GEN IV Integrated Oxide fuels recycling strategies

Deliverables

Old number D131

Communication and dissemination action plan

Old number D432

"Impact of the precursor ""history"" (nature, structural, microstructural and morphological parameters) during the conversion and sintering to actinide based dioxide materials"

Old number D144

Destruction of organic

Old number D123

WPASR 6

Old number D411

Innovative dissolution routes for highly plutonium doped (U,Pu)O2 and (U,Pu,MA)O2 samples

Old number D142

Clustering Events 1

Old number D331

Impact assessment report for fuel cycle implications

Old number D315

Clustering Events 3

Old number D331

Product quality, characterization & testing

Old number D234

Status on TODGA organic phase loading

Old number D133

report on travel bursary and secondment grant attribution

Old number D421

WPASR 1

Old number D411

Performances on microelectrode for online monitoring of relevant parameters

Old number D213

Draft iSanex/Ganex package ready for testing

Old number D425

Impacts on process safety of gas generation

Old number D124

Major Hazard and Criticality review of the Euro-Ganex process

Old number D325

contribution of computational multi-disciplinary approaches to the design of solvent extraction devices

Old number D214

Knowledge and Data Management Plan

Old number D427

optimized flowsheets for homogeneous recycling of advanced MOX fuel in GEN IV reactors

Old number D222

Status on solvent clean-up & recycling

Old number D134

Molecular modeling of particular degradation mechanism of extracting and complexing agents

Old number D125

WPASR 2

Old number D411

Report on the development of the different MABB precursor synthesis routes and their contribution on MA homogeneity, dust reduction, lowering sintering temperature

Old number D233

Report with collected data on the main solvents and the density laws build

Old number D324

WPASR 4

Old number D411

Report on dissolution model development

Old number D231

Mapping of the different status and alternatives for each ESNII concept

Old number D313

organisation of the think-tank event

Old number D422

Stability and safety studies of hold extraction systems (1 for each CyMe4BTBP, HidroBTBP, TODGA & PTD)

Old number D121

Assessment of applications of PTD in i-SANEX and EUROGANEX processes

Old number D221

Report on the methodology to establish a density law for NCS evaluations. It will include the needs in terms of data and chemical measurements

Old number D323

WPASR 5

Old number D411

Report on hazard analysis mainly focusing on criticality aspects

Old number D322

Packages tested and released

Old number D426

Experimental and modeling studies of transfer kinetics in the reference separation processes

Old number D211

Report on the comparison of SX processes for heterogeneous recycling

Old number D312

optimized flowsheets for heterogeneous recycling of advanced MOX fuel in GEN IV reactors

Old number D223

Report on efficiency of the electrochemical decomposition of ligands from SX processes and on its inputs on MABB precursor properties

Old number D232

Status on Distribution data and chemical modelling

Old number D132

Project website

Old number D433

Clustering Events 4

Old number D331

Communication toolkit

Old number D431

Identification of optimized conditions for effecter fission product masking/scrubbing

Old number D112

Clustering Events 2

Old number D331

Safety Review minutes, including recommendations for future R&D which could eliminate, reduce or mitigate hazards

Old number D312

Report on the speciation and extraction of key fission products

Old number D111

WPASR 3

Old number D411

Understanding the evolution of an interface during dissolution of actinide oxide materials by macro/microscopic approaches combination

Old number D141

Assessment of the corrosion vulnerability of common plant materials in the presence of key process streams

Old number D326

studies of non-powder routes for the synthesis of MOX fuels materials, potentially bearing minor actinides and blanket fuel materials

Old number D143

deliverable report on specification for on line packages

Old number D423

Stability studies of stripping agents

Old number D122

Process Description report of Concept Euro-GANEX Plant

Old number D311

Report on ‘Sim-Plant’ Methodology and flowsheet comparison

Old number D314

WPASR 7

Old number D411

Status of flowsheet calculations made for WP22 process testing

Old number D215

Draft Purex package ready for testing

Old number D424

Impacts of solvent degradation and recycle on the EURO-GANEX process

Old number D212

Stakeholders Event 2

Old number D332

Exploitation plan based on the conclusions of the interactions with stakeholders/end-users

