Carbon Captured Fuel and Energy Carriers for an Intensified Steel Off-Gases based Electricity Generation in a Smarter Industrial Ecosystem

Información del proyecto

C2FUEL

Identificador del acuerdo de subvención: 838014

DOI

10.3030/838014

Proyecto finalizado el 17 Octubre 2023

Fecha de la firma de la CE 3 Mayo 2019

Fecha de inicio 1 Junio 2019

Fecha de finalización 30 Noviembre 2023

Financiado con arreglo a

• SOCIETAL CHALLENGES - Secure, clean and efficient energy

Coste total

€ 4 130 291,25

Aportación de la UE

€ 3 999 840,00

Coordinado por

ENGIE
France

CORDIS proporciona enlaces a los documentos públicos y las publicaciones de los proyectos de los programas marco HORIZONTE.

Los enlaces a los documentos y las publicaciones de los proyectos del Séptimo Programa Marco, así como los enlaces a algunos tipos de resultados específicos, como conjuntos de datos y «software», se obtienen dinámicamente de OpenAIRE .

Resultado final

Documents, reports (23)

Report on 5000 hours durability of SOE stack under relevant operation conditions

Results of 5000 hours durability test of a SOE stack under optimal conditions. Conclusion on components that dominate degradation phenomena (task 2.3).

DK6 demonstration site ready for unit integration

Report of preliminary assessment regarding safety, security, regulatory aspects and site constraints. Delivery of Hazop and ATEX analysis of the integrated process. Achievement of site preparation and zoning scheme for demonstrator installation (subtask 5.1.1).

Process of FA production from electroreduction

Report on development, validation and test of CO2 electroreduction catalyst. Definition of optimal system and operating conditions for FA production (task 4.4 and task 4.6).

Influence of pressure on the single cells performance and durability

Results of electrochemical and microstructural analysis of a single cell under different operating pressures. Results of a 500 hours durability test at high pressure (subtask 2.2.4).

Multiscale modelling results

Results of the 0D and 3D SOE stack models developed in task 2.4 under steady and dynamic states. Delivery of a SOE stack model to integrate to the demonstration pilot model.

Technical workshop summary

Presentation of project first results WP1 to WP4 to a wide international audience task 74

Goal and scope of the LCA

Definition of goal and scope of the LCA. Creation of data collection templates to manage collection process (task 6.3).

Steel-off gases pre-treatment unit design

Definition of the pretreatment section required before CO2 conditioning step Integration of the gas treatment unit within demonstrator pilot subtask 121

Results for combustion engine test from DME

Report of tests performed on a DME internal combustion engine prototype. Measurement of differences on emissions and combustion compared to a Diesel engine (task 5.5).

Report on 5000 hours durability test of SOEC under relevant operation conditions

Results of electrochemical and microstructural analysis of a single cell operating under the previously identified optimal operation conditions. Conclusion on SOEC reliability for hydrogen and syngas production (subtask 2.2.6).

Demonstration workshop summary

Hosted workshop to give a public show of the demonstration of C2FUEL operation (task 7.4).

Study of social acceptance of the C2FUEL project (1)

Intermediate results of social acceptance of C2FUEL project. Partial communication analysis and first interviews report (task 7.1).

Catalyst synthetized for FA production

Results of tested catalysts for formic acid production. Definition of selected catalyst and results of high pressure operation and long term stability tests (task 4.2).

Characterization of the stacks performances during high temperature electrolysis

Results of electrochemical and microstructural analysis of stacks operating under the previously identified optimal operation conditions (task 2.3).

Preliminary Environmental assessment through LCA

Report of preliminary LCA to identify most significant environmental impacts and sensitive parameters (task 6.3).

Specifications for the demonstrator

Portfolio of all data gathered in task 11 and task 12 to define precisely the KPI of the demonstrator systems to be built within C2FUEL project

Electricity production and consumption in Dunkirk area

Analysis of Dunkirk area electricity sourcing. Assessment of renewable electricity surplus potential. Levelized cost forecast of both grid and renewable electricity (task 1.4).

