GEN IV Integrated Oxide fuels recycling strategies

Livrables

Old number D131

Communication and dissemination action plan

Old number D432

"Impact of the precursor ""history"" (nature, structural, microstructural and morphological parameters) during the conversion and sintering to actinide based dioxide materials"

Old number D144

Destruction of organic

Old number D123

WPASR 6

Old number D411

Innovative dissolution routes for highly plutonium doped (U,Pu)O2 and (U,Pu,MA)O2 samples

Old number D142

Clustering Events 1

Old number D331

Impact assessment report for fuel cycle implications

Old number D315

Clustering Events 3

Old number D331

Product quality, characterization & testing

Old number D234

Status on TODGA organic phase loading

Old number D133

report on travel bursary and secondment grant attribution

Old number D421

WPASR 1

Old number D411

Performances on microelectrode for online monitoring of relevant parameters

Old number D213

Draft iSanex/Ganex package ready for testing

Old number D425

Impacts on process safety of gas generation

Old number D124

Major Hazard and Criticality review of the Euro-Ganex process

Old number D325

contribution of computational multi-disciplinary approaches to the design of solvent extraction devices

Old number D214

Knowledge and Data Management Plan

Old number D427

optimized flowsheets for homogeneous recycling of advanced MOX fuel in GEN IV reactors

Old number D222

Status on solvent clean-up & recycling

Old number D134

Molecular modeling of particular degradation mechanism of extracting and complexing agents

Old number D125

WPASR 2

Old number D411

Report on the development of the different MABB precursor synthesis routes and their contribution on MA homogeneity, dust reduction, lowering sintering temperature

Old number D233

Report with collected data on the main solvents and the density laws build

Old number D324

WPASR 4

Old number D411

Report on dissolution model development

Old number D231

Mapping of the different status and alternatives for each ESNII concept

Old number D313

organisation of the think-tank event

Old number D422

Stability and safety studies of hold extraction systems (1 for each CyMe4BTBP, HidroBTBP, TODGA & PTD)

Old number D121

Assessment of applications of PTD in i-SANEX and EUROGANEX processes

Old number D221

Report on the methodology to establish a density law for NCS evaluations. It will include the needs in terms of data and chemical measurements

Old number D323

WPASR 5

Old number D411

Report on hazard analysis mainly focusing on criticality aspects

Old number D322

Packages tested and released

Old number D426

Experimental and modeling studies of transfer kinetics in the reference separation processes

Old number D211

Report on the comparison of SX processes for heterogeneous recycling

Old number D312

optimized flowsheets for heterogeneous recycling of advanced MOX fuel in GEN IV reactors

Old number D223

Report on efficiency of the electrochemical decomposition of ligands from SX processes and on its inputs on MABB precursor properties

Old number D232

Status on Distribution data and chemical modelling

Old number D132

Project website

Old number D433

Clustering Events 4

Old number D331

Communication toolkit

Old number D431

Identification of optimized conditions for effecter fission product masking/scrubbing

Old number D112

Clustering Events 2

Old number D331

Safety Review minutes, including recommendations for future R&D which could eliminate, reduce or mitigate hazards

Old number D312

Report on the speciation and extraction of key fission products

Old number D111

WPASR 3

Old number D411

Understanding the evolution of an interface during dissolution of actinide oxide materials by macro/microscopic approaches combination

Old number D141

Assessment of the corrosion vulnerability of common plant materials in the presence of key process streams

Old number D326

studies of non-powder routes for the synthesis of MOX fuels materials, potentially bearing minor actinides and blanket fuel materials

Old number D143

deliverable report on specification for on line packages

Old number D423

Stability studies of stripping agents

Old number D122

Process Description report of Concept Euro-GANEX Plant

Old number D311

Report on ‘Sim-Plant’ Methodology and flowsheet comparison

Old number D314

WPASR 7

Old number D411

Status of flowsheet calculations made for WP22 process testing

Old number D215

Draft Purex package ready for testing

Old number D424

Impacts of solvent degradation and recycle on the EURO-GANEX process

Old number D212

Stakeholders Event 2

Old number D332

Exploitation plan based on the conclusions of the interactions with stakeholders/end-users