Old number D333

Stakeholders Event 1

Old number D332

Publications

Characteristics of the extraction systems for the minor actinoids and lanthanoids separation using hydrophilic masking agents and TODGA

Author(s): Šebesta, J.; Distler, P.; John, J.; Bavol, D.; Gruner, B.
Published in: Czech Chemical Society Symposium Series, Issue Volume 18, issue 3, 2020, 2020, Page(s) 157-158, ISSN 2336-7210
Publisher: Česká společnost chemická

Study of the effect of radiation on the Ln (III)/An(III) separation in the systems using hydrophilic masking agents during extraction into TODGA

Author(s): Šebesta, J.; Distler, P.; John, J.
Published in: Jaderná energetika v pracích mladé generace 2019., Issue 2020, 2020, Page(s) 128-133, ISBN 978-80-02-02895-6
Publisher: Česká nukleární společnost

Characterization of Am(III) and Eu(III) extraction in the CHALMEX systems

Author(s): Mindová, M.; Distler, P.; John, J.; Bavol, D.; Gruner, B.
Published in: Czech Chemical Society Symposium Series, Issue Volume 18, Issue 3, 2020, 2020, Page(s) 157, ISSN 2336-7210
Publisher: Česká společnost chemická

Attempts to isolate technetium in the process of separating actinides from spent nuclear fuel (in Polish)

Author(s): Magdalena Rejnis-Strzelak, Irena Herdzik-Koniecko, Jerzy Narbutt
Published in: Abstracts, 62nd Annual Scientific Meeting of the Polish Chemical Society, Warsaw, Sep. 2-6, 2019, Issue Poster S16 P10, 2019, Page(s) page S16-25
Publisher: Polish Chemical Society

Influence of gamma radiation on the properties of Ln(III)/An(III) extractiion systems using the lipophilic extractant CyMe4-BTBP

Author(s): Mindová, M.; Distler, P.
Published in: Jaderná energetika v pracích mladé generace 2019, Issue 2020, 2020, Page(s) 123-127, ISBN 978-80-02-02895-6
Publisher: Česká nukleární společnost

Solvent extraction of americium from spent nuclear fuel and closing the fuel cycle - new perspectives for development of nuclear energy (in Polish)

Author(s): Jerzy Narbutt
Published in: Abstracts, 62nd Annual Scientific Meeting of the Polish Chemical Society, Warsaw, Sep. 2-6, 2019, Issue Section lecture S16 WS03, 2019, Page(s) page S16-6
Publisher: Polish Chemical Society

A review of ageing, hydrolysis and radiolysis effects on PyTri-based stripping solvents for i-SANEX/GANEX processes

Author(s): E. Mossini, E. Macerata, M.C. Charbonnel, A. Casnati, A. Mele, A. Geist, M. Mariani
Published in: RB2018 - Second edition of Radical Behaviour workshop, 2018
Publisher: E. Mossini

FLUORINATED CARBONATES AS NEW DILUENTS FOR EXTRACTION OF F-ELEMENTS

Author(s): VASILIY BABAIN, MIKHAIL ALYAPYSHEV, I.G. VORONAEV, LIUDMILA TKACHENKO, E.V. KENF, MIRIAM MINDOVÁ, PETR DISTLER, JAN JOHN
Published in: Czech Chemical Society Symposium Series, Issue Vol. 16, No. 2, 2018, Page(s) p. 135, ISSN 2336-7202
Publisher: Czech Chemical Society

APPLICATION OF MOLECULAR MODELLING FOR STUDYING THE STABILITY OF ORGANIC LIGANDS IN NUCLEAR FUEL CYCLE

Author(s): TOMÁŠ KOUBSKÝ, LADISLAV KALVODA
Published in: Czech Chemical Society Symposium Series, Issue Vol. 16, No. 2, 2018, Page(s) p. 81, ISSN 2336-7202
Publisher: Czech Chemical Society

