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Multifunctional Graphene-based Nanocomposites with Robust Electromagnetic and Thermal Properties for 3D-printing Application


Rheological methodology, optimized processing

"Report on ""Rheological methodology and optimized processing of nanocomposites'"

Materials synthesis and nanocomposite fabrication

Materials synthesis and nanocomposite fabrication; test samples to provide for other WPs

Report on Dissemination, Communication and Outreach activities

This Deliverable D9.2 will be presented in two stages: - First Stage Report will be presented at month 24; - Final report will be delivered at Month 45.

Design of foam-like open closed-shell structures with optimized lightness and mechanical robustness

Design of foam-like closed-shell structures based on the novel material for 3D-printing, to be used for electromagnetic shielding, with optimized lightness and mechanical robustness

Graphene 3D Website and Flyer

This Deliverable Report D9.1 will be presented in Month 3 and will be regulary upgraded to Month 48.


Influence of polymer swelling and dissolution into food simulants on the release of graphene nanoplates and carbon nanotubes from poly(lactic) acid and polypropylene composite films

Author(s): Hristiana Velichkova, Ivanka Petrova, Stanislav Kotsilkov, Evgeni Ivanov, Nikolay K. Vitanov, Rumiana Kotsilkova
Published in: Journal of Applied Polymer Science, Issue 134/44, 2017, Page(s) 45469, ISSN 0021-8995
DOI: 10.1002/app.45469

Recent Applications of Ionic Liquids in the Sol-Gel Process for Polymer–Silica Nanocomposites with Ionic Interfaces

Author(s): Katarzyna Donato, Libor Matějka, Raquel Mauler, Ricardo Donato
Published in: Colloids and Interfaces, Issue 1/1, 2018, Page(s) 5, ISSN 2504-5377
DOI: 10.3390/colloids1010005

Fully carbon metasurface: Absorbing coating in microwaves

Author(s): D. Bychanok, S. Li, G. Gorokhov, K. Piasotski, D. Meisak, P. Kuzhir, E. A. Burgess, C. P. Gallagher, F. Y. Ogrin, A. P. Hibbins, A. Pasc, A. Sanchez-Sanchez, V. Fierro, A. Celzard
Published in: Journal of Applied Physics, Issue 121/16, 2017, Page(s) 165103, ISSN 0021-8979
DOI: 10.1063/1.4982232

How effectively do carbon nanotube inclusions contribute to the electromagnetic performance of a composite material? Estimation criteria from microwave and terahertz measurements

Author(s): M.V. Shuba, D.I. Yuko, P.P. Kuzhir, S.A. Maksimenko, M.A. Kanygin, A.V. Okotrub, R. Tenne, Ph. Lambin
Published in: Carbon, Issue Available online 20 December 2017, 2017, Page(s) 21, ISSN 0008-6223
DOI: 10.1016/j.carbon.2017.12.067

Influence of carbon nanotube surface treatment on resistivity and low-frequency noise characteristics of epoxy-based composites

Author(s): Marina Tretjak, Sandra Pralgauskaitė, Jan Macutkevic, Jonas Matukas, Juras Banys, Polina Kuzhir, Evgeni Ivanov, Rumiana Kotsilkova
Published in: Polymer Composites, Issue 5 March 2018, 2018, Page(s) 7, ISSN 0272-8397
DOI: 10.1002/pc.24775

Terahertz absorption in graphite nanoplatelets/polylactic acid composites

Author(s): D Bychanok, P Angelova, A Paddubskaya, D Meisak, L Shashkova, M Demidenko, A Plyushch, E Ivanov, R Krastev, R Kotsilkova, F Y Ogrin, P Kuzhir
Published in: Journal of Physics D: Applied Physics, Issue 51/14, 2018, Page(s) 145307, ISSN 0022-3727
DOI: 10.1088/1361-6463/aab1a5

Experimental and theoretical study on piezoresistive properties of a structural resin reinforced with carbon nanotubes for strain sensing and damage monitoring

Author(s): Giovanni Spinelli, Patrizia Lamberti, Vincenzo Tucci, Luigi Vertuccio, Liberata Guadagno
Published in: Composites Part B: Engineering, Issue 145, 2018, Page(s) 90-99, ISSN 1359-8368
DOI: 10.1016/j.compositesb.2018.03.025

