Carbon Captured Fuel and Energy Carriers for an Intensified Steel Off-Gases based Electricity Generation in a Smarter Industrial Ecosystem

Projektinformationen

C2FUEL

ID Finanzhilfevereinbarung: 838014

DOI

10.3030/838014

Das Projekt endete am 17 Oktober 2023

EK-Unterschriftsdatum 3 Mai 2019

Startdatum 1 Juni 2019

Enddatum 30 November 2023

Finanziert unter

• SOCIETAL CHALLENGES - Secure, clean and efficient energy

Gesamtkosten

€ 4 130 291,25

EU-Beitrag

€ 3 999 840,00

Koordiniert durch

ENGIE
France

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Links zu Ergebnissen und Veröffentlichungen von RP7-Projekten sowie Links zu einigen Typen spezifischer Ergebnisse wie Datensätzen und Software werden dynamisch von OpenAIRE abgerufen.

Leistungen

Documents, reports (23)

Report on 5000 hours durability of SOE stack under relevant operation conditions

Results of 5000 hours durability test of a SOE stack under optimal conditions. Conclusion on components that dominate degradation phenomena (task 2.3).

DK6 demonstration site ready for unit integration

Report of preliminary assessment regarding safety, security, regulatory aspects and site constraints. Delivery of Hazop and ATEX analysis of the integrated process. Achievement of site preparation and zoning scheme for demonstrator installation (subtask 5.1.1).

Process of FA production from electroreduction

Report on development, validation and test of CO2 electroreduction catalyst. Definition of optimal system and operating conditions for FA production (task 4.4 and task 4.6).

Influence of pressure on the single cells performance and durability

Results of electrochemical and microstructural analysis of a single cell under different operating pressures. Results of a 500 hours durability test at high pressure (subtask 2.2.4).

Multiscale modelling results

Results of the 0D and 3D SOE stack models developed in task 2.4 under steady and dynamic states. Delivery of a SOE stack model to integrate to the demonstration pilot model.

Technical workshop summary

Presentation of project first results WP1 to WP4 to a wide international audience task 74

Goal and scope of the LCA

Definition of goal and scope of the LCA. Creation of data collection templates to manage collection process (task 6.3).

Steel-off gases pre-treatment unit design

Definition of the pretreatment section required before CO2 conditioning step Integration of the gas treatment unit within demonstrator pilot subtask 121

Results for combustion engine test from DME

Report of tests performed on a DME internal combustion engine prototype. Measurement of differences on emissions and combustion compared to a Diesel engine (task 5.5).

Report on 5000 hours durability test of SOEC under relevant operation conditions

Results of electrochemical and microstructural analysis of a single cell operating under the previously identified optimal operation conditions. Conclusion on SOEC reliability for hydrogen and syngas production (subtask 2.2.6).

Demonstration workshop summary

Hosted workshop to give a public show of the demonstration of C2FUEL operation (task 7.4).

Study of social acceptance of the C2FUEL project (1)

Intermediate results of social acceptance of C2FUEL project. Partial communication analysis and first interviews report (task 7.1).

Catalyst synthetized for FA production

Results of tested catalysts for formic acid production. Definition of selected catalyst and results of high pressure operation and long term stability tests (task 4.2).

Characterization of the stacks performances during high temperature electrolysis

Results of electrochemical and microstructural analysis of stacks operating under the previously identified optimal operation conditions (task 2.3).

Preliminary Environmental assessment through LCA

Report of preliminary LCA to identify most significant environmental impacts and sensitive parameters (task 6.3).

Specifications for the demonstrator

Portfolio of all data gathered in task 11 and task 12 to define precisely the KPI of the demonstrator systems to be built within C2FUEL project

Electricity production and consumption in Dunkirk area

Analysis of Dunkirk area electricity sourcing. Assessment of renewable electricity surplus potential. Levelized cost forecast of both grid and renewable electricity (task 1.4).