PARTITIONING OF MINOR AN(III) AND LN(III) BY THE 1,2,4-TRIAZINE EXTRACTING COMPOUNDS

Author(s): PETR DISTLER, ASHFAQ AFSAR, KAMILA ŠŤASTNÁ, JAMES WESTWOOD, FRANK W. LEWIS, KAREL ŠTAMBERG, LAURENCE HARWOOD, JAN JOHN
Published in: Czech Chemical Society Symposium Series, Issue Vol. 16, No. 2, 2018, Page(s) p. 56, ISSN 2336-7202
Publisher: Czech Chemical Society

Problem of a Thorough Geometric Optimization

Author(s): Tomáš Koubský
Published in: Proceedings of the 7th students´ science conference on the solid state physics and materials, Issue 2017-09-18 / 2017-09-22, 2018, Page(s) p. 20-22, ISBN 978-80-01-06374-3
Publisher: Czech Technical University Publishing House

Study of organic ligands by classical simulation methods (in Czech: Studium organických ligandů klasickými simulačními metodami)

Author(s): Lucie Celbová
Published in: Proceedings of the 8th students´ science conference on the solid state physics and materials, Issue Sedliště, 17-21/09/2018, 2018, Page(s) pp. 11-13, ISBN 978-80-01-06511-2
Publisher: CTU in Prague

Fluorinated Carbonates as New Diluents for Extraction of f-Elements

Author(s): Babain, V.A.; Alyapyshev, M.Yu.; Voronaev, I.G.; Tkachenko, L.I.; Kenf, E.V.; Mindová, M.; Distler, P.; John, J.
Published in: Czech Chemical Society, Symposium Series, Issue Volume 16, Issue 2, 2018, 2018, Page(s) 135, ISSN 2336-7202
Publisher: Česká společnost chemická

Optimizing the separation of fission product technetium in the process of recycling actinides from spent nuclear fuel

Author(s): Irena Herdzik-Koniecko, Magdalena Rejnis-Strzelak, Jerzy Narbutt
Published in: International Conference on Development and Applications of Nuclear Technologies, NUTECH-2020, Conference Abstracts, Issue Poster, Warsaw, 4-7 October 2020, 2020, Page(s) Conference Abstracts & Programme, page 56, ISBN 978-83-946412-4-5
Publisher: Institute of Nuclear Chemistry and Technology

Fluorinated Carbonates as New Diluents for Extraction and Separation of f- Block Elements

Author(s): Petr Distler, Miriam Mindová, Jan John, Vasilij A. Babain, Mikhail Yu. Alyapyshev, Lyudmila I. Tkachenko, Ekaterina V. Kenf, Laurence M. Harwood, Ashfaq Afsar
Published in: Solvent Extraction and Ion Exchange, Issue 38/2, 2020, Page(s) 180-193, ISSN 0736-6299
Publisher: Marcel Dekker Inc.
DOI: 10.1080/07366299.2019.1708004

Stability of Different BTBP and BTPhen Extracting or Masking Compounds Against Gamma Radiation

Author(s): Distler P., Mindova M., Šebesta J., Grűner B., Bavol D., Egberink R. J. M., Verboom W., Babain V. A., John J.,
Published in: Chemistry Research, Issue 24 issues/ year, 2021, Page(s) 19 MS pages, ISSN 1520-5045
Publisher: American Chemical Society

The conversion of ammonium uranate prepared via sol-gel synthesis into uranium oxides

Author(s): Christian Schreinemachers, Gregory Leinders, Giuseppe Modolo, Marc Verwerft, Koen Binnemans, Thomas Cardinaels
Published in: Nuclear Engineering and Technology, Issue 52/5, 2020, Page(s) 1013-1021, ISSN 1738-5733
Publisher: Korean Nuclear Society
DOI: 10.1016/j.net.2019.11.004

Separation of Minor Actinides from Lanthanides Using Immobilized Ligand Systems: The Role of the Counterion