Old number D333

Stakeholders Event 1

Old number D332

Publications

Characteristics of the extraction systems for the minor actinoids and lanthanoids separation using hydrophilic masking agents and TODGA

Auteurs: Šebesta, J.; Distler, P.; John, J.; Bavol, D.; Gruner, B.
Publié dans: Czech Chemical Society Symposium Series, Numéro Volume 18, issue 3, 2020, 2020, Page(s) 157-158, ISSN 2336-7210
Éditeur: Česká společnost chemická

Study of the effect of radiation on the Ln (III)/An(III) separation in the systems using hydrophilic masking agents during extraction into TODGA

Auteurs: Šebesta, J.; Distler, P.; John, J.
Publié dans: Jaderná energetika v pracích mladé generace 2019., Numéro 2020, 2020, Page(s) 128-133, ISBN 978-80-02-02895-6
Éditeur: Česká nukleární společnost

Characterization of Am(III) and Eu(III) extraction in the CHALMEX systems

Auteurs: Mindová, M.; Distler, P.; John, J.; Bavol, D.; Gruner, B.
Publié dans: Czech Chemical Society Symposium Series, Numéro Volume 18, Numéro 3, 2020, 2020, Page(s) 157, ISSN 2336-7210
Éditeur: Česká společnost chemická

Attempts to isolate technetium in the process of separating actinides from spent nuclear fuel (in Polish)

Auteurs: Magdalena Rejnis-Strzelak, Irena Herdzik-Koniecko, Jerzy Narbutt
Publié dans: Abstracts, 62nd Annual Scientific Meeting of the Polish Chemical Society, Warsaw, Sep. 2-6, 2019, Numéro Poster S16 P10, 2019, Page(s) page S16-25
Éditeur: Polish Chemical Society

Influence of gamma radiation on the properties of Ln(III)/An(III) extractiion systems using the lipophilic extractant CyMe4-BTBP

Auteurs: Mindová, M.; Distler, P.
Publié dans: Jaderná energetika v pracích mladé generace 2019, Numéro 2020, 2020, Page(s) 123-127, ISBN 978-80-02-02895-6
Éditeur: Česká nukleární společnost

Solvent extraction of americium from spent nuclear fuel and closing the fuel cycle - new perspectives for development of nuclear energy (in Polish)

Auteurs: Jerzy Narbutt
Publié dans: Abstracts, 62nd Annual Scientific Meeting of the Polish Chemical Society, Warsaw, Sep. 2-6, 2019, Numéro Section lecture S16 WS03, 2019, Page(s) page S16-6
Éditeur: Polish Chemical Society

A review of ageing, hydrolysis and radiolysis effects on PyTri-based stripping solvents for i-SANEX/GANEX processes

Auteurs: E. Mossini, E. Macerata, M.C. Charbonnel, A. Casnati, A. Mele, A. Geist, M. Mariani
Publié dans: RB2018 - Second edition of Radical Behaviour workshop, 2018
Éditeur: E. Mossini

FLUORINATED CARBONATES AS NEW DILUENTS FOR EXTRACTION OF F-ELEMENTS

Auteurs: VASILIY BABAIN, MIKHAIL ALYAPYSHEV, I.G. VORONAEV, LIUDMILA TKACHENKO, E.V. KENF, MIRIAM MINDOVÁ, PETR DISTLER, JAN JOHN
Publié dans: Czech Chemical Society Symposium Series, Numéro Vol. 16, No. 2, 2018, Page(s) p. 135, ISSN 2336-7202
Éditeur: Czech Chemical Society

APPLICATION OF MOLECULAR MODELLING FOR STUDYING THE STABILITY OF ORGANIC LIGANDS IN NUCLEAR FUEL CYCLE

Auteurs: TOMÁŠ KOUBSKÝ, LADISLAV KALVODA
Publié dans: Czech Chemical Society Symposium Series, Numéro Vol. 16, No. 2, 2018, Page(s) p. 81, ISSN 2336-7202
Éditeur: Czech Chemical Society

