koordiniert durch

CENTRO DE INVESTIGACION COOPERATIVA DE ENERGIAS ALTERNATIVAS FUNDACION, CIC ENERGIGUNE FUNDAZIOA
Spain

CORDIS bietet Links zu öffentlichen Ergebnissen und Veröffentlichungen von HORIZONT-Projekten.

Links zu Ergebnissen und Veröffentlichungen von RP7-Projekten sowie Links zu einigen Typen spezifischer Ergebnisse wie Datensätzen und Software werden dynamisch von OpenAIRE abgerufen.

Leistungen

Documents, reports (5)

Cross-project collaboration plan

This deliverable will be coordinated with the other relevant projects 101017821 LIGHTCAP 101017928 HYSOLCHEM 101017709 EPISTORE The concrete crossproject collaboration activities will be reported in the subsequent reporting periods

Final Plan for Dissemination and Communication Activities

A final report will be prepared summarizing the communication and dissemination activities. Within this report we will also report our analysis and measurement of the effectiveness of the activities developed within WP6.

Optimal properties of porous materials and non-wetting liquids for nanotriboelectrification maximization during intrusion-extrusion process

This deliverable summarizes the experimental and simulation findings on the effect of tribopolarity, temperature, compression frequency, topology, surface area and pore size on triboelectrification during non-wetting liquid intrusion-extrusion. It contains recommendations on how to maximize electrical energy output for the Heterogeneous Lyophobic System (HLS) as well as validation of a model describing triboelectrification during int-ext.

Optimal properties of porous materials and non-wetting liquids for heat of intrusion-extrusion maximization

This deliverable summarizes the experimental and simulation findings on the effect of surface entropy, surface tension, contact angle, temperature, topology, on the heat of intrusion-extrusion. It contains recommendations on how to maximize the heat of intrusion-extrusion as well as validation of a model describing the heat of int-ext.

Dissemination and exploitation plan

This document describes the initiatives that will be undertaken by the members of the consortium to deliver i key information about the project to stakeholders those who are possibly impacted by the outcome of the project including the establishment of suitable for a twoway communication between the consortium and stakeholders ii communication with other related EU and national ongoing initiatives and networks iii engagement of decisionmakers and politicians to address among the others possible regulatory issues iv communication to the scientific community of the key questions that are investigated in the project and results have been obtained v engagement with endusers and the public society at broad This document will prevent ad hoc initiatives thus maximizing the impact of the project on every and each community potentially interested in our activity

Open Research Data Pilot (1)

Data management plan: Final Version

Data management plan: Final Version ofthe collection of guidelines to manage the technical data generated during the Electro-Intrusion project is to ensure the accessibility and intelligibility of the data that will be generated during the Electro-Intrusion project in order to comply with the Guidelines of the “Open Research Data Pilot”.

Websites, patent fillings, videos etc. (1)

Project website, visual identity and social media presence

The implementation of the dissemination plan requires a presence of the ElectronIntrusion project on the web and on social media a continuous that will be developed all along the project D62 concerns the creation of a web site of the project and the creation of accounts on the major social networks with their presentation and linking to communities possibly interested in the activities of the ElectronIntrusion project These tools will be used during the entire project as a reference point for dissemination of results

Veröffentlichungen

Peer reviewed articles (29)

Triboelectrification during non-wetting liquids intrusion–extrusion in hydrophobic nanoporous silicon monoliths

Autoren: Luis Bartolomé, Nicola Verziaggi, Manuel Brinker, Eder Amayuelas, Sebastiano Merchori, Mesude Z. Arkan, Raivis Eglītis, Andris Šutka, Mirosław Chorążewski, Patrick Huber, Simone Meloni, Yaroslav Grosu
Veröffentlicht in: Nano Energy, Ausgabe 146, 2025, Seite(n) 111488, ISSN 2211-2855
Herausgeber: Elsevier BV
DOI: 10.1016/j.nanoen.2025.111488

Tuning Wetting–Dewetting Thermomechanical Energy for Hydrophobic Nanopores via Preferential Intrusion

