Renewable Hydride Donors and Their Utilization in Catalytic Reduction and Deoxygenation Reactions

Informazioni relative al progetto

ReNewHydrides

ID dell’accordo di sovvenzione: 818260

DOI 10.3030/818260

Data della firma CE 8 Febbraio 2019

Data di avvio 1 Ottobre 2019

Data di completamento 30 Settembre 2025

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale € 1 999 837,50

Contributo UE € 1 999 837,50

Coordinato da

COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
France

Pubblicazioni

Peer reviewed articles (21)

Additive-free selective methylation of secondary amines with formic acid over a Pd/In$_2$O$_3$ catalyst

Autori: Caroline Genre; Idir Benaissa; Timothé Godou; Mathieu Pinault; Thibault Cantat
Pubblicato in: Catalysis Science and Technology, Numero 1, 2022, ISSN 2044-4761
Editore: RSC
DOI: 10.1039/d1cy01626a

Reductive depolymerization of polyesters and polycarbonates with hydroboranes by using a lanthanum(III) tris(amide) catalyst

Autori: Marie Kobylarski; Jean-Claude Berthet; Thibault Cantat
Pubblicato in: Chemical Communications, Numero 1, 2021, ISSN 1364-548X
Editore: RSC
DOI: 10.1039/d2cc00184e

Breaking C–O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes

Autori: Louis Monsigny, Pierre Thuéry, Jean-Claude Berthet, Thibault Cantat
Pubblicato in: ACS Catalysis, Numero 9/10, 2019, Pagina/e 9025-9033, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.9b01408

The Role of (tBuPOCOP)Ir(I) and Iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes

Autori: Gabriel Durin; Jean-Claude Berthet; Emmanuel Nicolas; Pierre Thuéry; Thibault Cantat
Pubblicato in: Organometallics, Numero 1, 2021, ISSN 1520-6041
Editore: ACS
DOI: 10.33774/chemrxiv-2021-2cff1

Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex

Autori: Nicolas Lentz, Alicia Aloisi, Pierre Thuéry, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Organometallics, Numero 40/5, 2021, Pagina/e 565-569, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.0c00777

Catalytic Metal-Free Deoxygenation of Nitrous Oxide with Disilanes

Autori: Lucile Anthore-Dalion, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: ACS Catalysis, Numero 9/12, 2019, Pagina/e 11563-11567, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.9b04434

Coupling Electrocatalytic CO 2 Reduction with Thermocatalysis Enables the Formation of a Lactone Monomer

Autori: Louise Ponsard, Emmanuel Nicolas, Ngoc Huan Tran, Sarah Lamaison, David Wakerley, Thibault Cantat, Marc Fontecave
Pubblicato in: ChemSusChem, Numero 14/10, 2021, Pagina/e 2198-2204, ISSN 1864-5631
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202100459

Catalytic methoxylation of aryl halides using $^{13}$C- and $^{14}$C-labeled CO$_2$

Autori: Alexia Ohleier; Antoine Sallustrau; Bouchaib Mouhsine; Fabien Caillé; Davide Audisio; Thibault Cantat
Pubblicato in: http://dx.doi.org/10.1039/D2CC03746G, Numero 1, 2022, ISSN 1364-548X
Editore: RSC
DOI: 10.1039/d2cc03746g

A Copper(I)-Catalyzed Sulfonylative Hiyama Cross-Coupling.

Autori: Adenot, Aurélien; Anthore-Dalion, Lucile; Nicolas, Emmanuel; Berthet, Jean-Claude; Thuéry, Pierre; Cantat, Thibault; Berthet, Jean‐Claude
Pubblicato in: Chemistry - A European Journal, Numero 1, 2021, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202103371

SO 2 conversion to sulfones: development and mechanistic insights of a sulfonylative Hiyama cross-coupling

Autori: Aurélien Adenot, Joëlle Char, Niklas von Wolff, Guillaume Lefèvre, Lucile Anthore-Dalion, Thibault Cantat
Pubblicato in: Chemical Communications, Numero 55/86, 2019, Pagina/e 12924-12927, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/c9cc06858a