Influence of operation conditions on single cells performance and durability

Identification of safe operation conditions range based on single cell tests Delivery of a suitable operation strategy to increase lifespan of single cells and SOE stacks subtask 221 Results of dynamic operation tests subtask 225

Influence of sweeping gases on the single cells performance and durability

Results of electrochemical impedance spectroscopy and post-test microstructure analysis of a single cell operating under different sweeping gases. Impact of sweeping gas on the oxygen electrode degradation (subtask 2.2.3).

Results for H2 regeneration from FA

Report of the 25 kW FA 2 Power system demonstration and regeneration of hydrogen to validate the route of seasonal storage (task 5.4).

Influence of CO2 impurities on the single cells performance and durability

Results of electrochemical impedance spectroscopy tests of a single cell operating under identified types and concentrations of impurities. Level of impact on cell performance and durability (subtask 2.2.2).

Results from CO2 conversion from FA demonstrator

Report of lab-scale demonstrator testing and validation according to predefined KPI (task 5.3).

Analysis of reactor types and spinning disc reactor lab scale design and testing

Assessment of possible reactor technologies to sue for FA production. Results of KPI analysis to identify suitable technology (task 4.3).

Websites, patent fillings, videos etc. (4)

Newsletters 3

External communication and dissemination of C2FUEL project results task 73

Project website

A public project website will be set up by M6 by ENGIE in order to widely communicate and disseminate project results (task 7.3).

Newsletters 1

Communication through project documentation, media and local newspapers to measure social acceptance of the project. Organisation of an interview survey with local stakeholders (task 7.1).

Newsletters 2

Organized workshops to establish a first mapping of key stakeholders. Communication through providing and sharing of scientific information as well as action coordination (task 7.2).

Demonstrators, pilots, prototypes (1)

Lab-scale demonstrator for FA production

Delivery of a 3D design of the reactor. Manufacturing of the FA lab-scale demonstrator.

Veröffentlichungen

Conference proceedings (9)

Presentation of C2FUEL project

Autoren: P. Olivier, C. Makhloufi
Veröffentlicht in: 2020
Herausgeber: INEA

In2O3 nanoparticles Gas Diffusion Electrode (GDE) (oral)

Autoren: Marta C. Figueiredo
Veröffentlicht in: Annual Meeting of the Danish Electrochemical society - 29/10/20, 2020
Herausgeber: Danish Electrochemical societ

Presentation of C2FUEL project

Autoren: P. Olivier, C. Makhloufi, M. Marrot
Veröffentlicht in: 4th INEA workshop on CCUS (sept 2019), 2019
Herausgeber: INEA

Poster: Effect of doping In2O3 with transition metals on the electrocatalytic reduction of CO2 to formate

Autoren: Tim Wissink, Marta Figueiredo, Emiel Hensen
Veröffentlicht in: EcoCat conference 23-25/11/2020, 2020
Herausgeber: NanoGe

Solid Oxide Electrolyser Demonstrator Development at Elcogen

Autoren: Lehtinen, Timo; Noponen, Matti
Veröffentlicht in: 2021 Meet. Abstr. MA2021-03 285, Ausgabe 2, 2021
Herausgeber: IOP Publishing
DOI: 10.1149/ma2021-031285mtgabs

EFFECT OF BOEHMITE NANOPARTICLES ON ALUMINA SUPPORTED CARBON MOLECULAR SIEVE MEMBRANES FOR VAPOR/GAS PERMEATION

Autoren: SERENA POTO,MARGOT A. LLOSA TANCO, D. ALFREDO PACHECO TANAKA,FAUSTO GALLUCCI, M. FERNANDA NEIRA D’ANGELO
Veröffentlicht in: World Online Conference on Sustainable Technologies (WOCST), 2021
Herausgeber: WOCST

Effect of membrane properties on the direct conversion of CO2 to dimethyl ether in a fixed bed membrane reactor

Autoren: Serena Poto, Fausto Gallucci, M. Fernanda Neira d’Angelo
Veröffentlicht in: 11th International Symposium on Catalysis in Multiphase Reactors (CAMURE-11), 2021
Herausgeber: AIDIC

Techno-economic assessment of the dimethyl ether synthesis via CO2 hydrogenation:conventional vs membrane assisted process (poster)

