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Crystal Engineering for Molecular Organic Semiconductors

Obiettivo

"The urgent need to develop inexpensive and ubiquitous solar energy conversion cannot be overstated. Solution processed organic semiconductors can enable this goal as they support drastically less expensive fabrication techniques compared to traditional semiconductors. Molecular organic semiconductors (MOSs) offer many advantages to their more-common pi-conjugated polymer counterparts, however a clear and fundamental challenge to enable the goal of high performance solution-processable molecular organic semiconductor devices is to develop the ability to control the crystal packing, crystalline domain size, and mixing ability (for multicomponent blends) in the thin-film device geometry. The CEMOS project will accomplish this by pioneering innovative methods of “bottom-up” crystal engineering for organic semiconductors. We will employ specifically tailored molecules designed to leverage both thermodynamic and kinetic aspects of molecular organic semiconductor systems to direct and control crystalline packing, promote crystallite nucleation, compatibilize disparate phases, and plasticize inelastic materials. We will demonstrate that our new classes of materials can enable the tuning of the charge carrier transport and morphology in MOS thin films, and we will evaluate their performance in actual thin-film transistor (TFT) and organic photovoltaic (OPV) devices. Our highly interdisciplinary approach, combining material synthesis and device fabrication/evaluation, will not only lead to improvements in the performance and stability of OPVs and TFTs but will also give deep insights into how the crystalline packing—independent from the molecular structure—affects the optoelectronic properties. The success of CEMOS will rapidly advance the performance of MOS devices by enabling reproducible and tuneable performance comparable to traditional semiconductors—but at radically lower processing costs."

Invito a presentare proposte

ERC-2013-StG
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Meccanismo di finanziamento

ERC-SG - ERC Starting Grant

Istituzione ospitante

ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE
Contributo UE
€ 1 477 472,00
Indirizzo
BATIMENT CE 3316 STATION 1
1015 Lausanne
Svizzera

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Regione
Schweiz/Suisse/Svizzera Région lémanique Vaud
Tipo di attività
Higher or Secondary Education Establishments
Ricercatore principale
Kevin Sivula (Prof.)
Contatto amministrativo
Caroline Vandevyver (Dr.)
Collegamenti
Costo totale
Nessun dato

Beneficiari (1)