Author(s): Laurence M. Harwood, Ashfaq Afsar, Petr Distler, Jan John, Jasraj S. Babra, Zoe Y. Selfe, Joeseph Cowell, James Westwood
Published in: HETEROCYCLES, Issue 99/2, 2019, Page(s) 825, ISSN 0385-5414
Publisher: Elsevier BV
DOI: 10.3987/com-18-s(f)71

Structural changes of Nd- and Ce-doped ammonium diuranate microspheres during the conversion to U1−LnO2±

Author(s): Christian Schreinemachers, Gregory Leinders, Renaud Podor, Joseph Lautru, Nicolas Clavier, Giuseppe Modolo, Marc Verwerft, Koen Binnemans, Thomas Cardinaels
Published in: Journal of Nuclear Materials, Issue 542, 2020, Page(s) 152454, ISSN 0022-3115
Publisher: Elsevier BV
DOI: 10.1016/j.jnucmat.2020.152454

Solvent Extraction Investigations on Pu(IV) and Th(IV) Complexes with Hydrophilic SO 3 -Ph-BTP and SO 3 -Ph-BTBP Ligands

Author(s): Łukasz Steczek, Jerzy Narbutt, Marie-Christine Charbonnel, Philippe Moisy
Published in: Solvent Extraction and Ion Exchange, Issue 37/3-4, 2019, Page(s) 259-268, ISSN 0736-6299
Publisher: Marcel Dekker Inc.
DOI: 10.1080/07366299.2019.1639366

A Study of Cerium Extraction Kinetics by TODGA in Acidified and Non-Acidified Organic Solvent Phases in the Context of Fission Product Management

Author(s): Michael Anthony Bromley Colin Boxall
Published in: Progress in Nuclear Science and Technology, 2018, Page(s) 70-73, ISSN 2185-4823
Publisher: Atomic Energy Society of Japan
DOI: 10.15669/pnst.5.70

On the Basic Extraction Properties of a Phenyl Trifluoromethyl Sulfone-Based GANEX System Containing CyMe 4 -BTBP and TBP

Author(s): Jenny Halleröd, Christian Ekberg, Thea Authen, Laura Bertolo, Mu Lin, Bohumír Grüner, Jaroslav Švehla, Christoph Wagner, Andreas Geist, Petra Panak, Emma Aneheim
Published in: Solvent Extraction and Ion Exchange, Issue 36/4, 2018, Page(s) 360-372, ISSN 0736-6299
Publisher: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1497043

Radiolytic and hydrolytic degradation of the hydrophilic diglycolamides

Author(s): Andreas Wilden, Bruce J. Mincher, Stephen P. Mezyk, Liam Twight, Kristyn M. Rosciolo-Johnson, Christopher A. Zarzana, Mary E. Case, Michelle Hupert, Andrea Stärk, Giuseppe Modolo
Published in: Solvent Extraction and Ion Exchange, Issue 36/4, 2018, Page(s) 347-359, ISSN 0736-6299
Publisher: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1495384

Stoichiometry of An( iii )–DMDOHEMA complexes formed during solvent extraction

Author(s): Patrik Weßling, Michael Trumm, Andreas Geist, Petra J. Panak
Published in: Dalton Transactions, Issue 47/32, 2018, Page(s) 10906-10914, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8dt02504e

Modified diglycolamides for grouped actinide separation

Author(s): Rikard Malmbeck, Daniel Magnusson, Andreas Geist
Published in: Journal of Radioanalytical and Nuclear Chemistry, Issue 314/3, 2017, Page(s) 2531-2538, ISSN 0236-5731
Publisher: Akademiai Kiado
DOI: 10.1007/s10967-017-5614-2

Optimization and Single-Stage Centrifugal Contactor Experiments with the Novel Hydrophilic Complexant PyTri-Diol for the i -SANEX Process

