Renewable Hydride Donors and Their Utilization in Catalytic Reduction and Deoxygenation Reactions

Informazioni relative al progetto

ReNewHydrides

ID dell’accordo di sovvenzione: 818260

DOI

10.3030/818260

Progetto chiuso

Data della firma CE 8 Febbraio 2019

Data di avvio 1 Ottobre 2019

Data di completamento 30 Settembre 2025

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale

€ 1 999 837,50

Contributo UE

€ 1 999 837,50

Coordinato da

COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
France

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I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Pubblicazioni

Peer reviewed articles (38)

Additive-free selective methylation of secondary amines with formic acid over a Pd/In$_2$O$_3$ catalyst

Autori: Caroline Genre; Idir Benaissa; Timothé Godou; Mathieu Pinault; Thibault Cantat
Pubblicato in: Catalysis Science and Technology, Numero 1, 2022, ISSN 2044-4761
Editore: RSC
DOI: 10.1039/d1cy01626a

Water-Mediated Rhenium-Catalyzed Photodeoxygenation of Polyfunctional Organic N-Oxides

Autori: Nicolas Joly, Marianne Kjellberg, Alexis Bouchet, Emmanuel Nicolas, Thibault Cantat, Lucile Anthore-Dalion
Pubblicato in: Synthesis, Numero 57, 2025, Pagina/e 3370-3376, ISSN 0039-7881
Editore: Georg Thieme Verlag
DOI: 10.1055/a-2649-0086

Reductive depolymerization of polyesters and polycarbonates with hydroboranes by using a lanthanum(III) tris(amide) catalyst

Autori: Marie Kobylarski; Jean-Claude Berthet; Thibault Cantat
Pubblicato in: Chemical Communications, Numero 1, 2021, ISSN 1364-548X
Editore: RSC
DOI: 10.1039/d2cc00184e

Catalytic Reduction of Imines with Silylformates: Formation of Silyl Carbamates through CO ₂ Insertion

Autori: Neethu Thyagarajan, Ruqaya Buhaibeh, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Chemistry – A European Journal, Numero 31, 2025, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202403907

Fluorophosphoniums as Lewis acids in organometallic catalysis: application to the carbonylation of β-lactones

Autori: Marie-Hélène Pietraru, Louise Ponsard, Nicolas Lentz, Pierre Thuéry, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Chemical Communications, Numero 60, 2024, Pagina/e 1043-1046, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/d3cc04282k

Breaking C–O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes

Autori: Louis Monsigny, Pierre Thuéry, Jean-Claude Berthet, Thibault Cantat
Pubblicato in: ACS Catalysis, Numero 9/10, 2019, Pagina/e 9025-9033, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.9b01408

Experimental Evaluation of the Hydricity of Hydrosilanes

Autori: Laurent Sévery, Emmanuel Nicolas, Alexis Mifleur, Thibault Cantat
Pubblicato in: Inorganic Chemistry, Numero 64, 2025, Pagina/e 12927-12931, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.5c01201

Production of Methane by Catalytic Decarboxylation of Methyl Formate as a Liquid Surrogate

Autori: Nathan De Riggi, Arnaud Imberdis, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Organometallics, Numero 43, 2025, Pagina/e 2466-2471, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.4c00023

The Role of (tBuPOCOP)Ir(I) and Iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes

Autori: Gabriel Durin; Jean-Claude Berthet; Emmanuel Nicolas; Pierre Thuéry; Thibault Cantat
Pubblicato in: Organometallics, Numero 1, 2021, ISSN 1520-6041
Editore: ACS
DOI: 10.33774/chemrxiv-2021-2cff1

Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex

Autori: Nicolas Lentz, Alicia Aloisi, Pierre Thuéry, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Organometallics, Numero 40/5, 2021, Pagina/e 565-569, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.0c00777

Catalytic Metal-Free Deoxygenation of Nitrous Oxide with Disilanes

Autori: Lucile Anthore-Dalion, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: ACS Catalysis, Numero 9/12, 2019, Pagina/e 11563-11567, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.9b04434

Scandium‐Catalyzed Highly Selective Deoxygenation of Alcohols by Using Hydrosilanes as Reductants

Autori: Ruqaya Buhaibeh, Neethu Thyagarajan, Guillaume Bousrez, Louis Monsigny, Thibault Cantat, Emmanuel Nicolas
Pubblicato in: Chemistry – A European Journal, Numero 31, 2025, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202501596

Coupling Electrocatalytic CO 2 Reduction with Thermocatalysis Enables the Formation of a Lactone Monomer