Autoren: Serena Poto, Thomas Vink, Fausto Gallucci, M. Fernanda Neira d’Angelo
Veröffentlicht in: Netherlands Process Symposium (NPS-17), 2022
Herausgeber: NPS

PERFORMANCE CHARACTERISTICS OF SOLID OXIDE ELECTROLYSIS TECHNOLOGY FROM ELCOGEN

Autoren: Timo Lehtinen, Matti Noponen, Sergii Pylypko and Enn Õunpuu
Veröffentlicht in: 45th International Conference and Expo on Advanced Ceramics and Composites (IACC), 2021
Herausgeber: ACerS Engineering Ceramics Division

Other (30)

EFFECT OF MEMBRANE PROPERTIES ON THE DIRECT CONVERSION OF CO2 TO DIMETHYL ETHER IN A FIXED BED MEMBRANE REACTOR (oral)

Autoren: SERENA POTO, FAUSTO GALLUCCI, M. FERNANDA NEIRA D’ANGELO
Veröffentlicht in: International Conference on Catalysis in Membrane Reactors (ICCMR-15), 2022
Herausgeber: The membrane society of Japan

Kinetic modelling of the methanol synthesis from CO2 and H2 over a CuO/CeO2/ZrO2 catalyst: the role of CO2 and CO hydrogenation

Autoren: Serena Poto, Damian Vico van Berkel, Fausto Gallucci, M. Fernanda Neira d’Angelo
Veröffentlicht in: North American Catalysis Society Meeting (NAM 27), 2022
Herausgeber: NAM

Catalytic performance study of supported Au catalysts for the direct hydrogenation of CO2 to formic acid

Autoren: Anouk de Leeuw den Bouter, Pierre Oliver, Camel Makhloufi, John van der Schaaf
Veröffentlicht in: Netherlands’ Catalysis and Chemistry Conference (NCCC), 2022
Herausgeber: NCCC

Design of membrane based gas-liquid absorption units: a fast, efficient, high throughput batch to continuous methodology (abstract)

Autoren: E. Ferreri, C. Castel, E. Favre
Veröffentlicht in: Euromembrane 2021, 2021
Herausgeber: The Meeting Planners

Design of membrane based gas-liquid absorption units: a fast, efficient, high throughput batch to continuous methodology (oral)

Autoren: Eglé FERRERI, Christophe CASTEL, Eric Favre
Veröffentlicht in: SFGP 2022, 2022
Herausgeber: Société Française de Génie des Procédés

High temperature electrolysis and co-electrolysis

Autoren: M. Noponen, Timo Lehtinen and X. Sun
Veröffentlicht in: C2Fuel workshop: International Workshop on CO2 capture and utilization, 2021
Herausgeber: C2Fuel - TU/e

C2FUEL Solid Oxide Electrolyser Demonstration System

Autoren: Timo Lehtinen, Matti Noponen
Veröffentlicht in: 15th European SOFC & SOE Forum, 2022
Herausgeber: EFCF

Kinetic modelling of the methanol synthesis from CO2 and H2 over a CuO/CeO2/ZrO2 catalyst: the role of CO2 and CO hydrogenation

Autoren: S. Poto, M.F. Neira d’Angelo, F. Gallucci
Veröffentlicht in: Netherlands’ Catalysis and Chemistry Conference (NCCC), 2022
Herausgeber: NCCC

An industrially-relevant demonstration of a CCU-based circular economy (poster)

Autoren: B. Wegman, F. Gallucci, P. Olivier, C. Makhloufi
Veröffentlicht in: C2Fuel workshop: International Workshop on CO2 capture and utilization, 2021
Herausgeber: C2Fuel - TU/e

Morphology study of bismuth nanoparticles as catalyst for electrochemical CO2 reduction to formate (poster)

Autoren: Alex J.W. Mana, Tim Wissinka, Marta C. Figueiredoa, Emiel J.M. Hensena
Veröffentlicht in: Netherlands’ Catalysis and Chemistry Conference (NCCC), 2022
Herausgeber: NCCC

Degradation of solid oxide electrolysis cells under different operation conditions

