GEN IV Integrated Oxide fuels recycling strategies

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Risultati finali

Status on the PyTri-Diol properties

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Communication and dissemination action plan

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"Impact of the precursor ""history"" (nature, structural, microstructural and morphological parameters) during the conversion and sintering to actinide based dioxide materials"

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Destruction of organic

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WPASR 6

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Innovative dissolution routes for highly plutonium doped (U,Pu)O2 and (U,Pu,MA)O2 samples

Old number D142

Clustering Events 1

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Impact assessment report for fuel cycle implications

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Clustering Events 3

Old number D331

Product quality, characterization & testing

Old number D234

Status on TODGA organic phase loading

Old number D133

report on travel bursary and secondment grant attribution

Old number D421

WPASR 1

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Performances on microelectrode for online monitoring of relevant parameters

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Draft iSanex/Ganex package ready for testing

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Impacts on process safety of gas generation

Old number D124

Major Hazard and Criticality review of the Euro-Ganex process

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contribution of computational multi-disciplinary approaches to the design of solvent extraction devices

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Knowledge and Data Management Plan

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optimized flowsheets for homogeneous recycling of advanced MOX fuel in GEN IV reactors

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Status on solvent clean-up & recycling

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Molecular modeling of particular degradation mechanism of extracting and complexing agents

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WPASR 2

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Report on the development of the different MABB precursor synthesis routes and their contribution on MA homogeneity, dust reduction, lowering sintering temperature

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Report with collected data on the main solvents and the density laws build

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WPASR 4

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Report on dissolution model development

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Mapping of the different status and alternatives for each ESNII concept

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organisation of the think-tank event

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Stability and safety studies of hold extraction systems (1 for each CyMe4BTBP, HidroBTBP, TODGA & PTD)

Old number D121

Assessment of applications of PTD in i-SANEX and EUROGANEX processes

Old number D221

Report on the methodology to establish a density law for NCS evaluations. It will include the needs in terms of data and chemical measurements

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WPASR 5

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Report on hazard analysis mainly focusing on criticality aspects

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Packages tested and released

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Experimental and modeling studies of transfer kinetics in the reference separation processes

Old number D211

Report on the comparison of SX processes for heterogeneous recycling

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optimized flowsheets for heterogeneous recycling of advanced MOX fuel in GEN IV reactors

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Report on efficiency of the electrochemical decomposition of ligands from SX processes and on its inputs on MABB precursor properties

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Status on Distribution data and chemical modelling

Old number D132

Project website

Old number D433

Clustering Events 4

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Communication toolkit

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Identification of optimized conditions for effecter fission product masking/scrubbing

Old number D112

Clustering Events 2

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Safety Review minutes, including recommendations for future R&D which could eliminate, reduce or mitigate hazards

Old number D312

Report on the speciation and extraction of key fission products

Old number D111

WPASR 3

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Understanding the evolution of an interface during dissolution of actinide oxide materials by macro/microscopic approaches combination

Old number D141

Assessment of the corrosion vulnerability of common plant materials in the presence of key process streams

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studies of non-powder routes for the synthesis of MOX fuels materials, potentially bearing minor actinides and blanket fuel materials

Old number D143

deliverable report on specification for on line packages

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Stability studies of stripping agents

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Process Description report of Concept Euro-GANEX Plant

Old number D311

Report on ‘Sim-Plant’ Methodology and flowsheet comparison

Old number D314

WPASR 7

Old number D411

Status of flowsheet calculations made for WP22 process testing

Old number D215

Draft Purex package ready for testing

Old number D424

Impacts of solvent degradation and recycle on the EURO-GANEX process

Old number D212

Stakeholders Event 2

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Exploitation plan based on the conclusions of the interactions with stakeholders/end-users

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Stakeholders Event 1

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Pubblicazioni

Characteristics of the extraction systems for the minor actinoids and lanthanoids separation using hydrophilic masking agents and TODGA

