Ultra-stable, highly efficient, low-cost perovskite photovoltaics with minimised environmental impact

Risultati finali

Report on selection of ISOS accelerated aging protocol to study intrinsic and extrinsic cell stability

This deliverable is related to T52 and T53 Selection of ISOS accelerated aging protocol to study intrinsic and extrinsic cell stability CEA M3 among the aging conditions described and recommended in ISOS recommendation reference paper the available and most relevant aging procedures will be selected It will consider the most important factors light temperature and humidity single stress or combination In addtion of the accelerated aging outdoor test procedures will be also detailed

Technology exploitation roadmap

This deliverable is part of T7.4 and aims to report a roadmap of all exploitation activities, market analysis and potential exploitation scenarios within DIAMOND project, under the coordination of PIX and support from all industrial partners (SNX, DYE and BeD), as the main end users and potential exploiters of this technology. It will be undertaken during the implementation stage (M24) and at the end of the project (M36). This roadmap will foresee the potential commercial use of DIAMOND solution, and also future use of knowledge gained within the project (i.e. of research results that cannot be commercially exploited). The definition of exploitation paths to the industrial sector will be made in cooperation with independent experts/advisors, who will contribute by reviewing and validation the envisaged plans.

Report on crystalline and stable α-FAPbI3 and Pb-Sn perovskite from scalable techniques.

This deliverable is related to T1.1 and aims at increasing the crystallinity and enhance the stability both of -FAPbI3 and Pb-Sn perovskite by addition of large organic cations and ionic liquid additives. The long organic cations, mostly containing an ammonium group have the double role of slowing down the crystallization and passivating surface and grain defects. Ionic liquids will be used to tune the crystallization and decrease the crystallization defects

Report on carbon-electrode based PSC with PCE ≥ 21% and roadmap to PCE ≥ 23% with long-term stability

This deliverable is related to T2.3 and will summarize the developments and results achieved to realize high performance (PCE 21%) perovskite solar cells based on carbon electrodes. Taking into account results from WP1 on novel materials, a roadmap towards long-term stable carbon-electrode based cells with PCE 23% will be presented.

Quality Assurance Report

A Quality Assurance report will be compiled within T8.4 and delivered before the mid-term review at M18. This will ensure standards have been met, including a set of indicators for project evaluation on quality, impact, engagement, gender and equality, and share the use of these in relevant tools such as the Gender Equality Action Plan. Regular quality.

Report on carbon electrode with optimized conductivity and charge selectivity.

This report will be a result of the development work on anode materials in Task 1.4. The carbon electrode should be highly conductive (<5 ohm/square) and chemically compatible with the underlying layers in a perovskite, i.e. not dissolve or react with the underlying layers. Moreover, the charge selectivity of the carbon layer should be tailored to promote - at the interface to perovskite - high extraction of holes whereas electrons are repelled without sustaining losses of the lateral conductivity of the carbon in its function as low-resistive back electrode.

Report on development, optimization and implementation of laser-sealing method to the fabrication of PSM

The report covers activities performed until M24 on T4.1, T4.2 and T4.3. Finite element model results will be reported for the mechanical stress and strain. Optimal conditions for the laser-sealing will be evaluated with standard tests, and results will be reported. Various deposition methods with minimal loss associated to the laser-sealing implementation will be explored by partners and results will be reported.

Report on Pb-Sn based PSC with PCE ≥ 22% and roadmap to PCE ≥ 24% with long-term stability

This deliverable is related to T2.2 and will be achieved by combining the efforts of WP1 towards the increase of the material quality (increasing the crystallinity and decreasing the number of defects), with the best devices stack geometry and electron and hole transport layers developed in WP2. Overall the deliverable will pin point which steps should be made towards >24% efficiency in Pb-Sn perovskite devices.

Report on the first operation of novel developed MPPT with 100 channels

Continuous maximum Power Point Tracking of 100 solar cells over 100 hours continuous illumination will be demonstrated within T5.2. For this, adapted sample holders will be constructed, the according measurement electronics set up, data logging installed and software programmed and successfully tested.

