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Electrobiocatalytic cascade for bulk reduction of CO2 to CO coupled to fermentative production of high value diamine monomers

Descrizione del progetto

Trasformare i gas a effetto serra in tesori chimici

In un mondo alle prese con crisi ambientali, l’accesso a piattaforme chimiche sostenibili rimane una sfida pressante. La domanda di prodotti chimici derivati dalla CO2 e dall’azoto continua a crescere, richiedendo soluzioni innovative. In quest’ottica, il progetto ECOMO, finanziato dal CEI, unisce bio-elettrocatalisi, materiali bio-ibridi e altro ancora per trasformare la CO2 in prodotti chimici di alto valore, offrendo un’ancora di salvezza alle nostre industrie. L’innovazione chiave sta nello sfruttare i catalizzatori naturali (enzimi e cellule microbiche) per la biotrasformazione. Queste piccole centrali elettriche funzionano con un’eccezionale efficienza dell’atomo e offrono processi ecologici. In particolare, ECOMO raggiunge la piena compatibilità tra processi elettrochimici e biocatalitici producendo CO da CO2 attraverso il trasferimento mediato di elettroni. Mirando alla produzione di monomeri di diammina di alto valore, ECOMO apre la strada a materiali polimerici sostenibili.

Obiettivo

The access to platform chemicals made of CO2 and nitrogen sources as starting materials via sustainable processes requires radical innovations. Driven by the global need of existing and growing markets, combined technologies that make use of renewable energy and the greenhouse gas CO2, and the use of nature’s catalysts such as enzymes and microbial cells through biotransformation steps are expected to have a game changing impact. Such catalysts can operate at ambient conditions at high atom efficiency through environmentally and energetically friendly processes. In this context ECOMO unites bioelectrocatalysis, biohybrid materials sciences, organic synthesis, technical microbiology, and process engineering for CO gas fermentation to acetate and a subsequent production of diamines. The fermentation steps will be achieved by specifically engineered microbial strains using CO as both the carbon source and energy carrier. As core novelty, the CO will be produced in situ apart from the electrode in the bulk solution from CO2 through a mediated electron transfer to free floating beads where CO-dehydrogenase is immobilized within the acetate forming bacterial cell culture. This will enable for the first time, full compatibility between electrochemical and biocatalytic processes. The synthetic aim is to yield high value-added diamine monomers as building blocks for established classes of polymeric materials. ECOMO will establish new bio based and biohybrid modules that will be directly compatible with the existing bioreactor infrastructure for the producing of specialty chemicals directly from CO2. By achieving the production of diamines as a proof-of-concept, ECOMO will foster further diversification to many other products made from CO2 and thus enhances the synthetic availability of needed building blocks for the chemical industry. The decoupling from fossil-sourced energy and raw materials underpin the timeliness of ECOMO.

Parole chiave

Meccanismo di finanziamento

HORIZON-EIC - HORIZON EIC Grants

Coordinatore

TECHNISCHE UNIVERSITAET MUENCHEN
Contribution nette de l'UE
€ 1 223 047,50
Indirizzo
Arcisstrasse 21
80333 Muenchen
Germania

Mostra sulla mappa

Regione
Bayern Oberbayern München, Kreisfreie Stadt
Tipo di attività
Higher or Secondary Education Establishments
Collegamenti
Costo totale
€ 1 230 547,50

Partecipanti (4)