Autoren: Luis Bartolomé, Argyrios Anagnostopoulos, Alexander R. Lowe*, Piotr Ślęczkowski, Eder Amayuelas, Andrea Le Donne, Michał Wasiak, Mirosław Chora̧żewski*, Simone Meloni*, and Yaroslav Grosu*
Veröffentlicht in: J. Phys. Chem. Lett., 2024, ISSN 1948-7185
Herausgeber: American Chemical Society
DOI: 10.1021/acs.jpclett.3c03330

Optimization of the wetting-drying characteristics of hydrophobic metal organic frameworks via crystallite size: The role of hydrogen bonding between intruded and bulk liquid

Autoren: Liam J.W. Johnson, Gonçalo Paulo, Luis Bartolomé, Eder Amayuelas, Alberto Gubbiotti, Diego Mirani, Andrea Le Donne, Gabriel A. López, Giulia Grancini, Paweł Zajdel, Simone Meloni, Alberto Giacomello, Yaroslav Grosu
Veröffentlicht in: Journal of Colloid and Interface Science, Ausgabe 645, 2023, Seite(n) 775–783, ISSN 1095-7103
Herausgeber: Elsevier
DOI: 10.1016/j.jcis.2023.04.059

Exploring the Heat of Water Intrusion into a Metal Organic Framework by Experiment and Simulation

Autoren: A. R. Lowe,* P. Ślęczkowski, E. Arkan, A. Le Donne, L. Bartolomé, E. Amayuelas, P. Zajdel, M. Chora̧żewski,* Simone Meloni,* Yaroslav Grosu*
Veröffentlicht in: ACS Appl. Mat. Int., 2024, ISSN 1944-8244
Herausgeber: American Chemical Society
DOI: 10.1021/acsami.3c15447

Modelling and validation of shock absorption with tunable performance through liquid intrusion–extrusion cycles

Autoren: Song Yang, Weiwei Zhao, Yelaman Maksum, Victor Stoudenets, Leonid Listovshchyk, Monzer Al Sakka, Yaroslav Grosu, Yulong Ding
Veröffentlicht in: Scientific Reports, Ausgabe 15, 2025, ISSN 2045-2322
Herausgeber: Nature Publishing Group
DOI: 10.1038/s41598-025-23782-6

Crystallite Size Effects on the Heat of Water Intrusion/Extrusion into/from Metal–Organic Frameworks

Autoren: Liam J. W. Johnson, Alexander R. Lowe, Andrea Le Donne, Emre Arkan, Sebastiano Merchiori, Luis Bartolomé, Eder Amayuelas, Diego Mirani, Gabriel A. López, Giulia Grancini, Mirosław Chora̧żewski, Simone Meloni, Yaroslav Grosu
Veröffentlicht in: The Journal of Physical Chemistry Letters, Ausgabe 16, 2025, Seite(n) 2089-2096, ISSN 1948-7185
Herausgeber: American Chemical Society
DOI: 10.1021/acs.jpclett.4c02639

Effects of Size and Porosity on the Hydrophobicity of Hierarchical Nanoparticles

Autoren: Yuriy G. Bushuev
Veröffentlicht in: Nano Letters, Ausgabe 25, 2025, Seite(n) 3351-3356, ISSN 1530-6984
Herausgeber: American Chemical Society
DOI: 10.1021/acs.nanolett.5c00058

Adaptive MPPT: Boosting efficiency in heterogeneous power scenarios

Autoren: Weiwei Zhao, Lin Li,Yaroslav Grosu, Yulong Ding
Veröffentlicht in: Sustainable Energy Technologies and Assessments, 2024, ISSN 2213-1388
Herausgeber: Elsevier Limited
DOI: 10.1016/j.seta.2024.103843

Hydrophobicity of molecular-scale textured surfaces: the case of zeolitic imidazolate frameworks, an atomistic perspective

Autoren: A. Le Donne, J. D. Littlefair, M. Tortora, S. Merchiori, L. Bartolomé, Y. Grosu, S. Meloni
Veröffentlicht in: J. Chem. Phys, 2023, ISSN 0021-9606
Herausgeber: American Institute of Physics
DOI: 10.1063/5.0173110