Reduction of secondary amides to imines catalysed by Schwartz’s reagent

Autori: Liam Donnelly; Jean-Claude Berthet; Thibault Cantat
Pubblicato in: Angewandte Chemie Internation Edition, Numero 2, 2022, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202206170

Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

Autori: R. Martin Romero; Neethu Thyagarajan; Nora Hellou; Clément Chauvier; Timothé Godou; Lucile Anthore-Dalion; Thibault Cantat
Pubblicato in: "Chemical Communications, 2022, 58, pp.6308-6311. ⟨10.1039/D2CC00666A⟩", Numero 1, 2022, ISSN 1364-548X
Editore: RSC
DOI: 10.26434/chemrxiv-2022-ww7pj-v2

Transition‐Metal‐Free Acceptorless Decarbonylation of Formic Acid Enabled by a Liquid Chemical‐Looping Strategy

Autori: Arnaud Imberdis, Guillaume Lefèvre, Thibault Cantat
Pubblicato in: Angewandte Chemie International Edition, Numero 58/48, 2019, Pagina/e 17215-17219, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201909039

Metal-free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes

Autori: Gabriel Durin; Albane Fontaine; Jean-Claude Berthet; Emmanuel Nicolas; Pierre Thuéry; Thibault Cantat
Pubblicato in: Angewandte Chemie International Edition, Numero 2, 2022, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202200911

Photocatalytic deoxygenation of N–O bonds with Rhenium complexes: from the reduction of nitrous oxide to pyridine N-oxides

Autori: Thibault Cantat; Lucile Anthore-Dalion; Emmanuel Nicolas; Pierre Thuéry; Alexia Ohleier; Marianne Kjellberg
Pubblicato in: Chemical Science, Numero 1, 2021, ISSN 2041-6539
Editore: RSC
DOI: 10.1039/d1sc01974k

Catalytic Disproportionation of Formic Acid to Methanol by using Recyclable Silylformates

Autori: Clément Chauvier, Arnaud Imberdis, Pierre Thuéry, Thibault Cantat
Pubblicato in: Angewandte Chemie International Edition, Numero 59/33, 2020, Pagina/e 14019-14023, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202002062

Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases

Autori: Gabriel Durin; Jean-Claude Berthet; Emmanuel Nicolas; Thibault Cantat
Pubblicato in: ACS Catalysis, Numero 1, 2021, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.1c01515

Catalytic challenges and strategies for the carbonylation of σ-bonds

Autori: Tawfiq Nasr Allah, Louise Ponsard, Emmanuel Nicolas, Thibault Cantat
Pubblicato in: Green Chemistry, Numero 23/2, 2021, Pagina/e 723-739, ISSN 1463-9262
Editore: Royal Society of Chemistry
DOI: 10.1039/d0gc02343d

Copper-Ligand Cooperativity in H$_2$ Activation Enables the Synthesis of Copper Hydride Complexes

Autori: Alicia Aloisi; Étienne Crochet; Emmanuel Nicolas; Jean-Claude Berthet; Camille Lescot; Pierre Thuéry; Thibault Cantat
Pubblicato in: Organometallics, Numero 1, 2021, ISSN 0276-7333
Editore: American Chemical Society
DOI: 10.1021/acs.organomet.1c00212

Uranyl(VI) Triflate as Catalyst for the Meerwein-Ponndorf-Verley Reaction.

Autori: Marie Kobylarski; Louis Monsigny; Pierre Thuéry; Jean-Claude Berthet; Thibault Cantat
Pubblicato in: Inorganic Chemistry, Numero 1, 2021, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c01798

Zirconium-catalysed hydrosilylation of esters and depolymerisation of polyester plastic waste

Autori: Marie Kobylarski; Liam J. Donnelly; Jean-Claude Berthet; Thibault Cantat
Pubblicato in: 2022, Numero 1, 2022, ISSN 1463-9262
Editore: Royal Society of Chemistry
DOI: 10.26434/chemrxiv-2022-xtzxz