PARTITIONING OF MINOR AN(III) AND LN(III) BY THE 1,2,4-TRIAZINE EXTRACTING COMPOUNDS

Auteurs: PETR DISTLER, ASHFAQ AFSAR, KAMILA ŠŤASTNÁ, JAMES WESTWOOD, FRANK W. LEWIS, KAREL ŠTAMBERG, LAURENCE HARWOOD, JAN JOHN
Publié dans: Czech Chemical Society Symposium Series, Numéro Vol. 16, No. 2, 2018, Page(s) p. 56, ISSN 2336-7202
Éditeur: Czech Chemical Society

Problem of a Thorough Geometric Optimization

Auteurs: Tomáš Koubský
Publié dans: Proceedings of the 7th students´ science conference on the solid state physics and materials, Numéro 2017-09-18 / 2017-09-22, 2018, Page(s) p. 20-22, ISBN 978-80-01-06374-3
Éditeur: Czech Technical University Publishing House

Study of organic ligands by classical simulation methods (in Czech: Studium organických ligandů klasickými simulačními metodami)

Auteurs: Lucie Celbová
Publié dans: Proceedings of the 8th students´ science conference on the solid state physics and materials, Numéro Sedliště, 17-21/09/2018, 2018, Page(s) pp. 11-13, ISBN 978-80-01-06511-2
Éditeur: CTU in Prague

Fluorinated Carbonates as New Diluents for Extraction of f-Elements

Auteurs: Babain, V.A.; Alyapyshev, M.Yu.; Voronaev, I.G.; Tkachenko, L.I.; Kenf, E.V.; Mindová, M.; Distler, P.; John, J.
Publié dans: Czech Chemical Society, Symposium Series, Numéro Volume 16, Numéro 2, 2018, 2018, Page(s) 135, ISSN 2336-7202
Éditeur: Česká společnost chemická

Optimizing the separation of fission product technetium in the process of recycling actinides from spent nuclear fuel

Auteurs: Irena Herdzik-Koniecko, Magdalena Rejnis-Strzelak, Jerzy Narbutt
Publié dans: International Conference on Development and Applications of Nuclear Technologies, NUTECH-2020, Conference Abstracts, Numéro Poster, Warsaw, 4-7 October 2020, 2020, Page(s) Conference Abstracts & Programme, page 56, ISBN 978-83-946412-4-5
Éditeur: Institute of Nuclear Chemistry and Technology

Fluorinated Carbonates as New Diluents for Extraction and Separation of f- Block Elements

Auteurs: Petr Distler, Miriam Mindová, Jan John, Vasilij A. Babain, Mikhail Yu. Alyapyshev, Lyudmila I. Tkachenko, Ekaterina V. Kenf, Laurence M. Harwood, Ashfaq Afsar
Publié dans: Solvent Extraction and Ion Exchange, Numéro 38/2, 2020, Page(s) 180-193, ISSN 0736-6299
Éditeur: Marcel Dekker Inc.
DOI: 10.1080/07366299.2019.1708004

Stability of Different BTBP and BTPhen Extracting or Masking Compounds Against Gamma Radiation

Auteurs: Distler P., Mindova M., Šebesta J., Grűner B., Bavol D., Egberink R. J. M., Verboom W., Babain V. A., John J.,
Publié dans: Chemistry Research, Numéro 24 issues/ year, 2021, Page(s) 19 MS pages, ISSN 1520-5045
Éditeur: American Chemical Society

The conversion of ammonium uranate prepared via sol-gel synthesis into uranium oxides

Auteurs: Christian Schreinemachers, Gregory Leinders, Giuseppe Modolo, Marc Verwerft, Koen Binnemans, Thomas Cardinaels
Publié dans: Nuclear Engineering and Technology, Numéro 52/5, 2020, Page(s) 1013-1021, ISSN 1738-5733
Éditeur: Korean Nuclear Society
DOI: 10.1016/j.net.2019.11.004

Separation of Minor Actinides from Lanthanides Using Immobilized Ligand Systems: The Role of the Counterion