Autoren: Xiufu Sun, Peter Vang Hendriksen, Anne Hauch1, Anders Kring Clausen, Timo Lehtinen, Matti Noponen (abstract)
Veröffentlicht in: 17th International Symposium on Solid Oxide Fuel Cells (SOFC), 2021
Herausgeber: The Electrochemical Society

Stability of In2O3 Nanoparticles in Gas Diffusion Electrodes for CO2 Reduction to Formate

Autoren: Tim Wissink
Veröffentlicht in: Netherlands’ Catalysis and Chemistry Conference (NCCC), 2022
Herausgeber: NCCC

Effect of doping In2O3 with transition metals on the electrocatalytic reduction of CO2 to formate (poster)

Autoren: Tim Wissink, Marta C. Figueiredo, Emiel J.M. Hensen
Veröffentlicht in: C2Fuel workshop: International Workshop on CO2 capture and utilization, 2021
Herausgeber: C2Fuel - TU/e

Stability of In2O3 Nanoparticles in PTFE-containing Gas Diffusion Electrodes for CO2 Electroreduction to formate

Autoren: Tim Wissink, Rim C.J. Van de Poll, Dr. Marta C.C. Figueiredo,Prof. Emiel J.M. Hensen
Veröffentlicht in: MAT-SUS conference -Materials for Sustainable Development, 2022
Herausgeber: nanoGe

Effect of the membrane properties on the direct conversion of CO2 to dimethyl ether in a fixed bed membrane reactor (oral)

Autoren: S. Poto, M.F. Neira d’Angelo, F. Gallucci
Veröffentlicht in: North American Catalysis Society Meeting (NAM 27), 2022
Herausgeber: NAM

EFFECT OF BOEHMITE NANOSHEETS ON ALUMINA SUPPORTED CARBON MOLECULAR SIEVE MEMBRANES FOR VAPOR/GAS PERMEATION: EXPERIMENTAL AND THEORETICAL INVESTIGATION (oral)

Autoren: SERENA POTO, MARGOT A. LLOSA TANCO, D. ALFREDO PACHECO TANAK*, FAUSTO GALLUCCI, M. FERNANDA NEIRA D’ANGELO
Veröffentlicht in: International Conference on Catalysis in Membrane Reactors (ICCMR-15), 2022
Herausgeber: The membrane society of Japan

PERFORMANCE CHARACTERISTICS OF SOLID OXIDE ELECTROLYSIS TECHNOLOGY FROM ELCOGEN (bstract + presentation video)

Autoren: Timo Lehtinen, Matti Noponen, Sergii Pylypko and Enn Õunpuu
Veröffentlicht in: 45th International Conference and Expo on Advanced Ceramics and Composites (IACC), 2021
Herausgeber: ACerS Engineering Ceramics Division

Transition metal doped In2O3 for CO2 reduction to formate: How to retain the oxide phase for improved stability

Autoren: T. Wissink, M.C.C. Figuereido, E.J.M. Hensen
Veröffentlicht in: Netherlands’ Catalysis and Chemistry Conference (NCCC, 2022
Herausgeber: NCCC

Effect of inlet gas composition on the durability of solid oxide electrolysis cells

Autoren: Xiufu Sun, Anders Kring Clausen, Peter Vang Hendriksen, Anne Hauch, Timo Lehtinen, Matti Noponen
Veröffentlicht in: 2022
Herausgeber: EFCF
DOI: 10.5281/zenodo.7846265

Presentation of C2FUEL project

Autoren: Adeline Miquelot
Veröffentlicht in: COZMOS workshop on Conversion of CO2 to Fuels, 2023
Herausgeber: COZMOS european project

Presentation of C2FUEL project

Autoren: Bérenger WEGMAN
Veröffentlicht in: ENGIE AMEA, 2023
Herausgeber: ENGIE

On-Site Demonstration of Pre-Combustion CO2 Capture from Industrial Blast-Furnace Gas with Heterogeneous Hollow-Fiber Contactor Membrane Absorption Modules

Autoren: Bérenger WEGMAN, Eglé Ferreri
Veröffentlicht in: The 23rd IERE General Meeting and Singapore Forum, 2023
Herausgeber: IERE

On the influence of trialkylamine reduction strategies in the direct hydrogenation of CO2 to formic acid (oral)

Autoren: Anouk de Leeuw den Bouter, Lars Vogels, Esther Vogels, Pierre Olivier, Adeline Miquelot, Camel Makhloufi, John van der Schaaf
Veröffentlicht in: 2022 AIChE Annual Meeting, 2022
Herausgeber: American Institute of Chemical Engineers.