Autori: Šebesta, J.; Distler, P.; John, J.; Bavol, D.; Gruner, B.
Pubblicato in: Czech Chemical Society Symposium Series, Numero Volume 18, issue 3, 2020, 2020, Pagina/e 157-158, ISSN 2336-7210
Editore: Česká společnost chemická

Study of the effect of radiation on the Ln (III)/An(III) separation in the systems using hydrophilic masking agents during extraction into TODGA

Autori: Šebesta, J.; Distler, P.; John, J.
Pubblicato in: Jaderná energetika v pracích mladé generace 2019., Numero 2020, 2020, Pagina/e 128-133, ISBN 978-80-02-02895-6
Editore: Česká nukleární společnost

Characterization of Am(III) and Eu(III) extraction in the CHALMEX systems

Autori: Mindová, M.; Distler, P.; John, J.; Bavol, D.; Gruner, B.
Pubblicato in: Czech Chemical Society Symposium Series, Numero Volume 18, Numero 3, 2020, 2020, Pagina/e 157, ISSN 2336-7210
Editore: Česká společnost chemická

Attempts to isolate technetium in the process of separating actinides from spent nuclear fuel (in Polish)

Autori: Magdalena Rejnis-Strzelak, Irena Herdzik-Koniecko, Jerzy Narbutt
Pubblicato in: Abstracts, 62nd Annual Scientific Meeting of the Polish Chemical Society, Warsaw, Sep. 2-6, 2019, Numero Poster S16 P10, 2019, Pagina/e page S16-25
Editore: Polish Chemical Society

Influence of gamma radiation on the properties of Ln(III)/An(III) extractiion systems using the lipophilic extractant CyMe4-BTBP

Autori: Mindová, M.; Distler, P.
Pubblicato in: Jaderná energetika v pracích mladé generace 2019, Numero 2020, 2020, Pagina/e 123-127, ISBN 978-80-02-02895-6
Editore: Česká nukleární společnost

Solvent extraction of americium from spent nuclear fuel and closing the fuel cycle - new perspectives for development of nuclear energy (in Polish)

Autori: Jerzy Narbutt
Pubblicato in: Abstracts, 62nd Annual Scientific Meeting of the Polish Chemical Society, Warsaw, Sep. 2-6, 2019, Numero Section lecture S16 WS03, 2019, Pagina/e page S16-6
Editore: Polish Chemical Society

A review of ageing, hydrolysis and radiolysis effects on PyTri-based stripping solvents for i-SANEX/GANEX processes

Autori: E. Mossini, E. Macerata, M.C. Charbonnel, A. Casnati, A. Mele, A. Geist, M. Mariani
Pubblicato in: RB2018 - Second edition of Radical Behaviour workshop, 2018
Editore: E. Mossini

FLUORINATED CARBONATES AS NEW DILUENTS FOR EXTRACTION OF F-ELEMENTS

Autori: VASILIY BABAIN, MIKHAIL ALYAPYSHEV, I.G. VORONAEV, LIUDMILA TKACHENKO, E.V. KENF, MIRIAM MINDOVÁ, PETR DISTLER, JAN JOHN
Pubblicato in: Czech Chemical Society Symposium Series, Numero Vol. 16, No. 2, 2018, Pagina/e p. 135, ISSN 2336-7202
Editore: Czech Chemical Society

APPLICATION OF MOLECULAR MODELLING FOR STUDYING THE STABILITY OF ORGANIC LIGANDS IN NUCLEAR FUEL CYCLE

Autori: TOMÁŠ KOUBSKÝ, LADISLAV KALVODA
Pubblicato in: Czech Chemical Society Symposium Series, Numero Vol. 16, No. 2, 2018, Pagina/e p. 81, ISSN 2336-7202
Editore: Czech Chemical Society

PARTITIONING OF MINOR AN(III) AND LN(III) BY THE 1,2,4-TRIAZINE EXTRACTING COMPOUNDS

Autori: PETR DISTLER, ASHFAQ AFSAR, KAMILA ŠŤASTNÁ, JAMES WESTWOOD, FRANK W. LEWIS, KAREL ŠTAMBERG, LAURENCE HARWOOD, JAN JOHN
Pubblicato in: Czech Chemical Society Symposium Series, Numero Vol. 16, No. 2, 2018, Pagina/e p. 56, ISSN 2336-7202
Editore: Czech Chemical Society