Auteurs: Laurence M. Harwood, Ashfaq Afsar, Petr Distler, Jan John, Jasraj S. Babra, Zoe Y. Selfe, Joeseph Cowell, James Westwood
Publié dans: HETEROCYCLES, Numéro 99/2, 2019, Page(s) 825, ISSN 0385-5414
Éditeur: Elsevier BV
DOI: 10.3987/com-18-s(f)71

Structural changes of Nd- and Ce-doped ammonium diuranate microspheres during the conversion to U1−LnO2±

Auteurs: Christian Schreinemachers, Gregory Leinders, Renaud Podor, Joseph Lautru, Nicolas Clavier, Giuseppe Modolo, Marc Verwerft, Koen Binnemans, Thomas Cardinaels
Publié dans: Journal of Nuclear Materials, Numéro 542, 2020, Page(s) 152454, ISSN 0022-3115
Éditeur: Elsevier BV
DOI: 10.1016/j.jnucmat.2020.152454

Solvent Extraction Investigations on Pu(IV) and Th(IV) Complexes with Hydrophilic SO 3 -Ph-BTP and SO 3 -Ph-BTBP Ligands

Auteurs: Łukasz Steczek, Jerzy Narbutt, Marie-Christine Charbonnel, Philippe Moisy
Publié dans: Solvent Extraction and Ion Exchange, Numéro 37/3-4, 2019, Page(s) 259-268, ISSN 0736-6299
Éditeur: Marcel Dekker Inc.
DOI: 10.1080/07366299.2019.1639366

A Study of Cerium Extraction Kinetics by TODGA in Acidified and Non-Acidified Organic Solvent Phases in the Context of Fission Product Management

Auteurs: Michael Anthony Bromley Colin Boxall
Publié dans: Progress in Nuclear Science and Technology, 2018, Page(s) 70-73, ISSN 2185-4823
Éditeur: Atomic Energy Society of Japan
DOI: 10.15669/pnst.5.70

On the Basic Extraction Properties of a Phenyl Trifluoromethyl Sulfone-Based GANEX System Containing CyMe 4 -BTBP and TBP

Auteurs: Jenny Halleröd, Christian Ekberg, Thea Authen, Laura Bertolo, Mu Lin, Bohumír Grüner, Jaroslav Švehla, Christoph Wagner, Andreas Geist, Petra Panak, Emma Aneheim
Publié dans: Solvent Extraction and Ion Exchange, Numéro 36/4, 2018, Page(s) 360-372, ISSN 0736-6299
Éditeur: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1497043

Radiolytic and hydrolytic degradation of the hydrophilic diglycolamides

Auteurs: Andreas Wilden, Bruce J. Mincher, Stephen P. Mezyk, Liam Twight, Kristyn M. Rosciolo-Johnson, Christopher A. Zarzana, Mary E. Case, Michelle Hupert, Andrea Stärk, Giuseppe Modolo
Publié dans: Solvent Extraction and Ion Exchange, Numéro 36/4, 2018, Page(s) 347-359, ISSN 0736-6299
Éditeur: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1495384

Stoichiometry of An( iii )–DMDOHEMA complexes formed during solvent extraction

Auteurs: Patrik Weßling, Michael Trumm, Andreas Geist, Petra J. Panak
Publié dans: Dalton Transactions, Numéro 47/32, 2018, Page(s) 10906-10914, ISSN 1477-9226
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c8dt02504e

Modified diglycolamides for grouped actinide separation

Auteurs: Rikard Malmbeck, Daniel Magnusson, Andreas Geist
Publié dans: Journal of Radioanalytical and Nuclear Chemistry, Numéro 314/3, 2017, Page(s) 2531-2538, ISSN 0236-5731
Éditeur: Akademiai Kiado
DOI: 10.1007/s10967-017-5614-2

Optimization and Single-Stage Centrifugal Contactor Experiments with the Novel Hydrophilic Complexant PyTri-Diol for the i -SANEX Process

