Advancing CO2 Capture Materials by Atomic Scale Design: the Quest for Understanding

Informazioni relative al progetto

AMADEUS

ID dell’accordo di sovvenzione: 819573

DOI

10.3030/819573

Progetto chiuso

Data della firma CE 19 Dicembre 2018

Data di avvio 1 Giugno 2019

Data di completamento 31 Maggio 2024

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale

€ 1 994 900,00

Contributo UE

€ 1 994 900,00

Coordinato da

EIDGENOESSISCHE TECHNISCHE HOCHSCHULE ZUERICH
Switzerland

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Pubblicazioni

Peer reviewed articles (31)

Model structures of molten salt-promoted MgO to probe the mechanism of MgCO3 formation during CO2 capture at a solid-liquid interface

Autori: Hansen Bork, Alexander; Ackerl, Norbert; Reuteler, Joakim; Jog, Sachin; Gut, David; Zboray, Robert; Müller, Christoph R.
Pubblicato in: Journal of Materials Chemistry A, 10 (32), Numero 1, 2022, Pagina/e 16803-16812, ISSN 2050-7488
Editore: Royal Society of Chemistry
DOI: 10.1039/d2ta02897b

CaO-Based CO 2 Sorbents with a Hierarchical Porous Structure Made via Microfluidic Droplet Templating

Autori: Alexey Kurlov, Andac Armutlulu, Felix Donat, André R. Studart, Christoph R. Müller
Pubblicato in: Industrial & Engineering Chemistry Research, Numero 59/15, 2020, Pagina/e 7182-7188, ISSN 0888-5885
Editore: American Chemical Society
DOI: 10.1021/acs.iecr.9b05996

Yolk-shell-type CaO-based sorbents for CO2 capture: assessing the role of nanostructuring for the stabilization of the cyclic CO2 uptake

Autori: Maximilian Krödel, Alexander Oing, Jan Negele, Annelies Landuyt, Agnieszka Kierzkowska, Alexander H. Bork, Felix Donat, Christoph R. Müller
Pubblicato in: Nanoscale, Numero 14 (45), 2022, Pagina/e 16816 - 16828, ISSN 2040-3364
Editore: Royal Society of Chemistry
DOI: 10.1039/d2nr04492g

Assessment of the Effect of Process Conditions and Material Characteristics of Alkali Metal Salt Promoted MgO-Based Sorbents on Their CO2 Capture Performance

Autori: Jian Chen, Lunbo Duan, Felix Donat, Christoph R. Müller
Pubblicato in: ACS Sustainable Chemistry & Engineering, Numero 9(19), 2021, Pagina/e 6659-6672, ISSN 2168-0485
Editore: American Chemical Society
DOI: 10.1021/acssuschemeng.1c00262

CO2 Capture at Medium to High Temperature Using Solid Oxide-Based Sorbents: Fundamental Aspects, Mechanistic Insights, and Recent Advances

Autori: Matthew T. Dunstan, Felix Donat, Alexander H. Bork, Clare P. Grey, Christoph R. Müller
Pubblicato in: Chemical Reviews, Numero 121(20), 2021, Pagina/e 12681-12745, ISSN 0009-2665
Editore: American Chemical Society
DOI: 10.1021/acs.chemrev.1c00100

Engineering the Cu/Mo2CTx (MXene) interface to drive CO2 hydrogenation to methanol

Autori: Hui Zhou, Zixuan Chen, Anna Vidal López, Estefanía Díaz López, Erwin Lam, Athanasia Tsoukalou, Elena Willinger, Denis A. Kuznetsov, Deni Mance, Agnieszka Kierzkowska, Felix Donat, Paula M. Abdala, Aleix Comas-Vives, Christophe Copéret, Alexey Fedorov, Christoph R. Müller
Pubblicato in: Nature Catalysis, Numero 4(10), 2021, Pagina/e 860 - 871, ISSN 2520-1158
Editore: Springer Nature
DOI: 10.1038/s41929-021-00684-0

Peering into buried interfaces with X-rays and electrons to unveil MgCO3 formation during CO2 capture in molten salt-promoted MgO

Autori: Alexander H. Bork, Margarita Rekhtina, Elena Willinger, Pedro Castro-Fernández, Jakub Drnec, Paula M. Abdala, Christoph R. Müller
Pubblicato in: Proceedings of the National Academy of Sciences (PNAS), Numero 118(26), 2021, Pagina/e e2103971118, ISSN 0027-8424
Editore: National Academy of Sciences
DOI: 10.1073/pnas.2103971118