Carbon-Coated Nickel Nanoparticles: Effect on the Magnetic and Electric Properties of Composite Materials

Author(s): Artyom Plyushch, Jan Macutkevič, Jūras Banys, Polina Kuzhir, Nikolay Kalanda, Alexander Petrov, Clara Silvestre, Mikhail Uimin, Anatoly Yermakov, Olga Shenderova
Published in: Coatings, Issue 8/5, 2018, Page(s) 165, ISSN 2079-6412
DOI: 10.3390/coatings8050165

Structure and Electromagnetic Properties of Cellular Glassy Carbon Monoliths with Controlled Cell Size

Author(s): Andrzej Szczurek, Vanessa Fierro, Artyom Plyushch, Jan Macutkevic, Polina Kuzhir, Alain Celzard
Published in: Materials, Issue 11/5, 2018, Page(s) 709, ISSN 1996-1944
DOI: 10.3390/ma11050709

Modeling the electrical properties of three-dimensional printed meshes with the theory of resistor lattices

Author(s): Alexander V. Melnikov, Mikhail Shuba, Philippe Lambin
Published in: Physical Review E, Issue 97/4, 2018, Page(s) 11, ISSN 2470-0045
DOI: 10.1103/PhysRevE.97.043307

Localized plasmon resonance in boron-doped multiwalled carbon nanotubes

Author(s): M. V. Shuba, D. I. Yuko, P. P. Kuzhir, S. A. Maksimenko, G. G. Chigir, A. N. Pyatlitski, O. V. Sedelnikova, A. V. Okotrub, Ph. Lambin
Published in: Physical Review B, Issue 97/20, 2018, Page(s) 205427, ISSN 2469-9950
DOI: 10.1103/PhysRevB.97.205427

Release of Graphene and Carbon Nanotubes from Biodegradable Poly(Lactic Acid) Films during Degradation and Combustion: Risk Associated with the End-of-Life of Nanocomposite Food Packaging Materials

Author(s): Stanislav Kotsilkov, Evgeni Ivanov, Nikolay Vitanov
Published in: Materials, Issue 11/12, 2018, Page(s) 2346, ISSN 1996-1944
DOI: 10.3390/ma11122346

Nanoindentation analysis of 3D printed poly(lactic acid)-based composites reinforced with graphene and multiwall carbon nanotubes

Author(s): Todor Batakliev, Vladimir Georgiev, Evgeni Ivanov, Rumiana Kotsilkova, Rosa Di Maio, Clara Silvestre, Sossio Cimmino
Published in: Journal of Applied Polymer Science, Issue 01 November 2018, 2018, Page(s) 47260, ISSN 0021-8995
DOI: 10.1002/app.47260

Rheological study of poly(lactic) acid nanocomposites with carbon nanotubes and graphene additives as a tool for materials characterization for 3D printing application

Author(s): Radost Ivanova, Rumiana Kotsilkova
Published in: Applied Rheology, Issue July 16, 2018 (28:5, 2018), 2018, Page(s) 54014 -1/10, ISSN 1430-6395
DOI: 10.3933/applrheol-28-54014

Morphological, Rheological and Electromagnetic Properties of Nanocarbon/Poly(lactic) Acid for 3D Printing: Solution Blending vs. Melt Mixing

Author(s): Giovanni Spinelli, Patrizia Lamberti, Vincenzo Tucci, Rumiana Kotsilkova, Sonia Tabakova, Radost Ivanova, Polya Angelova, Verislav Angelov, Evgeni Ivanov, Rosa Di Maio, Clara Silvestre, Darya Meisak, Alesia Paddubskaya, Polina Kuzhir
Published in: Materials, Issue 11/11, 2018, Page(s) 2256, ISSN 1996-1944
DOI: 10.3390/ma11112256

Effect of boron and nitrogen additives on structure and transport properties of arc-produced carbon

Author(s): O.V. Sedelnikova, Yu.V. Fedoseeva, A.I. Romanenko, A.V. Gusel'nikov, O.Yu. Vilkov, E.A. Maksimovskiy, D.S. Bychanok, P.P. Kuzhir, L.G. Bulusheva, A.V. Okotrub
Published in: Carbon, Issue 143, 2019, Page(s) 660-668, ISSN 0008-6223
DOI: 10.1016/j.carbon.2018.11.071

