Descrizione del progetto
Una migliore comprensione della dinamica degli eccitoni potrebbe condurre a materiali fotoattivi dalle prestazioni più elevate
La fotosintesi artificiale potrebbe apportare un contributo decisivo al mix di fonti di energie rinnovabili. Sebbene i progressi tecnologici abbiano avvicinato gli scienziati allo sviluppo di piattaforme efficienti per la raccolta della luce, i meccanismi su scala atomica sono tuttora poco noti. Nonostante i grandi sforzi di ricerca compiuti, vi sono tuttora importanti interrogativi da risolvere in quanto gli stati eccitati a vita estremamente breve, i cosiddetti eccitoni, sono difficili da misurare. Il progetto WEPOF, finanziato dall’UE, svilupperà metodi avanzati di microscopia per osservare questi stati eccitati generati dalla luce in materiali basati su strutture organiche covalenti. Il miglioramento della comprensione dei processi eccitonici guiderà la progettazione di materiali fotoattivi in grado di fornire una maggiore efficienza di conversione dell’energia.
Obiettivo
One of the most urgent challenges our society is facing nowadays is the development of an energy economy based on renewable resources. A fascinating approach is artificial photosynthesis, where solar energy is exploited to produce chemical fuels out of carbon dioxide, water, and sunlight.
While recent technological advances are bringing us closer to the goal of developing efficient light-harvesting platforms, a fundamental gap about the atomic-scale mechanisms remains to be filled. Understanding the atomistic details of the processes involved is of tremendous importance to drive a rational design of photoactive materials. Relevant questions include: how do electrical charges move upon light absorption? How does the atomic structure influence the ability to harvest light? Why do some materials work better than others? Answering to questions as these represents an extraordinary demanding task, since excitons, the most fundamental light-induced excitations, composed of bound electron-hole pairs, are only transient short-lived entities occurring in complex materials.
The WEPOF project aims at enabling the direct experimental observation of excitons in photoactive covalent organic frameworks, providing a fundamental understanding of photoexcited states in energy materials. While the structural complexity of organic frameworks will be tackled by individuating elementary functional units, allowing rationalizing their structure-function relations, the development of unique scanning probe microscopy methods will enable to watch excitons on their relevant length- and timescales.
The understanding of excitonic processes will allow steering the design of photoactive materials with improved energy conversion efficiency, providing a conceptual framework for next-generation material platforms for artificial photosynthesis.
Campo scientifico
Programma(i)
- HORIZON.1.1 - European Research Council (ERC) Main Programme
Argomento(i)
Meccanismo di finanziamento
HORIZON-AG - HORIZON Action Grant Budget-BasedIstituzione ospitante
6020 Innsbruck
Austria