Influence of operation conditions on single cells performance and durability

Identification of safe operation conditions range based on single cell tests Delivery of a suitable operation strategy to increase lifespan of single cells and SOE stacks subtask 221 Results of dynamic operation tests subtask 225

Influence of sweeping gases on the single cells performance and durability

Results of electrochemical impedance spectroscopy and post-test microstructure analysis of a single cell operating under different sweeping gases. Impact of sweeping gas on the oxygen electrode degradation (subtask 2.2.3).

Results for H2 regeneration from FA

Report of the 25 kW FA 2 Power system demonstration and regeneration of hydrogen to validate the route of seasonal storage (task 5.4).

Influence of CO2 impurities on the single cells performance and durability

Results of electrochemical impedance spectroscopy tests of a single cell operating under identified types and concentrations of impurities. Level of impact on cell performance and durability (subtask 2.2.2).

Results from CO2 conversion from FA demonstrator

Report of lab-scale demonstrator testing and validation according to predefined KPI (task 5.3).

Analysis of reactor types and spinning disc reactor lab scale design and testing

Assessment of possible reactor technologies to sue for FA production. Results of KPI analysis to identify suitable technology (task 4.3).

Websites, patent fillings, videos etc. (4)

Newsletters 3

External communication and dissemination of C2FUEL project results task 73

Project website

A public project website will be set up by M6 by ENGIE in order to widely communicate and disseminate project results (task 7.3).

Newsletters 1

Communication through project documentation, media and local newspapers to measure social acceptance of the project. Organisation of an interview survey with local stakeholders (task 7.1).

Newsletters 2

Organized workshops to establish a first mapping of key stakeholders. Communication through providing and sharing of scientific information as well as action coordination (task 7.2).

Demonstrators, pilots, prototypes (1)

Lab-scale demonstrator for FA production

Delivery of a 3D design of the reactor. Manufacturing of the FA lab-scale demonstrator.

Publicaciones

Conference proceedings (9)

Presentation of C2FUEL project

Autores: P. Olivier, C. Makhloufi
Publicado en: 2020
Editor: INEA

In2O3 nanoparticles Gas Diffusion Electrode (GDE) (oral)

Autores: Marta C. Figueiredo
Publicado en: Annual Meeting of the Danish Electrochemical society - 29/10/20, 2020
Editor: Danish Electrochemical societ

Presentation of C2FUEL project

Autores: P. Olivier, C. Makhloufi, M. Marrot
Publicado en: 4th INEA workshop on CCUS (sept 2019), 2019
Editor: INEA

Poster: Effect of doping In2O3 with transition metals on the electrocatalytic reduction of CO2 to formate

Autores: Tim Wissink, Marta Figueiredo, Emiel Hensen
Publicado en: EcoCat conference 23-25/11/2020, 2020
Editor: NanoGe

Solid Oxide Electrolyser Demonstrator Development at Elcogen

Autores: Lehtinen, Timo; Noponen, Matti
Publicado en: 2021 Meet. Abstr. MA2021-03 285, Edición 2, 2021
Editor: IOP Publishing
DOI: 10.1149/ma2021-031285mtgabs

EFFECT OF BOEHMITE NANOPARTICLES ON ALUMINA SUPPORTED CARBON MOLECULAR SIEVE MEMBRANES FOR VAPOR/GAS PERMEATION

Autores: SERENA POTO,MARGOT A. LLOSA TANCO, D. ALFREDO PACHECO TANAKA,FAUSTO GALLUCCI, M. FERNANDA NEIRA D’ANGELO
Publicado en: World Online Conference on Sustainable Technologies (WOCST), 2021
Editor: WOCST

Effect of membrane properties on the direct conversion of CO2 to dimethyl ether in a fixed bed membrane reactor