Membrane contactors for CO2 capture and purification unit at demonstrator scale on industrial operating conditions (oral)

Autoren: E. Ferreri
Veröffentlicht in: International Conference of Membrane 2023 (ICOM 2023), 2023
Herausgeber: Membrane Society of Australasia

EFFECT OF CARBONIZATION TEMPERATURE ON THE gas PERMEATION OF ALUMINA-CARBON MOLECULAR SIEVE MEMBRANES (Al-CMSM)

Autoren: MARGOT A. LLOSA TANCO, SERENA POTO, FAUSTO GALLUCCI,D. ALFREDO PACHECO TANAKA,
Veröffentlicht in: International Conference on Catalysis in Membrane Reactors (ICCMR-15), 2022
Herausgeber: The membrane society of Japan

Effect of membrane properties on the direct conversion of CO2 to dimethyl ether in a fixed bed membrane reactor

Autoren: Serena POTO, Fausto GALLUCCI, M. Fernanda NEIRA D’ANGELO
Veröffentlicht in: 26th International Symposium on Chemical Reaction Engineering (ISCRE-26), 2021
Herausgeber: Department of Chemical Engineering Indian Institute of Technology Delhi

Carbon molecular sieve membranes for water separation in CO2 hydrogenation reactions: effect of the carbonization temperature (oral)

Autoren: Serena Poto, Alejo Aguirre, Margot A. Llosa Tanco, David A. Pacheco Tanaka, Fausto Gallucci, M. Fernanda Neira d’Angelo
Veröffentlicht in: Euromembrane 2022, 2022
Herausgeber: EMS

In2O3 Nanoparticles for Electrocatalytic CO2 Reduction to Formate: effects of catalyst phase and GDE configuration (poster)

Autoren: T. Wissink, M.C. Figueiredo, E.J.M. Hensen
Veröffentlicht in: Electrochemistry 2022 conference, 2022
Herausgeber: Electrochemistry 2022 conference
DOI: 10.5281/zenodo.7846297

Design of membrane based gas-liquid absorption units: a fast, efficient, high throughput batch to continuous methodology

Autoren: E. Ferreri, C. Castel, E. Favre
Veröffentlicht in: ECCE13 (13th European Congress of Chemical Engineering, 2021
Herausgeber: DECHEMA e.V.

CO2 direct hydrogenation to DME via membrane reactor (oral)

Autoren: Serena Poto, Margot A. Llosa Tanco, D.A. Pacheco Tanaka, F. Gallucci, M.F. Neira d'Angelo
Veröffentlicht in: C2Fuel workshop: International Workshop on CO2 capture and utilization, 2021
Herausgeber: C2Fuel - TU/e

Thesis and dissertations (2)

Electrochemical Reduction of CO2 to Formate on Indium and Bismuth Catalysts

Autoren: Tim Wissink
Veröffentlicht in: 2023, ISBN 978-90-386-5880-3
Herausgeber: Eindhoven University of Technology

One-step CO2 hydrogenation to dimethyl ether via packed bed membrane reactors

Autoren: Serena Poto
Veröffentlicht in: 2023
Herausgeber: Eindhoven University of Technology

Peer reviewed articles (9)

Evaluation of the relevant mass and heat transfer phenomena in a packed bed membrane reactor for the direct conversion of CO2 to dimethyl ether

Autoren: Serena Poto, Huub van den Bogaard, Fausto Gallucci , M. Fernanda Neira d’Angelo
Veröffentlicht in: Fuel 350 (2023) 128783, 2023, ISSN 0016-2361
Herausgeber: Elsevier BV
DOI: 10.1016/j.fuel.2023.128783