Author(s): Eros Mossini, Elena Macerata, Andreas Wilden, Peter Kaufholz, Giuseppe Modolo, Nicolò Iotti, Alessandro Casnati, Andreas Geist, Mario Mariani
Published in: Solvent Extraction and Ion Exchange, Issue 36/4, 2018, Page(s) 373-386, ISSN 0736-6299
Publisher: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1507134

Behaviour of the extractant Me-TODGA upon gamma irradiation: quantification of degradation compounds and individual influences on complexation and extraction

Author(s): V. Hubscher-Bruder, V. Mogilireddy, S. Michel, A. Leoncini, J. Huskens, W. Verboom, H. Galán, A. Núñez, J. Cobos, G. Modolo, A. Wilden, H. Schmidt, M.-C. Charbonnel, P. Guilbaud, N. Boubals
Published in: New Journal of Chemistry, Issue 41/22, 2017, Page(s) 13700-13711, ISSN 1144-0546
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7nj02136d

Synthesis of size-controlled UO 2 microspheres from the hydrothermal conversion of U( iv ) aspartate

Author(s): V. Trillaud, J. Maynadié, J. Manaud, J. Hidalgo, D. Meyer, R. Podor, N. Dacheux, N. Clavier
Published in: CrystEngComm, Issue 20/48, 2018, Page(s) 7749-7760, ISSN 1466-8033
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8ce01352g

2,6-Bis(1-alkyl-1H-1,2,3-triazol-4-yl)-pyridines: selective lipophilic chelating ligands for minor actinides

Author(s): Annalisa Ossola, Elena Macerata, Eros Mossini, Marco Giola, Maria Chiara Gullo, Arturo Arduini, Alessandro Casnati, Mario Mariani
Published in: Journal of Radioanalytical and Nuclear Chemistry, Issue 318/3, 2018, Page(s) 2013-2022, ISSN 0236-5731
Publisher: Akademiai Kiado
DOI: 10.1007/s10967-018-6253-y

Application of quantum mechanical simulations for studying the radiolytic stability of prospective extractants in the nuclear fuel cycle

Author(s): Tomáš Koubský, Jakub Luštinec
Published in: Journal of Radioanalytical and Nuclear Chemistry, Issue 318/3, 2018, Page(s) 2407-2413, ISSN 0236-5731
Publisher: Akademiai Kiado
DOI: 10.1007/s10967-018-6225-2

Extraction Properties of 4-Tetra(hydroxyphenyl)BTPhen in Liquid-Liquid Extraction Systems with Cyclohexanone/Octanol or in a Solid-Phase Extraction System

Author(s): Laurence M. Harwood, Jan John, Ashfaq Afsar, Jasraj S. Babra, Petr Distler, Iain Hopkins, James Westwood, Zoe Y. Selfe
Published in: HETEROCYCLES, Issue 101/1, 2020, Page(s) 209, ISSN 0385-5414
Publisher: Elsevier BV
DOI: 10.3987/com-19-s(f)14

Thermodynamic parameters of Am(III), Cm(III) and Eu(III) extraction by CyMe4-BTPhen in cyclohexanone from HNO3 solutions

Author(s): Petr Distler, Karel Stamberg, Jan John, Laurence M. Harwood, Frank W. Lewis
Published in: The Journal of Chemical Thermodynamics, Issue 141, 2020, Page(s) 105955, ISSN 0021-9614
Publisher: Academic Press
DOI: 10.1016/j.jct.2019.105955

Activation of the Aromatic Core of 3,3′-(Pyridine-2,6-diylbis(1 H -1,2,3-triazole-4,1-diyl))bis(propan-1-ol)—Effects on Extraction Performance, Stability Constants, and Basicity

Author(s): Patrik Weßling, Michael Trumm, Elena Macerata, Annalisa Ossola, Eros Mossini, Maria Chiara Gullo, Arturo Arduini, Alessandro Casnati, Mario Mariani, Christian Adam, Andreas Geist, Petra J. Panak
Published in: Inorganic Chemistry, Issue 58/21, 2019, Page(s) 14642-14651, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b02325

On the basic extraction properties of a phenyl trifuoromethyl sulfone based GANEX system containing CyMe4-BTBP and TBP.