Problem of a Thorough Geometric Optimization

Autori: Tomáš Koubský
Pubblicato in: Proceedings of the 7th students´ science conference on the solid state physics and materials, Numero 2017-09-18 / 2017-09-22, 2018, Pagina/e p. 20-22, ISBN 978-80-01-06374-3
Editore: Czech Technical University Publishing House

Study of organic ligands by classical simulation methods (in Czech: Studium organických ligandů klasickými simulačními metodami)

Autori: Lucie Celbová
Pubblicato in: Proceedings of the 8th students´ science conference on the solid state physics and materials, Numero Sedliště, 17-21/09/2018, 2018, Pagina/e pp. 11-13, ISBN 978-80-01-06511-2
Editore: CTU in Prague

Fluorinated Carbonates as New Diluents for Extraction of f-Elements

Autori: Babain, V.A.; Alyapyshev, M.Yu.; Voronaev, I.G.; Tkachenko, L.I.; Kenf, E.V.; Mindová, M.; Distler, P.; John, J.
Pubblicato in: Czech Chemical Society, Symposium Series, Numero Volume 16, Numero 2, 2018, 2018, Pagina/e 135, ISSN 2336-7202
Editore: Česká společnost chemická

Optimizing the separation of fission product technetium in the process of recycling actinides from spent nuclear fuel

Autori: Irena Herdzik-Koniecko, Magdalena Rejnis-Strzelak, Jerzy Narbutt
Pubblicato in: International Conference on Development and Applications of Nuclear Technologies, NUTECH-2020, Conference Abstracts, Numero Poster, Warsaw, 4-7 October 2020, 2020, Pagina/e Conference Abstracts & Programme, page 56, ISBN 978-83-946412-4-5
Editore: Institute of Nuclear Chemistry and Technology

Fluorinated Carbonates as New Diluents for Extraction and Separation of f- Block Elements

Autori: Petr Distler, Miriam Mindová, Jan John, Vasilij A. Babain, Mikhail Yu. Alyapyshev, Lyudmila I. Tkachenko, Ekaterina V. Kenf, Laurence M. Harwood, Ashfaq Afsar
Pubblicato in: Solvent Extraction and Ion Exchange, Numero 38/2, 2020, Pagina/e 180-193, ISSN 0736-6299
Editore: Marcel Dekker Inc.
DOI: 10.1080/07366299.2019.1708004

Stability of Different BTBP and BTPhen Extracting or Masking Compounds Against Gamma Radiation

Autori: Distler P., Mindova M., Šebesta J., Grűner B., Bavol D., Egberink R. J. M., Verboom W., Babain V. A., John J.,
Pubblicato in: Chemistry Research, Numero 24 issues/ year, 2021, Pagina/e 19 MS pages, ISSN 1520-5045
Editore: American Chemical Society

The conversion of ammonium uranate prepared via sol-gel synthesis into uranium oxides

Autori: Christian Schreinemachers, Gregory Leinders, Giuseppe Modolo, Marc Verwerft, Koen Binnemans, Thomas Cardinaels
Pubblicato in: Nuclear Engineering and Technology, Numero 52/5, 2020, Pagina/e 1013-1021, ISSN 1738-5733
Editore: Korean Nuclear Society
DOI: 10.1016/j.net.2019.11.004

Separation of Minor Actinides from Lanthanides Using Immobilized Ligand Systems: The Role of the Counterion

Autori: Laurence M. Harwood, Ashfaq Afsar, Petr Distler, Jan John, Jasraj S. Babra, Zoe Y. Selfe, Joeseph Cowell, James Westwood
Pubblicato in: HETEROCYCLES, Numero 99/2, 2019, Pagina/e 825, ISSN 0385-5414
Editore: Elsevier BV
DOI: 10.3987/com-18-s(f)71