Mechanism of Water Intrusion into Flexible ZIF-8: Liquid Is Not Vapor

Autoren: Eder Amayuelas, Marco Tortora, Luis Bartolomé, Josh David Littlefair, Gonçalo Paulo, Andrea Le Donne, Benjamin Trump, Andrey Andreevich Yakovenko, Mirosław Chorążewski, Alberto Giacomello, Paweł Zajdel, Simone Meloni, Yaroslav Grosu
Veröffentlicht in: Nano Letters, 2023, ISSN 1530-6984
Herausgeber: American Chemical Society
DOI: 10.1021/acs.nanolett.3c00235

Turning Molecular Springs into Nano-Shock Absorbers: The Effect of Macroscopic Morphology and Crystal Size on the Dynamic Hysteresis of Water Intrusion–Extrusion into-from Hydrophobic Nanopores

Autoren: Paweł Zajdel, David G. Madden, Robin Babu, Marco Tortora, Diego Mirani, Nikolay Nikolaevich Tsyrin, Luis Bartolomé, Eder Amayuelas, David Fairen-Jimenez, Alexander Rowland Lowe, Mirosław Chorążewski, Juscelino B. Leao, Craig M. Brown, Markus Bleuel, Victor Stoudenets, Carlo Massimo Casciola, María Echeverría, Francisco Bonilla, Giulia Grancini, Simone Meloni, and Yaroslav Grosu
Veröffentlicht in: ACS Applied Materials & Interfaces, Ausgabe 14, 2022, Seite(n) 6699–26713, ISSN 1944-8252
Herausgeber: American Chemical Society
DOI: 10.1021/acsami.2c04314

Quality-dependent performance of hydrophobic ZIF-67 upon high-pressure water intrusion–extrusion process

Autoren: Eder Amayuelas, *a Luis Bartolome´, a Yan Zhang,a Juan Miguel Lo´pez del Amo, a Oleksandr Bondarchuk,b Artem Nikulin,a Francisco Bonilla,a Elena Palomo del Barrio,ac Paweł Zajdel *d and Yaroslav Grosu
Veröffentlicht in: Phys Chem Chem Phys, 2024, ISSN 1463-9076
Herausgeber: Royal Society of Chemistry
DOI: 10.1039/d3cp03519k

Bimetallic Zeolitic Imidazole Frameworks for Improved Stability andPerformance of Intrusion−Extrusion Energy Applications

Autoren: Eder Amayuelas, Sandeep Kumar Sharma, Pranav Utpalla, Jaideep Mor, Luis Bartolomé, Marcus Carter, Benjamin Trump, Andrey Andreevich Yakovenko, Pawel Zajdel, and Yaroslav Grosu
Veröffentlicht in: J Phys Chem C, 2023, ISSN 1932-7447
Herausgeber: American Chemical Society
DOI: 10.1021/acs.jpcc.3c04368

Spontaneous Dipole Reorientation in Confined Water and Its Effect on Wetting/Dewetting of Hydrophobic Nanopores

Autoren: Yuriy G. Bushuev*, Yaroslav Grosu, and Mirosław Chorążewski
Veröffentlicht in: Applied Materials & Interfaces, 2024, ISSN 1944-8244
Herausgeber: American Chemical Society
DOI: 10.1021/acsami.3c17272

Effect of Crystallite Size on the Flexibility and Negative Compressibility of Hydrophobic Metal–Organic Frameworks

Autoren: L. J.W. Johnson, D. Mirani, A. Le Donne, L. Bartolomé, E. Amayuelas, G. A. López, G. Grancini, M. Carter, A. A. Yakovenko, B. A. Trump, S. Meloni, P. Zajdel, Y. Grosu
Veröffentlicht in: Nano letters, 2023, ISSN 1530-6984
Herausgeber: American Chemical Society
DOI: 10.1021/acs.nanolett.3c02431

The impact of secondary channels on the wetting properties of interconnected hydrophobic nanopores

Autoren: Gonçalo Paulo, Alberto Gubbiotti, Yaroslav Grosu, Simone Meloni & Alberto Giacomello
Veröffentlicht in: Communications physics, 2023, ISSN 2399-3650
Herausgeber: Springer Nature
DOI: 10.1038/s42005-023-01140-0

Understanding the Wettability of C₁N₁ (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes

Autoren: Irene Lamata‐Bermejo, Waldemar Keil, Karlo Nolkemper, Julian Heske, Janina Kossmann, Hossam Elgabarty, Martin Wortmann, Mirosław Chorążewski, Claudia Schmidt, Thomas D. Kühne, Nieves López‐Salas, Mateusz Odziomek
Veröffentlicht in: Angewandte Chemie International Edition, Ausgabe 63, 2024, ISSN 1433-7851
Herausgeber: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202411493