Auteurs: Eros Mossini, Elena Macerata, Andreas Wilden, Peter Kaufholz, Giuseppe Modolo, Nicolò Iotti, Alessandro Casnati, Andreas Geist, Mario Mariani
Publié dans: Solvent Extraction and Ion Exchange, Numéro 36/4, 2018, Page(s) 373-386, ISSN 0736-6299
Éditeur: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1507134

Behaviour of the extractant Me-TODGA upon gamma irradiation: quantification of degradation compounds and individual influences on complexation and extraction

Auteurs: V. Hubscher-Bruder, V. Mogilireddy, S. Michel, A. Leoncini, J. Huskens, W. Verboom, H. Galán, A. Núñez, J. Cobos, G. Modolo, A. Wilden, H. Schmidt, M.-C. Charbonnel, P. Guilbaud, N. Boubals
Publié dans: New Journal of Chemistry, Numéro 41/22, 2017, Page(s) 13700-13711, ISSN 1144-0546
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c7nj02136d

Synthesis of size-controlled UO 2 microspheres from the hydrothermal conversion of U( iv ) aspartate

Auteurs: V. Trillaud, J. Maynadié, J. Manaud, J. Hidalgo, D. Meyer, R. Podor, N. Dacheux, N. Clavier
Publié dans: CrystEngComm, Numéro 20/48, 2018, Page(s) 7749-7760, ISSN 1466-8033
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c8ce01352g

2,6-Bis(1-alkyl-1H-1,2,3-triazol-4-yl)-pyridines: selective lipophilic chelating ligands for minor actinides

Auteurs: Annalisa Ossola, Elena Macerata, Eros Mossini, Marco Giola, Maria Chiara Gullo, Arturo Arduini, Alessandro Casnati, Mario Mariani
Publié dans: Journal of Radioanalytical and Nuclear Chemistry, Numéro 318/3, 2018, Page(s) 2013-2022, ISSN 0236-5731
Éditeur: Akademiai Kiado
DOI: 10.1007/s10967-018-6253-y

Application of quantum mechanical simulations for studying the radiolytic stability of prospective extractants in the nuclear fuel cycle

Auteurs: Tomáš Koubský, Jakub Luštinec
Publié dans: Journal of Radioanalytical and Nuclear Chemistry, Numéro 318/3, 2018, Page(s) 2407-2413, ISSN 0236-5731
Éditeur: Akademiai Kiado
DOI: 10.1007/s10967-018-6225-2

Extraction Properties of 4-Tetra(hydroxyphenyl)BTPhen in Liquid-Liquid Extraction Systems with Cyclohexanone/Octanol or in a Solid-Phase Extraction System

Auteurs: Laurence M. Harwood, Jan John, Ashfaq Afsar, Jasraj S. Babra, Petr Distler, Iain Hopkins, James Westwood, Zoe Y. Selfe
Publié dans: HETEROCYCLES, Numéro 101/1, 2020, Page(s) 209, ISSN 0385-5414
Éditeur: Elsevier BV
DOI: 10.3987/com-19-s(f)14

Thermodynamic parameters of Am(III), Cm(III) and Eu(III) extraction by CyMe4-BTPhen in cyclohexanone from HNO3 solutions

Auteurs: Petr Distler, Karel Stamberg, Jan John, Laurence M. Harwood, Frank W. Lewis
Publié dans: The Journal of Chemical Thermodynamics, Numéro 141, 2020, Page(s) 105955, ISSN 0021-9614
Éditeur: Academic Press
DOI: 10.1016/j.jct.2019.105955

Activation of the Aromatic Core of 3,3′-(Pyridine-2,6-diylbis(1 H -1,2,3-triazole-4,1-diyl))bis(propan-1-ol)—Effects on Extraction Performance, Stability Constants, and Basicity

Auteurs: Patrik Weßling, Michael Trumm, Elena Macerata, Annalisa Ossola, Eros Mossini, Maria Chiara Gullo, Arturo Arduini, Alessandro Casnati, Mario Mariani, Christian Adam, Andreas Geist, Petra J. Panak
Publié dans: Inorganic Chemistry, Numéro 58/21, 2019, Page(s) 14642-14651, ISSN 0020-1669
Éditeur: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b02325

On the basic extraction properties of a phenyl triuoromethyl sulfone based GANEX system containing CyMe4-BTBP and TBP.