Synergetic effect of triglycine sulfate and graphite nanoplatelets on dielectric and piezoelectric properties of epoxy resin composites

Author(s): Artyom Plyushch, Jan Macutkevic, Vytautas Samulionis, Juras Banys, Dzmitry Bychanok, Polina Kuzhir, Sandrine Mathieu, Vanessa Fierro, Alain Celzard
Published in: Polymer Composites, Issue 18 July 2018, 2018, Page(s) 15-26, ISSN 0272-8397
DOI: 10.1002/pc.24932

Numerical Simulation of the Percolation Threshold in Non-Overlapping Ellipsoid Composites: Toward Bottom-Up Approach for Carbon Based Electromagnetic Components Realization

Author(s): Artyom Plyushch, Patrizia Lamberti, Giovanni Spinelli, Jan Macutkevič, Polina Kuzhir
Published in: Applied Sciences, Issue 8/6, 2018, Page(s) 882, ISSN 2076-3417
DOI: 10.3390/app8060882

Sign inversion in the terahertz photoconductivity of single-walled carbon nanotube films

Author(s): Peter Karlsen, Mikhail V. Shuba, Polina P. Kuzhir, Albert G. Nasibulin, Patrizia Lamberti, Euan Hendry
Published in: Physical Review B, Issue 98/24, 2018, Page(s) 241404(R), ISSN 2469-9950
DOI: 10.1103/PhysRevB.98.241404

Ultra-Light Reduced Graphene Oxide Based Aerogel/Foam Absorber of Microwave Radiation

Author(s): Artyom Plyushch, Tianliang Zhai, Hesheng Xia, Chiara Santillo, Letizia Verdolotti , Marino Lavorgna, Polina Kuzhir
Published in: "Materials / Special Issue ""Carbon Based Functional Microwave Shields""", Issue Materials 2019, 12(2), 213, 2019, Page(s) 2-10, ISSN 1996-1944
DOI: 10.3390/ma12020213

Effects of Graphene Nanoplatelets and Multiwall Carbon Nanotubes on the Structure and Mechanical Properties of Poly(lactic acid) Composites: A Comparative Study

Author(s): Todor Batakliev, Ivanka Petrova-Doycheva, Verislav Angelov, Vladimir Georgiev, Evgeni Ivanov, Rumiana Kotsilkova, Marcello Casa, Claudia Cirillo, Renata Adami, Maria Sarno, Paolo Ciambelli
Published in: Applied Sciences, Issue 9/3, 2019, Page(s) 469, ISSN 2076-3417
DOI: 10.3390/app9030469

Synthesis of UV curable rGO/PDMS nanocomposites

Author(s): N. Jalagonia, T. Kuchukhidze, E. Sanaia, L. Kalatozishvili, R. Ivanova, B. Khvitia, G. Bokuchava
Published in: Bulletin of the Georgian National Academy of Science, Issue vol. 12, no. 4, 72-77, 2018, 2018, Page(s) 6, ISSN 0132-1447

Electrokinetic Properties of 3D-Printed Conductive Lattice Structures

Author(s): Philippe Lambin, Alexander Melnikov, Mikhail Shuba
Published in: Applied Sciences, Issue 9/3, 2019, Page(s) 541, ISSN 2076-3417
DOI: 10.3390/app9030541

Rheological and electrical behaviour of nanocarbon/poly(lactic) acid for 3D printing applications

Author(s): Giovanni Spinelli, Patrizia Lamberti, Vincenzo Tucci, Radost Ivanova, Sonia Tabakova, Evgeni Ivanov, Rumiana Kotsilkova, Sossio Cimmino, Rosa Di Maio, Clara Silvestre
Published in: Composites Part B: Engineering, Issue 167, 2019, Page(s) 467-476, ISSN 1359-8368
DOI: 10.1016/j.compositesb.2019.03.021

Restoring self-limited growth of single-layer graphene on copper foil via backside coating