Local grafting heterogeneities control water intrusion and extrusion in nanopores

Autoren: Sonia Cambiaso, Fabio Rasera, Antonio Tinti, Davide Bochicchio, Yaroslav Grosu, Giulia Rossi, Alberto Giacomello
Veröffentlicht in: Communications Materials, Ausgabe 5, 2024, ISSN 2662-4443
Herausgeber: Springer Nature
DOI: 10.1038/s43246-024-00531-2

Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu₂(tebpz) MOF

Autoren: Sebastiano Merchiori, Andrea Le Donne, Ribhu Bhatia, Marta Alvelli, Jiang‐Jing Yu, Xu‐Dong Wu, Mian Li, Dan Li, Lukasz Scheller, Alexander R. Lowe, Monika Geppert‐Rybczynska, Benjamin A. Trump, Andrey A. Yakovenko, Mirosław Chorążewski, Paweł Zajdel, Yaroslav Grosu, Simone Meloni
Veröffentlicht in: Small, 2024, ISSN 1613-6810
Herausgeber: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/smll.202402173

Partial Water Intrusion and Extrusion in Hydrophobic Nanopores for Thermomechanical Energy Dissipation

Autoren: Gonçalo Paulo, Luis Bartolomé, Oleksandr Bondarchuk, Simone Meloni, Yaroslav Grosu, Alberto Giacomello
Veröffentlicht in: The Journal of Physical Chemistry C, Ausgabe 128, 2024, Seite(n) 12036-12045, ISSN 1932-7447
Herausgeber: American Chemical Society
DOI: 10.1021/acs.jpcc.4c02900

Bubbles enable volumetric negative compressibility in metastable elastocapillary systems

Autoren: Davide Caprini, Francesco Battista, Paweł Zajdel, Giovanni Di Muccio, Carlo Guardiani, Benjamin Trump, Marcus Carter, Andrey A. Yakovenko, Eder Amayuelas, Luis Bartolomé, Simone Meloni, Yaroslav Grosu, Carlo Massimo Casciola, Alberto Giacomello
Veröffentlicht in: Nature Communications, Ausgabe 15, 2024, ISSN 2041-1723
Herausgeber: Nature Publishing Group
DOI: 10.1038/s41467-024-49136-w

Subnanometer Topological Tuning of the Liquid Intrusion/Extrusion Characteristics of Hydrophobic Micropores

Autoren: Yuriy G. Bushuev, Yaroslav Grosu, Mirosław A. Chora̧żewski, Simone Meloni
Veröffentlicht in: Nano Letters, Ausgabe 22, 2022, Seite(n) 2164-2169, ISSN 1530-6992
Herausgeber: American Chemical Society
DOI: 10.1021/acs.nanolett.1c02140

Energetic Characteristics of Hydrophobic Porous Materials as Candidates for Manufacturing of Nanorockets

Autoren: Alexander R. Lowe, Mirosław A. Chora̧żewski, Yaroslav Grosu, Yuriy G. Bushuev
Veröffentlicht in: The Journal of Physical Chemistry Letters, Ausgabe 15, 2024, Seite(n) 12112-12119, ISSN 1948-7185
Herausgeber: American Chemical Society
DOI: 10.1021/acs.jpclett.4c02581

Mild-Temperature Supercritical Water Confined in Hydrophobic Metal–Organic Frameworks

Autoren: Sebastiano Merchiori, Andrea Le Donne*, Josh D. Littlefair, Alexander Rowland Lowe, Jiang-Jing Yu, Xu-Dong Wu, Mian Li, Dan Li, Monika Geppert-Rybczyńska, Lukasz Scheller, Benjamin A. Trump, Andrey A. Yakovenko, Paweł Zajdel*, Mirosław Chorążewski*, Yaroslav Grosu*, and Simone Meloni
Veröffentlicht in: Journal of the American Chemical Society, 2024, ISSN 0002-7863
Herausgeber: American Chemical Society
DOI: 10.1021/jacs.4c01226

Triboelectrification During Water Intrusion–Extrusion into‐from Hydrophobic Nanopores