Report on life-cycle, critical materials, techno-economic, and social assessment

This report summarizes the findings of the work performed in T6.1 and T6.2. A comprehensive sustainability and cost assessment for DIAMOND modules will be presented, as well as an inventory of potential materials for perovskite cells and modules developed in the project, assessing their criticality.

Project Management Handbook

The Project Management Handbook PMH will be assembled within T84 Quality assurance and impact monitoring to ensure quality assurance processes for all project deliverables and published publications The PMH will also include a detailed Project Management Plan with a Gantt chart and a Work Breakdown Structure WBS

Report on optimized HTL and ETL for optimal junction

This deliverable is related to T1.2. Optimized selective contacts passivate the interface with the perovskites and extract charge carriers without significant voltage losses.

Dissemination, exploitation and communication plan

This deliverable reports the plan for the dissemination exploitation including communication PDEC activities within T71 and T72 of the DIAMOND project which will be delivered at M6 and updated at months 12 24 and 36 A project website will be developed and launched at the begin of the project M6 to further assist in the spreading of project news the wide perception of the goals and the consortium involved open access scientific publications will be made available The PDEC will consider the target audiences as central elements both academic and industrial during the three years of the project

Report on highest efficient PSC with PCE ≥ 26% and roadmap to PCE ≥ 27% with long-term stability

This deliverable is related to T2.1 and will be realized by developing methods that suppress -phase to -phase transformation by manipulating the crystallization process, thus ultimately yielding a homogenous pure phase perovskite films with preferred crystal orientation.

Data Management Plan

The Data Management Plan DMP will be prepared in T83 based on FAIR principles defined by the EC The DMP will serve for an optimal identification storage labeling and distribution among the partners and ensure proper publication The DMP will be updated annually after first version in M6

Pubblicazioni

Extending the π-Conjugated System in Spiro-Type Hole Transport Material Enhances the Efficiency and Stability of Perovskite Solar Modules

Autori: Xuepeng Liu, Bin Ding, Mingyuan Han, Zhenhai Yang, Jianlin Chen, Pengju Shi, Xiangying Xue, Rahim Ghadari, Xianfu Zhang, Rui Wang, Keith Brooks, Li Tao, Sachin Kinge, Songyuan Dai, Jiang Sheng, Paul J. Dyson, Mohammad Khaja Nazeeruddin, Yong Ding
Pubblicato in: Angewandte Chemie, 2023, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202304350

A universal ligand for lead coordination and tailored crystal growth in perovskite solar cells

Autori: B. Yang, J. Suo, D. Bogachuk, W. Kaiser, C. Baretzky, O. Er-Raji, G. Loukeris, A. A. Alothman, E. Mosconi, M. Kohlstädt, U. Würfel, F. De Agelis, A. Hagfeldt
Pubblicato in: Energy & Environmental Science, 2024, ISSN 1754-5692
Editore: Royal Society of Chemistry
DOI: 10.1039/D3EE02344C

Comparative life cycle assessment of different fabrication processes for perovskite solar mini-modules

Autori: F. Rossi, L. Rotondi, M. Stefanelli, A. Sinicropi, L. Vesce, M.L.Parisi
Pubblicato in: EPJ Photovoltaics, 2024, ISSN 2105-0716
Editore: EDP Sciences
DOI: 10.1051/epjpv/2024014

Quality Assessment of Perovskite Solar Cells: An Industrial Point of View

Autori: Nicolò Lago, Francesco Moretti, Noah Tormena, Alessandro Caria, Matteo Buffolo, Carlo De Santi, Nicola Trivellin, Andrea Cester, Gaudenzio Meneghesso, Enrico Zanoni, Matteo Meneghini, Fabio Matteocci, Jessica Barichello, Luigi Vesce, Aldo Di Carlo, Federico Quartiani
Pubblicato in: Photonics, Numero 11, 2024, ISSN 2304-6732
Editore: MDPI AG
DOI: 10.3390/photonics11090880