Author(s): Nicolas Reckinger, Marcello Casa, Jeroen E. Scheerder, Wout Keijers, Matthieu Paillet, Jean-Roch Huntzinger, Emile Haye, Alexandre Felten, Joris Van de Vondel, Maria Sarno, Luc Henrard, Jean-François Colomer
Published in: Nanoscale, Issue 11/11, 2019, Page(s) 5094-5101, ISSN 2040-3364
DOI: 10.1039/c8nr09841g

Selective Laser Sintering Fabricated Thermoplastic Polyurethane/Graphene Cellular Structures with Tailorable Properties and High Strain Sensitivity

Author(s): Alfredo Ronca, Gennaro Rollo, Pierfrancesco Cerruti, Guoxia Fei, Xinpeng Gan, Giovanna Buonocore, Marino Lavorgna, Hesheng Xia, Clara Silvestre, Luigi Ambrosio
Published in: Applied Sciences, Issue 9/5, 2019, Page(s) 864, ISSN 2076-3417
DOI: 10.3390/app9050864

PLA/Graphene/MWCNT Composites with Improved Electrical and Thermal Properties Suitable for FDM 3D Printing Applications

Author(s): Ivanov, Evgeni Kotsilkova, Rumiana; Xia, Hesheng ; Chen, Yinghong ; Donato, Ricardo ; Donato, Katarzyna ; Godoy, Anna Paula ; Di Maio, Rosa ; Silvestre, Clara ; Cimmino, Sossio; Verislav Angelov
Published in: Appl. Sci. 2019 , 9 , 1209, Issue 9; 22 March 2019, 2019, Page(s) 14, ISSN 2076-3417
DOI: 10.3390/app9061209

Study on Aging and Recover of Poly (Lactic) Acid Composite Films with Graphene and Carbon Nanotubes Produced by Solution Blending and Extrusion

Author(s): Rumiana Kotsilkova, Polya Angelova, Todor Batakliev, Verislav Angelov, Rosa Di Maio, Clara Silvestre
Published in: Coatings, Issue 9/6, 2019, Page(s) 359, ISSN 2079-6412
DOI: 10.3390/coatings9060359

Carbon nanotubes vs graphene nanoplatelets for 3D-printable composites

Author(s): G. Gorokhov, D. Bychanok, D. Meisak, I. Shlyk, A. Liubimau, P. Angelova, C. Menseidov, E. Ivanov, R. Kotsilkova, M. Casa, P. Ciambelli, P. Kuzhir
Published in: IOP Conference Series: Materials Science and Engineering, Issue 503, 2019, Page(s) 012010, ISSN 1757-899X
DOI: 10.1088/1757-899x/503/1/012010

Exploring thermal annealing and graphene-carbon nanotube additives to enhance crystallinity, thermal, electrical and tensile properties of aged poly(lactic) acid-based filament for 3D printing

Author(s): Rumiana Kotsilkova, Ivanka Petrova-Doycheva, Dzhihan Menseidov, Evgeni Ivanov, Alesya Paddubskaya, Polina Kuzhir
Published in: Composites Science and Technology, Issue 181, 2019, Page(s) 107712, ISSN 0266-3538
DOI: 10.1016/j.compscitech.2019.107712

Frequency and density dependencies of the electromagnetic parameters of carbon nanotube and graphene nanoplatelet based composites in the microwave and terahertz ranges

Author(s): M V Shuba, D I Yuko, G Gorokhov, D Meisak, D S Bychanok, P P Kuzhir, S A Maksimenko, P Angelova, E Ivanov, R Kotsilkova
Published in: Materials Research Express, Issue 6/9, 2019, Page(s) 095050, ISSN 2053-1591
DOI: 10.1088/2053-1591/ab2edf

Stretching and Tunability of Graphene-Based Passive Terahertz Components

Author(s): Konstantin G. Batrakov, Nadezhda I. Volynets, Alesia G. Paddubskaya, Polina P. Kuzhir, Maria Stella Prete, Olivia Pulci, Evgeni Ivanov, Rumiana Kotsilkova, Tommi Kaplas, Yuri Svirko
Published in: physica status solidi (b), Issue 28 June 2019, 2019, Page(s) 1800683, ISSN 0370-1972
DOI: 10.1002/pssb.201800683

Nanocarbon/Poly(Lactic) Acid for 3D Printing: Effect of Fillers Content on Electromagnetic and Thermal Properties