Autori: Louise Ponsard, Emmanuel Nicolas, Ngoc Huan Tran, Sarah Lamaison, David Wakerley, Thibault Cantat, Marc Fontecave
Pubblicato in: ChemSusChem, Numero 14/10, 2021, Pagina/e 2198-2204, ISSN 1864-5631
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202100459

Catalytic methoxylation of aryl halides using $^{13}$C- and $^{14}$C-labeled CO$_2$

Autori: Alexia Ohleier; Antoine Sallustrau; Bouchaib Mouhsine; Fabien Caillé; Davide Audisio; Thibault Cantat
Pubblicato in: http://dx.doi.org/10.1039/D2CC03746G, Numero 1, 2022, ISSN 1364-548X
Editore: RSC
DOI: 10.1039/d2cc03746g

A Copper(I)-Catalyzed Sulfonylative Hiyama Cross-Coupling.

Autori: Adenot, Aurélien; Anthore-Dalion, Lucile; Nicolas, Emmanuel; Berthet, Jean-Claude; Thuéry, Pierre; Cantat, Thibault; Berthet, Jean‐Claude
Pubblicato in: Chemistry - A European Journal, Numero 1, 2021, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202103371

SO 2 conversion to sulfones: development and mechanistic insights of a sulfonylative Hiyama cross-coupling

Autori: Aurélien Adenot, Joëlle Char, Niklas von Wolff, Guillaume Lefèvre, Lucile Anthore-Dalion, Thibault Cantat
Pubblicato in: Chemical Communications, Numero 55/86, 2019, Pagina/e 12924-12927, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/c9cc06858a

Evaluation of acetophenone as a novel alcohol-cycloalkane bifunctional liquid organic hydrogen carrier (LOHC)

Autori: Florian D'Ambra, Julia Levy, Parviz Hajiyev, Thibault Cantat, Gérard Gébel, Vincent Faucheux, Emmanuel Nicolas
Pubblicato in: International Journal of Hydrogen Energy, Numero 48, 2025, Pagina/e 33207-33222, ISSN 0360-3199
Editore: Pergamon Press Ltd.
DOI: 10.1016/j.ijhydene.2023.05.024

Metal‐Free Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with “Inverse” Frustrated Lewis Pairs**

Autori: Gabriel Durin, Jean‐Claude Berthet, Pierre Thuéry, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Chemistry – A European Journal, Numero 29, 2025, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202302155

Reduction of secondary amides to imines catalysed by Schwartz’s reagent

Autori: Liam Donnelly; Jean-Claude Berthet; Thibault Cantat
Pubblicato in: Angewandte Chemie Internation Edition, Numero 2, 2022, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202206170

Additive‐Free Pd/In₂O₃‐Catalyzed <i>N</i>‐methylation of Primary Amides by Using Formic Acid

Autori: Idir Benaissa, Kassiogé Dembélé, Thibault Cantat, Caroline Genre
Pubblicato in: ChemCatChem, Numero 16, 2025, ISSN 1867-3880
Editore: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.202400807

The Role of ( ^{<i>t</i> Bu} POCOP)Ir(I) and Iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes

Autori: Gabriel Durin, Jean-Claude Berthet, Emmanuel Nicolas, Pierre Thuéry, Thibault Cantat
Pubblicato in: Organometallics, Numero 41, 2023, Pagina/e 1786-1796, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.1c00576

CO₂/¹³CO₂ Dynamic Exchange in the Formate Complex [(2,9-(^<i>t</i>Bu)₂-phen)Cu(O₂CH)] and Its Catalytic Activity in the Dehydrogenation of Formic Acid

Autori: Kieu Phung, Pierre Thuéry, Jean-Claude Berthet, Thibault Cantat
Pubblicato in: Organometallics, Numero 42, 2023, Pagina/e 3357-3365, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.3c00302

Catalyst‐Free Depolymerization of Aromatic and Aliphatic Polyesters Using Me₃SiI

Autori: Xin Liu, Marie Kobylarski, Jean‐Claude Berthet, Thibault Cantat
Pubblicato in: European Journal of Organic Chemistry, Numero 28, 2025, ISSN 1434-193X
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.202401379

Formoxyboranes as hydroborane surrogates for the catalytic reduction of carbonyls through transfer hydroboration

Autori: Gabriel Durin, R. Martin Romero, Timothé Godou, Clément Chauvier, Pierre Thuéry, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Catalysis Science &amp; Technology, Numero 14, 2024, Pagina/e 1848-1853, ISSN 2044-4753
Editore: Royal Society of Chemistry
DOI: 10.1039/d3cy01702h

Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

Autori: R. Martin Romero; Neethu Thyagarajan; Nora Hellou; Clément Chauvier; Timothé Godou; Lucile Anthore-Dalion; Thibault Cantat
Pubblicato in: "Chemical Communications, 2022, 58, pp.6308-6311. &#x27E8;10.1039/D2CC00666A&#x27E9;", Numero 1, 2022, ISSN 1364-548X
Editore: RSC
DOI: 10.26434/chemrxiv-2022-ww7pj-v2

Transition‐Metal‐Free Acceptorless Decarbonylation of Formic Acid Enabled by a Liquid Chemical‐Looping Strategy

Autori: Arnaud Imberdis, Guillaume Lefèvre, Thibault Cantat
Pubblicato in: Angewandte Chemie International Edition, Numero 58/48, 2019, Pagina/e 17215-17219, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201909039

Catalytic Carbonylation of Acrylic Acid to Succinic Anhydride**

Autori: Marie‐Hélène Pietraru, Nicolas Lentz, Louise Ponsard, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: ChemCatChem, Numero 15, 2025, ISSN 1867-3880
Editore: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.202300720

Alkyl Formates as Transfer Hydroalkylation Reagents and Their Use in the Catalytic Conversion of Imines to Alkylamines**

Autori: Etienne Crochet, Lucile Anthore‐Dalion, Thibault Cantat
Pubblicato in: Angewandte Chemie International Edition, Numero 62, 2023, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202214069

Metal-free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes

Autori: Gabriel Durin; Albane Fontaine; Jean-Claude Berthet; Emmanuel Nicolas; Pierre Thuéry; Thibault Cantat
Pubblicato in: Angewandte Chemie International Edition, Numero 2, 2022, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202200911

Photocatalytic deoxygenation of N–O bonds with Rhenium complexes: from the reduction of nitrous oxide to pyridine N-oxides

Autori: Thibault Cantat; Lucile Anthore-Dalion; Emmanuel Nicolas; Pierre Thuéry; Alexia Ohleier; Marianne Kjellberg
Pubblicato in: Chemical Science, Numero 1, 2021, ISSN 2041-6539
Editore: RSC
DOI: 10.1039/d1sc01974k

Catalytic Disproportionation of Formic Acid to Methanol by using Recyclable Silylformates

Autori: Clément Chauvier, Arnaud Imberdis, Pierre Thuéry, Thibault Cantat
Pubblicato in: Angewandte Chemie International Edition, Numero 59/33, 2020, Pagina/e 14019-14023, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202002062

Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases

Autori: Gabriel Durin; Jean-Claude Berthet; Emmanuel Nicolas; Thibault Cantat
Pubblicato in: ACS Catalysis, Numero 1, 2021, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.1c01515

Catalyst-free depolymerization of polycaprolactone to silylated monoesters and iodide derivatives using iodosilanes

Autori: Xin Liu, Marie Kobylarski, Jean-Claude Berthet, Thibault Cantat
Pubblicato in: Chemical Communications, Numero 59, 2024, Pagina/e 11228-11231, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/d3cc03029f

Catalytic challenges and strategies for the carbonylation of σ-bonds

Autori: Tawfiq Nasr Allah, Louise Ponsard, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Green Chemistry, Numero 23/2, 2021, Pagina/e 723-739, ISSN 1463-9262
Editore: Royal Society of Chemistry
DOI: 10.1039/d0gc02343d

Hydrogenolysis of Haloboranes: from Synthesis of Hydroboranes to Formal Hydroboration Reactions

Autori: Guilhem Zwart, Alexis Mifleur, Gabriel Durin, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Angewandte Chemie International Edition, Numero 63, 2025, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202411468

Copper-Ligand Cooperativity in H$_2$ Activation Enables the Synthesis of Copper Hydride Complexes

Autori: Alicia Aloisi; Étienne Crochet; Emmanuel Nicolas; Jean-Claude Berthet; Camille Lescot; Pierre Thuéry; Thibault Cantat
Pubblicato in: Organometallics, Numero 1, 2021, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.1c00212

Uranyl(VI) Triflate as Catalyst for the Meerwein-Ponndorf-Verley Reaction.

Autori: Marie Kobylarski; Louis Monsigny; Pierre Thuéry; Jean-Claude Berthet; Thibault Cantat
Pubblicato in: Inorganic Chemistry, Numero 1, 2021, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c01798

Zirconium-catalysed hydrosilylation of esters and depolymerisation of polyester plastic waste

Autori: Marie Kobylarski; Liam J. Donnelly; Jean-Claude Berthet; Thibault Cantat
Pubblicato in: 2022, Numero 1, 2022, ISSN 1463-9262
Editore: Royal Society of Chemistry
DOI: 10.26434/chemrxiv-2022-xtzxz