Light to Store chemical Energy in reduced Graphene Oxide for electricity generation

Projektinformationen

LESGO

ID Finanzhilfevereinbarung: 952068

DOI

10.3030/952068

Projekt abgeschlossen

EK-Unterschriftsdatum 23 Juni 2020

Startdatum 1 November 2020

Enddatum 30 April 2024

Finanziert unter

• EXCELLENT SCIENCE - Future and Emerging Technologies (FET)

Gesamtkosten

€ 4 193 488,75

EU-Beitrag

€ 4 193 488,75

Koordiniert durch

FUNDACIO INSTITUT DE CIENCIES FOTONIQUES
Spain

Periodic Reporting for period 2 - LESGO (Light to Store chemical Energy in reduced Graphene Oxide for electricity generation)

Berichtszeitraum: 2022-05-01 bis 2024-04-30

Zusammenfassung vom Kontext und den Gesamtzielen des Projekts

LESGO’s main objective was to demonstrate that graphene-based materials such as graphene oxide (GO) can be used to securely store H using an energy efficient hydrogen loading based on the use of a flow cell electrolyzer. This overall goal was addressed by implementing three major research and technological development lines: Research on materials and cell configuration design for an effective H binding to the C atoms of a GO lattice; A comprehensive performance characterization of the electrolyser meant to carry out such H binding; And computational and experimental research on the H desorption mechanism to eventually achieve generation of electricity in an alkaline fuel cell.

Arbeit, die ab Beginn des Projekts bis zum Ende des durch den Bericht erfassten Berichtszeitraums geleistet wurde, und die wichtigsten bis dahin erzielten Ergebnisse

During LESGO’s implementation we have been able to master the production of GO with the specific needs required for its reduction and optimize the production of nanoparticles used in the GO reduction. For the latter the method developed was pulse laser ablation which can lead to a potentially low-cost and up-scalable production for such nano-particles. We have also obtained rare-Earth free anodes based on FeNi nanoparticles with negligible overpotential and long-term of operation. Regarding the GO hydrogenation system to be developed, we have implemented and tested its operation which included the fabrication of a prototype flow cell incorporating on time Raman monitoring, a solar cells and DC-DC converter that we used to test the hydrogenation system under real operation conditions and to effectively demonstrate GO reduction to rGO-H. Regarding the rGO-H dehydrogenation we implemented several computational models to theoretically demonstrate that hydrogen desorption energies can be as low as 0.9-1 eV; We have reached a preliminary experimental demonstration of the thee viability of rGO-H dehydrogenation using femtosecond laser pulses and the oxidation of rGO-H in a prototype alkaline fuel cell. Finally, we have conducted a preliminary exploration of the potential benefits of EV fuel cells operating on rGO-H fuel, potentially yielding improved energy densities and overall battery performance.

Fortschritte, die über den aktuellen Stand der Technik hinausgehen und voraussichtliche potenzielle Auswirkungen (einschließlich der bis dato erzielten sozioökonomischen Auswirkungen und weiter gefassten gesellschaftlichen Auswirkungen des Projekts)

Throughout LESGO's implementation, citizen engagement workshops, webinars, and community outreach activities across Europe facilitated exploring the societal acceptance around the technology and the stakeholder collaboration. Annual face-to-face meetings and regular online meetings ensured consistent progress and communication. The project disseminated results through 18 peer-reviewed publications, with additional works in progress, and shared outcomes at conferences and large European events.
LESGO finalized its IP Strategy and Exploitation Plan based on Key Exploitable Results, determining patenting is currently unviable but confirming strong market interest in alternative hydrogen storage methods without significant competing patents.

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