Author(s): Giovanni Spinelli, Patrizia Lamberti, Vincenzo Tucci, Rumiana Kotsilkova, Evgeni Ivanov, Dzhihan Menseidov, Carlo Naddeo, Vittorio Romano, Liberata Guadagno, Renata Adami, Darya Meisak, Dzmitry Bychanok, Polina Kuzhir
Published in: Materials, Issue 12/15, 2019, Page(s) 2369, ISSN 1996-1944
DOI: 10.3390/ma12152369

Simultaneous realization of conductive segregation network microstructure and minimal surface porous macrostructure by SLS 3D printing

Author(s): Xinpeng Gan, Jinzhi Wang, Zhanhua Wang, Zhuo Zheng, Marino Lavorgna, Alfredo Ronca, Guoxia Fei, Hesheng Xia
Published in: Materials & Design, Issue 178, 2019, Page(s) 107874, ISSN 0264-1275
DOI: 10.1016/j.matdes.2019.107874

Silicon carbide/phosphate ceramics composite for electromagnetic shielding applications: Whiskers vs particles

Author(s): A. Plyushch, J. Macutkevic, S. Svirskas, J. Banys, V. Plausinaitiene, Dz. Bychanok, S. A. Maksimenko, A. Selskis, A. Sokal, K. N. Lapko, P. P. Kuzhir
Published in: Applied Physics Letters, Issue 114/18, 2019, Page(s) 183105, ISSN 0003-6951
DOI: 10.1063/1.5093421

Electromagnetic properties of chloroprene rubber after long-term ultraviolet ageing, oil immersion and thermal degradation

Author(s): R Sela, D Bychanok, Y Padrez, D Adamchuk, V Ksenevich, N Naveh, P Kuzhir
Published in: Materials Research Express, Issue 6/7, 2019, Page(s) 075327, ISSN 2053-1591
DOI: 10.1088/2053-1591/ab1574

Preparation and 3D-printing of highly conductive polylactic acid/carbon nanotube nanocomposites via local enrichment strategy

Author(s): Shaohong Shi, Yinghong Chen, Jingjing Jing, Lu Yang
Published in: RSC Advances, Issue 9/51, 2019, Page(s) 29980-29986, ISSN 2046-2069
DOI: 10.1039/c9ra05684j

Alignment of polymer based magnetic composites in magnetic field

Author(s): A.V. Kukhta, P.P. Kuzhir, S.A. Maksimenko, S.A. Vorobyova, I.N. Kukhta, A.E. Pochtenny, M.I. Taoubi, S. Bistarelli, S. Bellucci
Published in: Progress in Organic Coatings, Issue 137, 2019, Page(s) 105366, ISSN 0300-9440
DOI: 10.1016/j.porgcoat.2019.105366

Rheological behavior of graphene/epoxy nanodispersions

Author(s): Ivanov E, Velichkova H, Kotsilkova R, Bistarelli S, Cataldo A, Micciulla F, Bellucci S.
Published in: Applied Rheology, Issue 27 (2017) 24469, 2017, Page(s) 24469, ISSN 1617-8106
DOI: 10.3933/ApplRheol-27-24469

Effects of Filament Extrusion, 3D Printing and Hot-Pressing on Electrical and Tensile Properties of Poly(Lactic) Acid Composites Filled with Carbon Nanotubes and Graphene

Author(s): Giovanni Spinelli, Rumiana Kotsilkova, Evgeni Ivanov, Ivanka Petrova-Doycheva, Dzhihan Menseidov, Vladimir Georgiev, Rosa Di Maio, Clara Silvestre
Published in: Nanomaterials, Issue 10/1, 2020, Page(s) 35, ISSN 2079-4991
DOI: 10.3390/nano10010035

Release of carbon nanoparticles of different size and shape from nanocomposite poly(lactic) acid film into food simulants

Author(s): Hristiana Velichkova, Stanislav Kotsilkov, Evgeni Ivanov, Rumiana Kotsilkova, Stanislav Gyoshev, Nikolay Stoimenov, Nikolay K. Vitanov
Published in: Food Additives & Contaminants: Part A, Issue 34/6, 2017, Page(s) 1072-1085, ISSN 1944-0049
DOI: 10.1080/19440049.2017.1310396