Autores: Serena Poto, Fausto Gallucci, M. Fernanda Neira d’Angelo
Publicado en: 11th International Symposium on Catalysis in Multiphase Reactors (CAMURE-11), 2021
Editor: AIDIC

Techno-economic assessment of the dimethyl ether synthesis via CO2 hydrogenation:conventional vs membrane assisted process (poster)

Autores: Serena Poto, Thomas Vink, Fausto Gallucci, M. Fernanda Neira d’Angelo
Publicado en: Netherlands Process Symposium (NPS-17), 2022
Editor: NPS

PERFORMANCE CHARACTERISTICS OF SOLID OXIDE ELECTROLYSIS TECHNOLOGY FROM ELCOGEN

Autores: Timo Lehtinen, Matti Noponen, Sergii Pylypko and Enn Õunpuu
Publicado en: 45th International Conference and Expo on Advanced Ceramics and Composites (IACC), 2021
Editor: ACerS Engineering Ceramics Division

Other (30)

EFFECT OF MEMBRANE PROPERTIES ON THE DIRECT CONVERSION OF CO2 TO DIMETHYL ETHER IN A FIXED BED MEMBRANE REACTOR (oral)

Autores: SERENA POTO, FAUSTO GALLUCCI, M. FERNANDA NEIRA D’ANGELO
Publicado en: International Conference on Catalysis in Membrane Reactors (ICCMR-15), 2022
Editor: The membrane society of Japan

Kinetic modelling of the methanol synthesis from CO2 and H2 over a CuO/CeO2/ZrO2 catalyst: the role of CO2 and CO hydrogenation

Autores: Serena Poto, Damian Vico van Berkel, Fausto Gallucci, M. Fernanda Neira d’Angelo
Publicado en: North American Catalysis Society Meeting (NAM 27), 2022
Editor: NAM

Catalytic performance study of supported Au catalysts for the direct hydrogenation of CO2 to formic acid

Autores: Anouk de Leeuw den Bouter, Pierre Oliver, Camel Makhloufi, John van der Schaaf
Publicado en: Netherlands’ Catalysis and Chemistry Conference (NCCC), 2022
Editor: NCCC

Design of membrane based gas-liquid absorption units: a fast, efficient, high throughput batch to continuous methodology (abstract)

Autores: E. Ferreri, C. Castel, E. Favre
Publicado en: Euromembrane 2021, 2021
Editor: The Meeting Planners

Design of membrane based gas-liquid absorption units: a fast, efficient, high throughput batch to continuous methodology (oral)

Autores: Eglé FERRERI, Christophe CASTEL, Eric Favre
Publicado en: SFGP 2022, 2022
Editor: Société Française de Génie des Procédés

High temperature electrolysis and co-electrolysis

Autores: M. Noponen, Timo Lehtinen and X. Sun
Publicado en: C2Fuel workshop: International Workshop on CO2 capture and utilization, 2021
Editor: C2Fuel - TU/e

C2FUEL Solid Oxide Electrolyser Demonstration System

Autores: Timo Lehtinen, Matti Noponen
Publicado en: 15th European SOFC & SOE Forum, 2022
Editor: EFCF

Kinetic modelling of the methanol synthesis from CO2 and H2 over a CuO/CeO2/ZrO2 catalyst: the role of CO2 and CO hydrogenation

Autores: S. Poto, M.F. Neira d’Angelo, F. Gallucci
Publicado en: Netherlands’ Catalysis and Chemistry Conference (NCCC), 2022
Editor: NCCC

An industrially-relevant demonstration of a CCU-based circular economy (poster)

Autores: B. Wegman, F. Gallucci, P. Olivier, C. Makhloufi
Publicado en: C2Fuel workshop: International Workshop on CO2 capture and utilization, 2021
Editor: C2Fuel - TU/e

Morphology study of bismuth nanoparticles as catalyst for electrochemical CO2 reduction to formate (poster)

Autores: Alex J.W. Mana, Tim Wissinka, Marta C. Figueiredoa, Emiel J.M. Hensena
Publicado en: Netherlands’ Catalysis and Chemistry Conference (NCCC), 2022
Editor: NCCC