Autoren: Luis Bartolomé, Josh David Littlefair, Eder Amayuelas, Liam J. W. Johnson, Andrea Le Donne, Andris Šutka, Simone Meloni, Yaroslav Grosu
Veröffentlicht in: Advanced Materials Technologies, Ausgabe 10, 2025, Seite(n) 2401744, ISSN 2365-709X
Herausgeber: Wiley
DOI: 10.1002/admt.202401744

Mobile energy recovery and storage: Multiple energy-powered EVs and refuelling stations

Autoren: Weiwei Zhao, Tongtong Zhang, Harriet Kildahl, Yulong Ding
Veröffentlicht in: Energy, 2022, ISSN 0360-5442
Herausgeber: Pergamon Press Ltd.
DOI: 10.1016/j.energy.2022.124697

Liquid intrusion in and extrusion from non-wettable nanopores for technological applications.

Autoren: Alberto Giacomello, Carlo Massimo Casciola, Yaroslav Grosu, Simone Meloni
Veröffentlicht in: European Physical Journal B, Ausgabe 94, 2021, Seite(n) 163, ISSN 1434-6028
Herausgeber: Springer Verlag
DOI: 10.1140/epjb/s10051-021-00170-3

Effect of the Topology on Wetting and Drying of Hydrophobic Porous Materials

Autoren: Yuriy G. Bushuev, Yaroslav Grosu, Mirosław A. Chora̧żewski, Simone Meloni
Veröffentlicht in: ACS Applied Materials & Interfaces, Ausgabe 14, 2022, Seite(n) 30067-300799, ISSN 1944-8252
Herausgeber: American Chemical Society
DOI: 10.1021/acsami.2c06039

Intrusion and extrusion of liquids in highly confining media: bridging fundamental research to applications.

Autoren: Andrea Le Donne, Antonio Tinti, Eder Amayuelas, Hemant K. Kashyap, Gaia Camisasca, Richard C. Remsing, Roland Roth, Yaroslav Grosu, Simone Meloni
Veröffentlicht in: Advances in Physics: X, Ausgabe 23746149, 2022, Seite(n) 2052353, ISSN 2374-6149
Herausgeber: Taylon and Francis
DOI: 10.1080/23746149.2022.2052353

Other (7)

Electro-Intrusion, FET Proactive projects-Research

Autoren: Y. Grosu
Veröffentlicht in: 2021
Herausgeber: """Research Meets Industry"" 14 Future and Emerging Technology/EIC Pathfinder projects"

Mechanical Energy at the Service of Ecology

Autoren: Tomasz Płosa, Mirosław Chorążewski
Veröffentlicht in: 2021
Herausgeber: XXXX
DOI: 10.31261/no_limits.2021.4.09

Triboelectric generators based on intrusion-extrusion of non-wetting liquids into-from nanopores

Autoren: L. Bartolomè, Y. Grosu
Veröffentlicht in: 2021
Herausgeber: 1st International Conference on Energy Materials

Converting vibrations and environmental heat into electricity via reversible water intrusion into hydrophobic nanopores

Autoren: Y. Grosu
Veröffentlicht in: 2021
Herausgeber: "Seminar at University of Rome ""La Sapienza"""

Exploring flexible nanoporous materials for energy-related applications

Autoren: Y. Grosu
Veröffentlicht in: 2021
Herausgeber: "Seminar at Università of Rome ""La Sapienza"""

Retrospective and perspective of intrusion-extrusion research: experimental and technological point of view

Autoren: Y. Grosu
Veröffentlicht in: 2021
Herausgeber: Summer workshop “Phase transitions at the nanoscale: wetting of nanoporous materials, cluster formation, and nanofriction”

Liquid intrusion (and extrusion) in porous and textured materials

Autoren: Simone Meloni
Veröffentlicht in: 2021
Herausgeber: FICN2021 - Frontiers in ion channels and nanopores:theory, experiments and simulations

Thesis and dissertations (1)

EFFETTO DELLA TEMPERATURA SUL MECCANISMO E SULLA CINETICA DI INTRUSIONE DI ACQUA IN METAL-ORGANIC FRAMEWORK IDROFOBI

Autoren: Daria Ballardini
Veröffentlicht in: 2022
Herausgeber: University of Ferrara