Graphene as a Prototypical Model for Two-Dimensional Continuous Mechanics

Author(s): Philippe Lambin
Published in: Applied Sciences, Issue 7/8, 2017, Page(s) 830, ISSN 2076-3417
DOI: 10.3390/app7080830

THz and microwave properties of 3D-printed nanocarbon based multilayers

Author(s): P. Kuzhir, A. Paddubskaya, N. Volynets, R. Kotsilkova, E. Ivanov, I. Biro, G. I. Mark, L. P. Biro, S. Maksimenko
Published in: 2017 International Conference on Electromagnetics in Advanced Applications (ICEAA), Issue 11-15 Sept. 2017, Verona, Italy, 2017, Page(s) 822-823
DOI: 10.1109/ICEAA.2017.8065377

Electromagnetic Response Of A One-Dimensional Chain Of Interconnected Carbon Nanotubes In The Sub-Terahertz Range

Author(s): A. V. Melnikov, M. V. Shuba
Published in: "International Conference on Physics, Chemistry and Application of Nanostructures ""Nanomeeting-2017"",", Issue 30 May – 2 June 2017, 2017, Page(s) 183-186
DOI: 10.1142/9789813224537_0043

Morphological, rheological and electrical study of PLA reinforced with carbon-based fillers for 3D printing applications

Author(s): Luigi Egiziano, Patrizia Lamberti, Giovanni Spinelli, Vincenzo Tucci, Rumiana Kotsilkova, Sonia Tabakova, Evgeni Ivanov, Clara Silvestre, Rosa Di Maio
Published in: AIP Conference Proceedings volume 1981, Issue 11 July 2018; 9TH INTERNATIONAL CONFERENCE ON “TIMES OF POLYMERS AND COMPOSITES”: From Aerospace to Nanotechnology, 2018, Page(s) 020152
DOI: 10.1063/1.5046014

Rheology as a tool for evaluationof hybrid structure in thermoplastic polymer nanocomposites with graphene and carbon nanotubes

Author(s): Rumiana Kotsilkova, Radost Ivanova, Ivanka Petrova-Doycheva
Published in: International Journal of Mechanical and Production Engineering (IJMPE) , pp. 26-29, Volume-6,Issue-9, Issue July 2018, 2018, Page(s) 9-12, ISSN 2320-2092

Influence of compatibilizer and filler functionalization on the nanomechanical properties of PP/MWCNT and Epoxy/MWCNT composites

Author(s): Evgeni Ivanov, Verislav Angelov
Published in: International Journal of Mechanical and Production Engineering (IJMPE) , pp. 30-33, Volume-6,Issue-9, Issue July 2018, 2018, Page(s) 13-16, ISSN 2320-2092

Evaluation of thermal and electrical conductivity of carbon-based PLA nanocomposites for 3D printing

Author(s): Patrizia Lamberti, Giovanni Spinelli, Polina P. Kuzhir, Liberata Guadagno, Carlo Naddeo, Vittorio Romano, Rumania Kotsilkova, Polya Angelova, Vlado Georgiev
Published in: AIP Conference Proceedings volume 1981, Issue Jul 11, 2018, 2018, Page(s) 020158
DOI: 10.1063/1.5046020

Electrodynamics of graphene heterostructures and electromagnetic applications

Author(s): Philippe Lambin, Bruno Majerus, Michael Lobet, Michael Sarrazin, Mirko Cormann, Tommi Kaplas, Yuri Svirko, Alesia Paddubskaya, Konstantin Batrakov, Polina Kuzhir
Published in: 2018 International Conference on Electromagnetics in Advanced Applications (ICEAA), Issue Date Added to IEEE Xplore: 05 November 2018, 2018, Page(s) 47-50
DOI: 10.1109/iceaa.2018.8520341

Changes in the mechanical properties of polypropylene by addition two types of nanofillers: carbon nanotubes and organoclay

Author(s): Petrova-Doycheva I., Ivanov E.
Published in: International Journal of Mechanical and Production Engineering (IJMPE), Issue Volume-6, Issue-9, Oct, 2018, 2018, Page(s) 34-37, ISSN 2320-2092
DOI: 10.5281/zenodo.1888103