Structural changes of Nd- and Ce-doped ammonium diuranate microspheres during the conversion to U1−LnO2±

Autori: Christian Schreinemachers, Gregory Leinders, Renaud Podor, Joseph Lautru, Nicolas Clavier, Giuseppe Modolo, Marc Verwerft, Koen Binnemans, Thomas Cardinaels
Pubblicato in: Journal of Nuclear Materials, Numero 542, 2020, Pagina/e 152454, ISSN 0022-3115
Editore: Elsevier BV
DOI: 10.1016/j.jnucmat.2020.152454

Solvent Extraction Investigations on Pu(IV) and Th(IV) Complexes with Hydrophilic SO 3 -Ph-BTP and SO 3 -Ph-BTBP Ligands

Autori: Łukasz Steczek, Jerzy Narbutt, Marie-Christine Charbonnel, Philippe Moisy
Pubblicato in: Solvent Extraction and Ion Exchange, Numero 37/3-4, 2019, Pagina/e 259-268, ISSN 0736-6299
Editore: Marcel Dekker Inc.
DOI: 10.1080/07366299.2019.1639366

A Study of Cerium Extraction Kinetics by TODGA in Acidified and Non-Acidified Organic Solvent Phases in the Context of Fission Product Management

Autori: Michael Anthony Bromley Colin Boxall
Pubblicato in: Progress in Nuclear Science and Technology, 2018, Pagina/e 70-73, ISSN 2185-4823
Editore: Atomic Energy Society of Japan
DOI: 10.15669/pnst.5.70

On the Basic Extraction Properties of a Phenyl Trifluoromethyl Sulfone-Based GANEX System Containing CyMe 4 -BTBP and TBP

Autori: Jenny Halleröd, Christian Ekberg, Thea Authen, Laura Bertolo, Mu Lin, Bohumír Grüner, Jaroslav Švehla, Christoph Wagner, Andreas Geist, Petra Panak, Emma Aneheim
Pubblicato in: Solvent Extraction and Ion Exchange, Numero 36/4, 2018, Pagina/e 360-372, ISSN 0736-6299
Editore: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1497043

Radiolytic and hydrolytic degradation of the hydrophilic diglycolamides

Autori: Andreas Wilden, Bruce J. Mincher, Stephen P. Mezyk, Liam Twight, Kristyn M. Rosciolo-Johnson, Christopher A. Zarzana, Mary E. Case, Michelle Hupert, Andrea Stärk, Giuseppe Modolo
Pubblicato in: Solvent Extraction and Ion Exchange, Numero 36/4, 2018, Pagina/e 347-359, ISSN 0736-6299
Editore: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1495384

Stoichiometry of An( iii )–DMDOHEMA complexes formed during solvent extraction

Autori: Patrik Weßling, Michael Trumm, Andreas Geist, Petra J. Panak
Pubblicato in: Dalton Transactions, Numero 47/32, 2018, Pagina/e 10906-10914, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/c8dt02504e

Modified diglycolamides for grouped actinide separation

Autori: Rikard Malmbeck, Daniel Magnusson, Andreas Geist
Pubblicato in: Journal of Radioanalytical and Nuclear Chemistry, Numero 314/3, 2017, Pagina/e 2531-2538, ISSN 0236-5731
Editore: Akademiai Kiado
DOI: 10.1007/s10967-017-5614-2

Optimization and Single-Stage Centrifugal Contactor Experiments with the Novel Hydrophilic Complexant PyTri-Diol for the i -SANEX Process

Autori: Eros Mossini, Elena Macerata, Andreas Wilden, Peter Kaufholz, Giuseppe Modolo, Nicolò Iotti, Alessandro Casnati, Andreas Geist, Mario Mariani
Pubblicato in: Solvent Extraction and Ion Exchange, Numero 36/4, 2018, Pagina/e 373-386, ISSN 0736-6299
Editore: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1507134

Behaviour of the extractant Me-TODGA upon gamma irradiation: quantification of degradation compounds and individual influences on complexation and extraction