Auteurs: J. Halleröd, Ch. Ekberg, T. Authen, L. Bertolo, Mu Lin, B. Grüner, J. Švehla, Ch. Wagner, A. Geist, P. Panak, E. Aneheim.
Publié dans: Extraction , Ion Exchange, Numéro Vol. 36, Numéro 4, 2018, Page(s) 360-372, ISSN 0736-6299
Éditeur: Marcel Dekker Inc.

Stability studies of GANEX system under different irradiation conditions

Auteurs: Iván Sánchez-García, Hitos Galán, Jose Manuel Perlado, Joaquín Cobos
Publié dans: EPJ Nuclear Sciences & Technologies, Numéro 5, 2019, Page(s) 19, ISSN 2491-9292
Éditeur: EDP Sciences
DOI: 10.1051/epjn/2019049

Do An( iii ) and Ln( iii ) ions form heteroleptic complexes with diglycolamide and hydrophilic BT(B)P ligands in solvent extraction systems? A spectroscopic and DFT study

Auteurs: Irena Herdzik-Koniecko, Christoph Wagner, Michael Trumm, Udo Müllich, Bernd Schimmelpfennig, Jerzy Narbutt, Andreas Geist, Petra J. Panak
Publié dans: New Journal of Chemistry, Numéro 43/16, 2019, Page(s) 6314-6322, ISSN 1144-0546
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c9nj00651f

Gamma and pulsed electron radiolysis studies of CyMe4BTBP and CyMe4BTPhen: identification of radiolysis products and effects on the hydrometallurgical separation of trivalent actinides and lanthanides

Auteurs: Schmidt H., Wilden* A., Modolo G., Bosbach D., Santiago-Schübel B., HupertM., Mincher B. J., Mezyk S. P., Švehla J., Grüner B., Ekberg Ch.,
Publié dans: Radiation Phys. Chem., Numéro 12 issues/ year, 2021, Page(s) 31 pp., ISSN 0969-806X
Éditeur: Pergamon Press Ltd.

Evaluation of the Hydrophilic Complexant N,N,N’,N’ -tetraethyldiglycolamide (TEDGA) and its Methyl-substituted Analogues in the Selective Am(III) Separation

Auteurs: Larissa Klaß, Andreas Wilden, Fabian Kreft, Christoph Wagner, Andreas Geist, Petra J. Panak, Irena Herdzik-Koniecko, Jerzy Narbutt, Giuseppe Modolo
Publié dans: Solvent Extraction and Ion Exchange, Numéro 37/5, 2019, Page(s) 297-312, ISSN 0736-6299
Éditeur: Marcel Dekker Inc.
DOI: 10.1080/07366299.2019.1651039

Fabrication of Nd- and Ce-doped uranium dioxide microspheres via internal gelation

Auteurs: Christian Schreinemachers; Gregory Leinders; Giuseppe Modolo; Marc Verwerft; Koen Binnemans; Thomas Cardinaels
Publié dans: Journal of Nuclear Materials, Numéro 21, 2020, ISSN 0022-3115
Éditeur: Elsevier BV

Solvent Extraction for Nuclear Power

Auteurs: Jerzy Narbutt
Publié dans: Liquid-Phase Extraction, Numéro Handbooks in Separation Science, Colin F. Poole, Editor, 2020, Page(s) 725-744, ISBN 9780128169117
Éditeur: Elsevier
DOI: 10.1016/b978-0-12-816911-7.00024-4

The use of synergistic effects of lipophilic modifiers of TODGA-containing organic phase for improving separation of Am(III) from the early lanthanides in the process of stripping the metals with hydrophilic ligands. A novel concept for solving the problem

Auteurs: Jerzy Narbutt, Irena Herdzik-Koniecko, Magdalena Rejnis-Strzelak
Publié dans: RAPORTY IChTJ, SERIA B, Numéro Nr 2/2017, 2017, Page(s) 1 - 14, ISSN 1425-7351
Éditeur: ICHTJ

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