Degradation of solid oxide electrolysis cells under different operation conditions

Autores: Xiufu Sun, Peter Vang Hendriksen, Anne Hauch1, Anders Kring Clausen, Timo Lehtinen, Matti Noponen (abstract)
Publicado en: 17th International Symposium on Solid Oxide Fuel Cells (SOFC), 2021
Editor: The Electrochemical Society

Stability of In2O3 Nanoparticles in Gas Diffusion Electrodes for CO2 Reduction to Formate

Autores: Tim Wissink
Publicado en: Netherlands’ Catalysis and Chemistry Conference (NCCC), 2022
Editor: NCCC

Effect of doping In2O3 with transition metals on the electrocatalytic reduction of CO2 to formate (poster)

Autores: Tim Wissink, Marta C. Figueiredo, Emiel J.M. Hensen
Publicado en: C2Fuel workshop: International Workshop on CO2 capture and utilization, 2021
Editor: C2Fuel - TU/e

Stability of In2O3 Nanoparticles in PTFE-containing Gas Diffusion Electrodes for CO2 Electroreduction to formate

Autores: Tim Wissink, Rim C.J. Van de Poll, Dr. Marta C.C. Figueiredo,Prof. Emiel J.M. Hensen
Publicado en: MAT-SUS conference -Materials for Sustainable Development, 2022
Editor: nanoGe

Effect of the membrane properties on the direct conversion of CO2 to dimethyl ether in a fixed bed membrane reactor (oral)

Autores: S. Poto, M.F. Neira d’Angelo, F. Gallucci
Publicado en: North American Catalysis Society Meeting (NAM 27), 2022
Editor: NAM

EFFECT OF BOEHMITE NANOSHEETS ON ALUMINA SUPPORTED CARBON MOLECULAR SIEVE MEMBRANES FOR VAPOR/GAS PERMEATION: EXPERIMENTAL AND THEORETICAL INVESTIGATION (oral)

Autores: SERENA POTO, MARGOT A. LLOSA TANCO, D. ALFREDO PACHECO TANAK*, FAUSTO GALLUCCI, M. FERNANDA NEIRA D’ANGELO
Publicado en: International Conference on Catalysis in Membrane Reactors (ICCMR-15), 2022
Editor: The membrane society of Japan

PERFORMANCE CHARACTERISTICS OF SOLID OXIDE ELECTROLYSIS TECHNOLOGY FROM ELCOGEN (bstract + presentation video)

Autores: Timo Lehtinen, Matti Noponen, Sergii Pylypko and Enn Õunpuu
Publicado en: 45th International Conference and Expo on Advanced Ceramics and Composites (IACC), 2021
Editor: ACerS Engineering Ceramics Division

Transition metal doped In2O3 for CO2 reduction to formate: How to retain the oxide phase for improved stability

Autores: T. Wissink, M.C.C. Figuereido, E.J.M. Hensen
Publicado en: Netherlands’ Catalysis and Chemistry Conference (NCCC, 2022
Editor: NCCC

Effect of inlet gas composition on the durability of solid oxide electrolysis cells

Autores: Xiufu Sun, Anders Kring Clausen, Peter Vang Hendriksen, Anne Hauch, Timo Lehtinen, Matti Noponen
Publicado en: 2022
Editor: EFCF
DOI: 10.5281/zenodo.7846265

Presentation of C2FUEL project

Autores: Adeline Miquelot
Publicado en: COZMOS workshop on Conversion of CO2 to Fuels, 2023
Editor: COZMOS european project

Presentation of C2FUEL project

Autores: Bérenger WEGMAN
Publicado en: ENGIE AMEA, 2023
Editor: ENGIE

On-Site Demonstration of Pre-Combustion CO2 Capture from Industrial Blast-Furnace Gas with Heterogeneous Hollow-Fiber Contactor Membrane Absorption Modules

Autores: Bérenger WEGMAN, Eglé Ferreri
Publicado en: The 23rd IERE General Meeting and Singapore Forum, 2023
Editor: IERE

On the influence of trialkylamine reduction strategies in the direct hydrogenation of CO2 to formic acid (oral)

Autores: Anouk de Leeuw den Bouter, Lars Vogels, Esther Vogels, Pierre Olivier, Adeline Miquelot, Camel Makhloufi, John van der Schaaf
Publicado en: 2022 AIChE Annual Meeting, 2022
Editor: American Institute of Chemical Engineers.