A carbazole-based self-assembled monolayer as the hole transport layer for efficient and stable Cs0.25FA0.75Sn0.5Pb0.5I3 solar cells

Autori: M. Pitaro, J. Sebastian Alonso, L. Di Mario, D. G. Romero, K. Tran, T. Zaharia, M. B. Johansson, E. M. J. Johansson, M. A. Loi
Pubblicato in: Journal Material Chemistry A, 2023, ISSN 2050-7488
Editore: Royal Society of Chemistry
DOI: 10.1039/D3TA01276J

Upscaling of Carbon-Based Perovskite Solar Module

Autori: M. Stefanelli, L. Vesce, A. Di Carlo
Pubblicato in: Nanomaterials, 2023, ISSN 2079-4991
Editore: MDPI
DOI: 10.3390/nano13020313

Low-temperature strain-free encapsulation for perovskite solar cells and modules passing multifaceted accelerated ageing tests

Autori: P. Mariani, M. Molina-García, J. Barichello, M. Zappia, EricaMagliano, L. Castriotta, L. Gabatel, S. Thorat, A. Del Rio Castillo, F. Drago, E. Leonardi, S. Pescetelli, L. Vesce, F. DiGiacomo, F. Matteocci, A. Agresti, N. DeGiorgi, S. Bellani, A. Di Carlo,
Pubblicato in: Nature communications, 2024, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-024-48877-y

The resource demands of multi-terawatt-scale perovskite tandem photovoltaics

Autori: Lukas Wagner, Jiajia Suo, Bowen Yang, Dmitry Bogachuk, Estelle Gervais, Robert Pietzcker, Andrea Gassmann, Jan Christoph Goldschmidt
Pubblicato in: Joule, 2024, ISSN 2542-4351
Editore: Cell Press
DOI: 10.1016/j.joule.2024.01.024

Perovskite solar cell technology scaling‐up: Eco‐efficient and industrially compatible sub‐module manufacturing by fully ambient air slot‐die/blade meniscus coating

Autori: Luigi Vesce, Maurizio Stefanelli, Federico Rossi, Luigi Angelo Castriotta, Riccardo Basosi, Maria Laura Parisi, Adalgisa Sinicropi, Aldo Di Carlo
Pubblicato in: Progress in Photovoltaics: Research and Applications, Numero 32, 2024, ISSN 1062-7995
Editore: Wiley
DOI: 10.1002/pip.3741

In situ SnSe deposition as passivation for scalable and stable quasi-2D lead–tin perovskite solar cells

Autori: Lijun Chen, Eelco Kinsa Tekelenburg, Kushagra Gahlot Matteo Pitaro, Jun Xi, Alessia Lasorsa, Giovanna Feraco, Loredana Protesescu, Patrick C. A. van der Wel, Giuseppe Portale, Petra Rudolf,Christoph J. Brabec and Maria Antonietta Loi
Pubblicato in: Energy & Environmental Science, 2023, ISSN 1754-5692
Editore: Royal Society of Chemistry
DOI: 10.1039/D3EE02507A

Roadmap on commercialization of metal halide perovskite photovoltaics

Autori: S.P. Feng, Y. Cheng, H.L. Yip, Y. Zhong, P.W.K. Fong, G. Li, A. Ng, C. Chen, L.A. Castriotta, F. Matteocci, L. Vesce, D. Saranin, A. Di Carlo, et al.
Pubblicato in: JPhys Materials, 2023, ISSN 2515-7639
Editore: IOP Publishing
DOI: 10.1088/2515-7639/acc893

Nanoarchitectonics in fully printed perovskite solar cells with carbon-based electrodes

Autori: Dmitry Bogachuk; Jessica Girard; Siddharth Tilala; David Martineau; Stéphanie Narbey; Anand Verma; Andreas Hinsch; Markus Kohlstädt; Lukas Wagner
Pubblicato in: Nanoscale, 2023, ISSN 2040-3364
Editore: Royal Society of Chemistry
DOI: 10.48550/arxiv.2211.09424

