Descrizione del progetto
Un metodo non distruttivo per studiare le proprietà chimiche e fisiche dei nanomateriali colloidali
I colloidi sono miscele complesse in cui particelle microscopiche di una sostanza sono uniformemente disperse in una seconda sostanza. Nell’industria, sono utilizzati nella lavorazione degli alimenti, nei cosmetici e nelle vernici in emulsione per ottenere le proprietà di flusso necessarie. Le moderne fonti di luce a raggi X sono perfette per studiare le reazioni e le strutture dei composti chimici. Tuttavia, le radiazioni forti distruggono i nanomateriali colloidali. Il progetto LINCHPIN, finanziato dall’UE, si propone di sviluppare microreattori innovativi che dovrebbero permettere ai ricercatori di analizzare i nanomateriali colloidali usando metodi di radiazione non distruttivi. Il lavoro del progetto potrebbe portare allo sviluppo di nanomateriali con eccellenti proprietà elettroniche da utilizzare nella conversione e nello stoccaggio dell’energia.
Obiettivo
The recent successful applications of photon-in-photon-out spectroscopy in condense matter physics, bio-inorganic chemistry and catalysis build upon the high brilliance of modern X-ray sources and realization of dedicated emission spectrometers. However, probing with highly energetic X-ray beam puts many constraints on the sample environment and requires probing faster than the X-ray radiation damage occurs. This strongly limits the applicability of the method in studying the chemistry of colloidal nanomaterials.
The objective of LINCHPIN is to investigate the emergence of electronic structure of nanomaterials in solution by hard X-ray photon-in-photon-out spectroscopy. To reach this very ambitious target, LINCHPIN consolidates an interdisciplinary engineering, spectroscopic and chemically driven effort. My group aim for developing micro-reactors, which will enable new fundamental insights related to the chemistry and electronic properties of the transition metal nitrides and sulfides.
The main scientific goals are to study at the relevant time scales the kinetics and dynamics of: (a) short-lived molecular intermediate states and pre-nucleation clusters, (b) metal-sulfur and metal-nitrogen bond formation and their condensation in solution, (c) electronic structure changes during growth of nanostructures, and (d) concurrently interdependent electronic and chemical processes. The ultimate goal is to have a handle on designing and selecting, still in the reaction solution, the nanomaterials with the most promising electronic properties relevant for energy conversion and storage. Moreover, the proposed micro-reactors along with experimental spectroscopic protocols and the concurrent fundamental knowledge create a paradigm shift for in situ time-resolved experiments with an impact in many other fields ranging from catalysis, sustainable flow chemistry to biomedical applications.
Campo scientifico
- natural scienceschemical sciencesinorganic chemistrybioinorganic chemistry
- natural scienceschemical sciencescatalysis
- engineering and technologynanotechnologynano-materials
- engineering and technologyenvironmental engineeringenergy and fuelsenergy conversion
- natural sciencesphysical sciencesopticsspectroscopy
Parole chiave
Programma(i)
Argomento(i)
Meccanismo di finanziamento
ERC-COG - Consolidator GrantIstituzione ospitante
20148 Hamburg
Germania