Membrane contactors for CO2 capture and purification unit at demonstrator scale on industrial operating conditions (oral)

Autores: E. Ferreri
Publicado en: International Conference of Membrane 2023 (ICOM 2023), 2023
Editor: Membrane Society of Australasia

EFFECT OF CARBONIZATION TEMPERATURE ON THE gas PERMEATION OF ALUMINA-CARBON MOLECULAR SIEVE MEMBRANES (Al-CMSM)

Autores: MARGOT A. LLOSA TANCO, SERENA POTO, FAUSTO GALLUCCI,D. ALFREDO PACHECO TANAKA,
Publicado en: International Conference on Catalysis in Membrane Reactors (ICCMR-15), 2022
Editor: The membrane society of Japan

Effect of membrane properties on the direct conversion of CO2 to dimethyl ether in a fixed bed membrane reactor

Autores: Serena POTO, Fausto GALLUCCI, M. Fernanda NEIRA D’ANGELO
Publicado en: 26th International Symposium on Chemical Reaction Engineering (ISCRE-26), 2021
Editor: Department of Chemical Engineering Indian Institute of Technology Delhi

Carbon molecular sieve membranes for water separation in CO2 hydrogenation reactions: effect of the carbonization temperature (oral)

Autores: Serena Poto, Alejo Aguirre, Margot A. Llosa Tanco, David A. Pacheco Tanaka, Fausto Gallucci, M. Fernanda Neira d’Angelo
Publicado en: Euromembrane 2022, 2022
Editor: EMS

In2O3 Nanoparticles for Electrocatalytic CO2 Reduction to Formate: effects of catalyst phase and GDE configuration (poster)

Autores: T. Wissink, M.C. Figueiredo, E.J.M. Hensen
Publicado en: Electrochemistry 2022 conference, 2022
Editor: Electrochemistry 2022 conference
DOI: 10.5281/zenodo.7846297

Design of membrane based gas-liquid absorption units: a fast, efficient, high throughput batch to continuous methodology

Autores: E. Ferreri, C. Castel, E. Favre
Publicado en: ECCE13 (13th European Congress of Chemical Engineering, 2021
Editor: DECHEMA e.V.

CO2 direct hydrogenation to DME via membrane reactor (oral)

Autores: Serena Poto, Margot A. Llosa Tanco, D.A. Pacheco Tanaka, F. Gallucci, M.F. Neira d'Angelo
Publicado en: C2Fuel workshop: International Workshop on CO2 capture and utilization, 2021
Editor: C2Fuel - TU/e

Thesis and dissertations (2)

Electrochemical Reduction of CO2 to Formate on Indium and Bismuth Catalysts

Autores: Tim Wissink
Publicado en: 2023, ISBN 978-90-386-5880-3
Editor: Eindhoven University of Technology

One-step CO2 hydrogenation to dimethyl ether via packed bed membrane reactors

Autores: Serena Poto
Publicado en: 2023
Editor: Eindhoven University of Technology

Peer reviewed articles (9)

Evaluation of the relevant mass and heat transfer phenomena in a packed bed membrane reactor for the direct conversion of CO2 to dimethyl ether

Autores: Serena Poto, Huub van den Bogaard, Fausto Gallucci , M. Fernanda Neira d’Angelo
Publicado en: Fuel 350 (2023) 128783, 2023, ISSN 0016-2361
Editor: Elsevier BV
DOI: 10.1016/j.fuel.2023.128783

