Filled carbon nanotubes in catalysis

Informazioni relative al progetto

ID dell’accordo di sovvenzione: FMBI950340

Progetto chiuso

Data di avvio 1 Febbraio 1996

Data di completamento 31 Gennaio 1997

Finanziato da

• Specific research and technological development programme in the field of the training and mobility of researchers, 1994-1998

Costo totale Nessun dato

Contributo UE Nessun dato

Coordinato da

THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD
Regno Unito

Obiettivo

The aim of this research project is to explore carbon nanotubes as catalyst support. The hollow core of opened carbon nanotubes will be filled with nanocrystals of platinum metals and, for the first time, with chiral Rh-complexes. Since the opening of the nanotubes are considerably smaller (10-30A) than the internal diameter of the nanotubes (50-1OOA) bulky catalysts (> 30A diameter) synthesized inside the tubules will be trapped and heterogenisized. This could be achived by 'the ship in the bottle' methodology whereby the components of the catalyst molecule are introduced separately into the 'bottle'. The introduction of the easily accessible (Rh(n-C2H4)2(u-Cl))2 followed by addition of bulky and chiral tertiary phosphine PR3 to form (Rh(PR3)3Cl))will be examined. The resulting complex is sufficiently large to be trapped inside the tubules. The catalytic activity of the resulting materials will be investigated.

Campo scientifico (EuroSciVoc)

CORDIS classifica i progetti con EuroSciVoc, una tassonomia multilingue dei campi scientifici, attraverso un processo semi-automatico basato su tecniche NLP. Cfr.: https://op.europa.eu/en/web/eu-vocabularies/euroscivoc.

• scienze naturali › scienze chimiche › chimica inorganica › metalli di transizione
• ingegneria e tecnologia › nanotecnologia › nanomateriali › nanocristalli
• scienze naturali › scienze chimiche › catalisi

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Programma(i)

• FP4-TMR - Specific research and technological development programme in the field of the training and mobility of researchers, 1994-1998

Argomento(i)

• 0302 - Post-doctoral research training grants
• TC06 - Surface Science, Colloids & Heterogenous Catalysis

Invito a presentare proposte

Dati non disponibili

Meccanismo di finanziamento

RGI -

Coordinatore

THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD

• Contributo UE: Nessun dato
• Indirizzo: South Parks Road ; OX1 3QR OXFORD ; Regno Unito
• Costo totale: Nessun dato

Partecipanti (1)

Not available

Germania

• Contributo UE: Nessun dato
• Costo totale: Nessun dato