Techno economic assessment of the one-step CO2 conversion to dimethyl ether: conventional vs membrane-assisted process

Autoren: Serena Poto, Thomas Vink, Pierre Oliver, Fausto Gallucci, M. Fernanda Neira d’Angelo
Veröffentlicht in: Journal of CO2 Utilization Volume 69, March 2023, 102419, 2023, ISSN 2212-9820
Herausgeber: Elsevier BV
DOI: 10.1016/j.jcou.2023.102419

Evolution of bismuth oxide catalysts during electrochemical CO2 reduction

Autoren: Wissink, T.; Man, A.J.W.; Chen, W.; Heinrichs, J.M.J.J.; van de Poll, R. C. J.; Figueiredo, M. C.; Hensen, E. J. M
Veröffentlicht in: Journal of CO2 Utilization, 2023, Seite(n) Volume 77, November 2023, 102604, ISSN 2212-9820
Herausgeber: Elsevier BV
DOI: 10.1016/j.jcou.2023.102604

Kinetic modelling of the methanol synthesis from CO2 and H2 over a CuO/CeO2/ZrO2 catalyst: The role of CO2 and CO hydrogenation

Autoren: Serena Poto, Damian Vico van Berkel, Fausto Gallucci, M. Fernanda Neira d’Angelo
Veröffentlicht in: Chemical Engineering Journal, 2022, ISSN 1385-8947
Herausgeber: Elsevier BV
DOI: 10.1016/j.cej.2022.134946

Experimental investigation of a packed bed membrane reactor for the direct conversion of CO2 to dimethyl ether

Autoren: Serena Poto, Margot Anabell Llosa-Tanco, David Alfredo Pacheco-Tanaka, Fausto Gallucci, M. Fernanda Neira d’Angelo
Veröffentlicht in: Journal of CO2 Utilization, 2023, Seite(n) Volume 72, June 2023, 102513, ISSN 2212-9820
Herausgeber: Elsevier BV
DOI: 10.1016/j.jcou.2023.102513

Stability of In2O3 Nanoparticles in PTFEcontaining Gas Diffusion Electrodes for CO2 electroreduction to Formate

Autoren: Tim Wissink; Rim C.J. van de Poll; Marta C. Figueiredo; Emiel J.M. Hensen
Veröffentlicht in: Journal of CO2 Utilization Volume 67, January 2023, 102331, Ausgabe 12, 2023, ISSN 2212-9820
Herausgeber: Elsevier BV
DOI: 10.1016/j.jcou.2022.102331

Direct conversion of CO2 to dimethyl ether in a fixed bed membrane reactor: Influence of membrane properties and process conditions

Autoren: Poto Serena; Gallucci Fausto; Neira d'Angelo M.Fernanda
Veröffentlicht in: Fuel, Ausgabe 1, 2021, Seite(n) Volume 302, 15 October 2021, 121080, ISSN 0016-2361
Herausgeber: Elsevier BV
DOI: 10.1016/j.fuel.2021.121080

Carbon molecular sieve membranes for water separation in CO2 hydrogenation reactions: effect of the carbonization temperature

Autoren: Serena Poto, A. Aguirre, F. Huigh, Margot Anabell Llosa-Tanco, David Alfredo Pacheco-Tanaka, Fausto Gallucci, M. Fernanda Neira d’Angelo
Veröffentlicht in: Journal of Membrane Science Volume 677, 5 July 2023, 121613, 2023, ISSN 2155-9589
Herausgeber: Elsevier
DOI: 10.1016/j.memsci.2023.121613

Vapor/gas separation through carbon molecular sieve membranes: Experimental and theoretical investigation

Autoren: Serena Poto; Joost G.H. Endepoel; Margot Anabell Llosa-Tanco; D.A. Pacheco-Tanaka; Fausto Gallucci; M. Fernanda Neira d'Angelo
Veröffentlicht in: International Journal of Hydrogen Energy, Ausgabe 3, 2021, ISSN 0360-3199
Herausgeber: Pergamon Press Ltd.
DOI: 10.1016/j.ijhydene.2021.10.155