Techno economic assessment of the one-step CO2 conversion to dimethyl ether: conventional vs membrane-assisted process

Autores: Serena Poto, Thomas Vink, Pierre Oliver, Fausto Gallucci, M. Fernanda Neira d’Angelo
Publicado en: Journal of CO2 Utilization Volume 69, March 2023, 102419, 2023, ISSN 2212-9820
Editor: Elsevier BV
DOI: 10.1016/j.jcou.2023.102419

Evolution of bismuth oxide catalysts during electrochemical CO2 reduction

Autores: Wissink, T.; Man, A.J.W.; Chen, W.; Heinrichs, J.M.J.J.; van de Poll, R. C. J.; Figueiredo, M. C.; Hensen, E. J. M
Publicado en: Journal of CO2 Utilization, 2023, Página(s) Volume 77, November 2023, 102604, ISSN 2212-9820
Editor: Elsevier BV
DOI: 10.1016/j.jcou.2023.102604

Kinetic modelling of the methanol synthesis from CO2 and H2 over a CuO/CeO2/ZrO2 catalyst: The role of CO2 and CO hydrogenation

Autores: Serena Poto, Damian Vico van Berkel, Fausto Gallucci, M. Fernanda Neira d’Angelo
Publicado en: Chemical Engineering Journal, 2022, ISSN 1385-8947
Editor: Elsevier BV
DOI: 10.1016/j.cej.2022.134946

Experimental investigation of a packed bed membrane reactor for the direct conversion of CO2 to dimethyl ether

Autores: Serena Poto, Margot Anabell Llosa-Tanco, David Alfredo Pacheco-Tanaka, Fausto Gallucci, M. Fernanda Neira d’Angelo
Publicado en: Journal of CO2 Utilization, 2023, Página(s) Volume 72, June 2023, 102513, ISSN 2212-9820
Editor: Elsevier BV
DOI: 10.1016/j.jcou.2023.102513

Stability of In2O3 Nanoparticles in PTFEcontaining Gas Diffusion Electrodes for CO2 electroreduction to Formate

Autores: Tim Wissink; Rim C.J. van de Poll; Marta C. Figueiredo; Emiel J.M. Hensen
Publicado en: Journal of CO2 Utilization Volume 67, January 2023, 102331, Edición 12, 2023, ISSN 2212-9820
Editor: Elsevier BV
DOI: 10.1016/j.jcou.2022.102331

Direct conversion of CO2 to dimethyl ether in a fixed bed membrane reactor: Influence of membrane properties and process conditions

Autores: Poto Serena; Gallucci Fausto; Neira d'Angelo M.Fernanda
Publicado en: Fuel, Edición 1, 2021, Página(s) Volume 302, 15 October 2021, 121080, ISSN 0016-2361
Editor: Elsevier BV
DOI: 10.1016/j.fuel.2021.121080

Carbon molecular sieve membranes for water separation in CO2 hydrogenation reactions: effect of the carbonization temperature

Autores: Serena Poto, A. Aguirre, F. Huigh, Margot Anabell Llosa-Tanco, David Alfredo Pacheco-Tanaka, Fausto Gallucci, M. Fernanda Neira d’Angelo
Publicado en: Journal of Membrane Science Volume 677, 5 July 2023, 121613, 2023, ISSN 2155-9589
Editor: Elsevier
DOI: 10.1016/j.memsci.2023.121613

Vapor/gas separation through carbon molecular sieve membranes: Experimental and theoretical investigation

Autores: Serena Poto; Joost G.H. Endepoel; Margot Anabell Llosa-Tanco; D.A. Pacheco-Tanaka; Fausto Gallucci; M. Fernanda Neira d'Angelo
Publicado en: International Journal of Hydrogen Energy, Edición 3, 2021, ISSN 0360-3199
Editor: Pergamon Press Ltd.
DOI: 10.1016/j.ijhydene.2021.10.155