Rethinking Electrochemical Deposition of Nickel Oxide for Photovoltaic Applications

Autori: Dmitry Bogachuk; Clemens Baretzky; Jonas Eckert; Bowen Yang; Jiajia Suo; Uma Kousalya Dangudubiyyam; Georgios Loukeris; Hadi Mohammadzadeh; Sven Kluska; Markus Kohlstädt; Uli Würfel
Pubblicato in: Solar RRL, 2023, ISSN 2367-198X
Editore: Wiley-VCH Verlag
DOI: 10.24406/publica-2749

The Dual Use of SAM Molecules for Eﬃcient and StablePerovskite Solar Cells

Autori: J. Suo, B. Yang, D. Bogachuk, G. Boschloo, A. Hagfeldt
Pubblicato in: Advanced Energy Materials, 2024, ISSN 1614-6832
Editore: Wiley-VCH Verlag
DOI: 10.1002/aenm.202400205

Novel Materials and Processes for Photovoltaic Technology

Autori: Luigi Vesce
Pubblicato in: Energies, Numero 16, 2025, ISSN 1996-1073
Editore: MDPI AG
DOI: 10.3390/en16010425

Semitransparent Perovskite Solar Submodule for 4T Tandem Devices: Industrial Engineering Route Toward Stable Devices

Autori: L. A. Castriotta, M. Stefanelli, L. Vesce, E. Magliano, E. Leonardi, F. Di Giacomo, H. Nikbakht, L. Serenelli, L. Martini, F. Menchini, F. Matteocci, M. Tucci, A. Di Carlo
Pubblicato in: IEEE Journal of Photovoltaics, 2024, ISSN 2156-3403
Editore: IEEE
DOI: 10.1109/JPHOTOV.2024.3377190

Organic and perovskite solar cells based on scalable slot-die coating technique: Progress and challenges

Autori: Reza Keshavarzi, Farzaneh Hajisharifi, Zahra Saki, Mirkazem Omrani, Reza Sheibani, Niloufar Afzali, Mojtaba Abdi-Jalebi, Luigi Vesce, Aldo Di Carlo
Pubblicato in: Nano Today, Numero 61, 2024, ISSN 1748-0132
Editore: Elsevier BV
DOI: 10.1016/j.nantod.2024.102600

Multifunctional sulfonium-based treatment for perovskite solar cells with less than 1% efficiency loss over 4,500-h operational stability tests

Autori: J. Suo, B. Yang, E. Mosconi, D. Bogachuk, T. A. S. Doherty, K. Frohna, D. J. Kubicki, F. Fu, Y. Kim, O. Er-Raji, T. Zhang, L. Baldinelli, L. Wagner, A. N. Tiwari, F. Gao, A. Hinsch, S. D. Stranks, F. De Angelis, A. Hagfeldt
Pubblicato in: Nature Energy, 2024, ISSN 2058-7546
Editore: Nature
DOI: 10.1038/s41560-023-01421-6

Optoelectronic perovskite film characterization via machine vision

Autori: M. Harth, L. Vesce, I Kouroudis, M. Stefanelli, A. Di Carlo, A. Gagliardi
Pubblicato in: Solar Energy, 2023, ISSN 1471-1257
Editore: Elsevier
DOI: 10.1016/j.solener.2023.111840

Carbon-Based Perovskite Solar Cell

Autori: L. Vesce, M. Stefanelli, A. Di Carlo
Pubblicato in: Materials Proceedings, 2023, ISSN 2673-3960
Editore: MDPI
DOI: 10.3390/IOCN2023-14539

Process Engineering for Low-Temperature Carbon-Based Perovskite Solar Modules

Autori: L. Vesce, M. Stefanelli, H. Nikbakht, A. Di Carlo
Pubblicato in: Engineering Proceedings, 2023, ISSN 2673-4591
Editore: MDPI
DOI: 10.3390/ECP2023-14721

Risultati finali

Pubblicazioni

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