Author(s): J. Halleröd, Ch. Ekberg, T. Authen, L. Bertolo, Mu Lin, B. Grüner, J. Švehla, Ch. Wagner, A. Geist, P. Panak, E. Aneheim.
Published in: Solvent Extraction and Ion Exchange, Issue Vol. 36, Issue 4, 2018, Page(s) 360-372, ISSN 0736-6299
Publisher: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1497043

Stability studies of GANEX system under different irradiation conditions

Author(s): Iván Sánchez-García, Hitos Galán, Jose Manuel Perlado, Joaquín Cobos
Published in: EPJ Nuclear Sciences & Technologies, Issue 5, 2019, Page(s) 19, ISSN 2491-9292
Publisher: EDP Sciences
DOI: 10.1051/epjn/2019049

Do An( iii ) and Ln( iii ) ions form heteroleptic complexes with diglycolamide and hydrophilic BT(B)P ligands in solvent extraction systems? A spectroscopic and DFT study

Author(s): Irena Herdzik-Koniecko, Christoph Wagner, Michael Trumm, Udo Müllich, Bernd Schimmelpfennig, Jerzy Narbutt, Andreas Geist, Petra J. Panak
Published in: New Journal of Chemistry, Issue 43/16, 2019, Page(s) 6314-6322, ISSN 1144-0546
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9nj00651f

Gamma and pulsed electron radiolysis studies of CyMe4BTBP and CyMe4BTPhen: identification of radiolysis products and effects on the hydrometallurgical separation of trivalent actinides and lanthanides

Author(s): Schmidt H., Wilden* A., Modolo G., Bosbach D., Santiago-Schübel B., HupertM., Mincher B. J., Mezyk S. P., Švehla J., Grüner B., Ekberg Ch.,
Published in: Radiation Phys. Chem., Issue 12 issues/ year, 2021, Page(s) 31 pp., ISSN 0969-806X
Publisher: Pergamon Press Ltd.

Evaluation of the Hydrophilic Complexant N,N,N’,N’ -tetraethyldiglycolamide (TEDGA) and its Methyl-substituted Analogues in the Selective Am(III) Separation

Author(s): Larissa Klaß, Andreas Wilden, Fabian Kreft, Christoph Wagner, Andreas Geist, Petra J. Panak, Irena Herdzik-Koniecko, Jerzy Narbutt, Giuseppe Modolo
Published in: Solvent Extraction and Ion Exchange, Issue 37/5, 2019, Page(s) 297-312, ISSN 0736-6299
Publisher: Marcel Dekker Inc.
DOI: 10.1080/07366299.2019.1651039

Fabrication of Nd- and Ce-doped uranium dioxide microspheres via internal gelation

Author(s): Christian Schreinemachers; Gregory Leinders; Giuseppe Modolo; Marc Verwerft; Koen Binnemans; Thomas Cardinaels
Published in: Journal of Nuclear Materials, Issue 21, 2020, ISSN 0022-3115
Publisher: Elsevier BV

Solvent Extraction for Nuclear Power

Author(s): Jerzy Narbutt
Published in: Liquid-Phase Extraction, Issue Handbooks in Separation Science, Colin F. Poole, Editor, 2020, Page(s) 725-744, ISBN 9780128169117
Publisher: Elsevier
DOI: 10.1016/b978-0-12-816911-7.00024-4

The use of synergistic effects of lipophilic modifiers of TODGA-containing organic phase for improving separation of Am(III) from the early lanthanides in the process of stripping the metals with hydrophilic ligands. A novel concept for solving the problem

Author(s): Jerzy Narbutt, Irena Herdzik-Koniecko, Magdalena Rejnis-Strzelak
Published in: RAPORTY IChTJ, SERIA B, Issue Nr 2/2017, 2017, Page(s) 1 - 14, ISSN 1425-7351
Publisher: ICHTJ

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