Autori: V. Hubscher-Bruder, V. Mogilireddy, S. Michel, A. Leoncini, J. Huskens, W. Verboom, H. Galán, A. Núñez, J. Cobos, G. Modolo, A. Wilden, H. Schmidt, M.-C. Charbonnel, P. Guilbaud, N. Boubals
Pubblicato in: New Journal of Chemistry, Numero 41/22, 2017, Pagina/e 13700-13711, ISSN 1144-0546
Editore: Royal Society of Chemistry
DOI: 10.1039/c7nj02136d

Synthesis of size-controlled UO 2 microspheres from the hydrothermal conversion of U( iv ) aspartate

Autori: V. Trillaud, J. Maynadié, J. Manaud, J. Hidalgo, D. Meyer, R. Podor, N. Dacheux, N. Clavier
Pubblicato in: CrystEngComm, Numero 20/48, 2018, Pagina/e 7749-7760, ISSN 1466-8033
Editore: Royal Society of Chemistry
DOI: 10.1039/c8ce01352g

2,6-Bis(1-alkyl-1H-1,2,3-triazol-4-yl)-pyridines: selective lipophilic chelating ligands for minor actinides

Autori: Annalisa Ossola, Elena Macerata, Eros Mossini, Marco Giola, Maria Chiara Gullo, Arturo Arduini, Alessandro Casnati, Mario Mariani
Pubblicato in: Journal of Radioanalytical and Nuclear Chemistry, Numero 318/3, 2018, Pagina/e 2013-2022, ISSN 0236-5731
Editore: Akademiai Kiado
DOI: 10.1007/s10967-018-6253-y

Application of quantum mechanical simulations for studying the radiolytic stability of prospective extractants in the nuclear fuel cycle

Autori: Tomáš Koubský, Jakub Luštinec
Pubblicato in: Journal of Radioanalytical and Nuclear Chemistry, Numero 318/3, 2018, Pagina/e 2407-2413, ISSN 0236-5731
Editore: Akademiai Kiado
DOI: 10.1007/s10967-018-6225-2

Extraction Properties of 4-Tetra(hydroxyphenyl)BTPhen in Liquid-Liquid Extraction Systems with Cyclohexanone/Octanol or in a Solid-Phase Extraction System

Autori: Laurence M. Harwood, Jan John, Ashfaq Afsar, Jasraj S. Babra, Petr Distler, Iain Hopkins, James Westwood, Zoe Y. Selfe
Pubblicato in: HETEROCYCLES, Numero 101/1, 2020, Pagina/e 209, ISSN 0385-5414
Editore: Elsevier BV
DOI: 10.3987/com-19-s(f)14

Thermodynamic parameters of Am(III), Cm(III) and Eu(III) extraction by CyMe4-BTPhen in cyclohexanone from HNO3 solutions

Autori: Petr Distler, Karel Stamberg, Jan John, Laurence M. Harwood, Frank W. Lewis
Pubblicato in: The Journal of Chemical Thermodynamics, Numero 141, 2020, Pagina/e 105955, ISSN 0021-9614
Editore: Academic Press
DOI: 10.1016/j.jct.2019.105955

Activation of the Aromatic Core of 3,3′-(Pyridine-2,6-diylbis(1 H -1,2,3-triazole-4,1-diyl))bis(propan-1-ol)—Effects on Extraction Performance, Stability Constants, and Basicity

Autori: Patrik Weßling, Michael Trumm, Elena Macerata, Annalisa Ossola, Eros Mossini, Maria Chiara Gullo, Arturo Arduini, Alessandro Casnati, Mario Mariani, Christian Adam, Andreas Geist, Petra J. Panak
Pubblicato in: Inorganic Chemistry, Numero 58/21, 2019, Pagina/e 14642-14651, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b02325

On the basic extraction properties of a phenyl trifuoromethyl sulfone based GANEX system containing CyMe4-BTBP and TBP.

Autori: J. Halleröd, Ch. Ekberg, T. Authen, L. Bertolo, Mu Lin, B. Grüner, J. Švehla, Ch. Wagner, A. Geist, P. Panak, E. Aneheim.
Pubblicato in: Solvent Extraction and Ion Exchange, Numero Vol. 36, Numero 4, 2018, Pagina/e 360-372, ISSN 0736-6299
Editore: Marcel Dekker Inc.
DOI: 10.1080/07366299.2018.1497043

Stability studies of GANEX system under different irradiation conditions

Autori: Iván Sánchez-García, Hitos Galán, Jose Manuel Perlado, Joaquín Cobos
Pubblicato in: EPJ Nuclear Sciences & Technologies, Numero 5, 2019, Pagina/e 19, ISSN 2491-9292
Editore: EDP Sciences
DOI: 10.1051/epjn/2019049

Do An( iii ) and Ln( iii ) ions form heteroleptic complexes with diglycolamide and hydrophilic BT(B)P ligands in solvent extraction systems? A spectroscopic and DFT study

Autori: Irena Herdzik-Koniecko, Christoph Wagner, Michael Trumm, Udo Müllich, Bernd Schimmelpfennig, Jerzy Narbutt, Andreas Geist, Petra J. Panak
Pubblicato in: New Journal of Chemistry, Numero 43/16, 2019, Pagina/e 6314-6322, ISSN 1144-0546
Editore: Royal Society of Chemistry
DOI: 10.1039/c9nj00651f

Gamma and pulsed electron radiolysis studies of CyMe4BTBP and CyMe4BTPhen: identification of radiolysis products and effects on the hydrometallurgical separation of trivalent actinides and lanthanides

Autori: Schmidt H., Wilden* A., Modolo G., Bosbach D., Santiago-Schübel B., HupertM., Mincher B. J., Mezyk S. P., Švehla J., Grüner B., Ekberg Ch.,
Pubblicato in: Radiation Phys. Chem., Numero 12 issues/ year, 2021, Pagina/e 31 pp., ISSN 0969-806X
Editore: Pergamon Press Ltd.

Evaluation of the Hydrophilic Complexant N,N,N’,N’ -tetraethyldiglycolamide (TEDGA) and its Methyl-substituted Analogues in the Selective Am(III) Separation

Autori: Larissa Klaß, Andreas Wilden, Fabian Kreft, Christoph Wagner, Andreas Geist, Petra J. Panak, Irena Herdzik-Koniecko, Jerzy Narbutt, Giuseppe Modolo
Pubblicato in: Solvent Extraction and Ion Exchange, Numero 37/5, 2019, Pagina/e 297-312, ISSN 0736-6299
Editore: Marcel Dekker Inc.
DOI: 10.1080/07366299.2019.1651039

Fabrication of Nd- and Ce-doped uranium dioxide microspheres via internal gelation

Autori: Christian Schreinemachers; Gregory Leinders; Giuseppe Modolo; Marc Verwerft; Koen Binnemans; Thomas Cardinaels
Pubblicato in: Journal of Nuclear Materials, Numero 21, 2020, ISSN 0022-3115
Editore: Elsevier BV

Solvent Extraction for Nuclear Power

Autori: Jerzy Narbutt
Pubblicato in: Liquid-Phase Extraction, Numero Handbooks in Separation Science, Colin F. Poole, Editor, 2020, Pagina/e 725-744, ISBN 9780128169117
Editore: Elsevier
DOI: 10.1016/b978-0-12-816911-7.00024-4

The use of synergistic effects of lipophilic modifiers of TODGA-containing organic phase for improving separation of Am(III) from the early lanthanides in the process of stripping the metals with hydrophilic ligands. A novel concept for solving the problem

Autori: Jerzy Narbutt, Irena Herdzik-Koniecko, Magdalena Rejnis-Strzelak
Pubblicato in: RAPORTY IChTJ, SERIA B, Numero Nr 2/2017, 2017, Pagina/e 1 - 14, ISSN 1425-7351
Editore: ICHTJ

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