Na 2 CO 3 -modified CaO-based CO 2 sorbents: the effects of structure and morphology on CO 2 uptake

Autori: Alexey Kurlov, Agnieszka M. Kierzkowska, Thomas Huthwelker, Paula M. Abdala, Christoph R. Müller
Pubblicato in: Physical Chemistry Chemical Physics, Numero 22/42, 2020, Pagina/e 24697-24703, ISSN 1463-9076
Editore: Royal Society of Chemistry
DOI: 10.1039/d0cp04410e

Chemical Looping Partial Oxidation of Methane: Reducing Carbon Deposition through Alloying

Autori: Felix Donat, Agnieszka Kierzkowska, and Christoph R. Müller
Pubblicato in: Energy & Fuels, Numero 36 (17), 2022, Pagina/e 9780-9784, ISSN 0887-0624
Editore: American Chemical Society
DOI: 10.1021/acs.energyfuels.2c01345

Investigation of K2CO3-modified CaO sorbents for CO2 capture using in-situ X-ray diffraction

Autori: Yongqing Xu,Felix Donat,Cong Luo, Jian Chen, Agnieszka Kierzkowska, Muhammad Awais Naeem, Liqi Zhang, Christoph R. Müller
Pubblicato in: Chemical Engineering Journal, Numero 453, 2022, Pagina/e 139913, ISSN 1385-8947
Editore: Elsevier BV
DOI: 10.1016/j.cej.2022.139913

Reversible transformation of sub-nanometer Ga-based clusters to isolated ^[4]Ga_(4Si) sites creates active centers for propane dehydrogenation

Autori: Zixuan Chen; Alexander I. Serykh; Agnieszka Kierzkowska; David Gajan; Scott R. Docherty; Alexander V. Yakimov; Paula M. Abdala; Christophe Copéret; Pierre Florian; Alexey Fedorov; Christoph R. Müller
Pubblicato in: Catalysis Science & Technology, 14 (2), Numero 3, 2024, Pagina/e 379 - 390, ISSN 2044-4761
Editore: Royal Society of Chemistry
DOI: 10.1039/d3cy01446k

Structural insight into an atomic layer deposition (ALD) grown Al2O3 layer on Ni/SiO2: impact on catalytic activity and stability in dry reforming of methane

Autori: Sung Min Kim, Andac Armutlulu, Wei-Chih Liao, Davood Hosseini, Dragos Stoian, Zixuan Chen, Paula M. Abdala, Christophe Copéret, Christoph Müller
Pubblicato in: Catalysis Science & Technology, Numero 11, 2021, Pagina/e 7563-7577, ISSN 2044-4753
Editore: Royal Society of Chemistry
DOI: 10.1039/d1cy01149a

Mechanistic Understanding of CaO‐Based Sorbents for High‐Temperature CO 2 Capture: Advanced Characterization and Prospects

Autori: Maximilian Krödel, Annelies Landuyt, Paula M. Abdala, Christoph R. Müller
Pubblicato in: ChemSusChem, Numero 13(23), 2020, Pagina/e 6259 - 6272, ISSN 1864-5631
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202002078

Nature of GaOx Shells Grown on Silica by Atomic Layer Deposition

Autori: Zixuan Chen, Nora K. Zimmerli, Muhammad Zubair, Alexander V. Yakimov, Snædís Björgvinsdóttir, Nicholas Alaniva, Elena Willinger, Alexander B. Barnes, Nicholas M. Bedford, Christophe Copéret, Pierre Florian, Paula M. Abdala, Alexey Fedorov, and Christoph R. Müller
Pubblicato in: Chemistry of Materials, Numero 35(18), 2023, Pagina/e 7475 - 7490, ISSN 0897-4756
Editore: American Chemical Society
DOI: 10.1021/acs.chemmater.3c00923

Surface Intermediates in In-Based ZrO2-Supported Catalysts for Hydrogenation of CO2 to Methanol

Autori: Athanasia Tsoukalou; Nikolai S. Bushkov; Scott R. Docherty; Deni Mance; Alexander I. Serykh; Paula M. Abdala; Christophe Copéret; Alexey Fedorov; Christoph R. Müller
Pubblicato in: The Journal of Physical Chemistry C, Numero 136(4), 2022, Pagina/e 1793 - 1799, ISSN 1932-7447
Editore: American Chemical Society
DOI: 10.1021/acs.jpcc.1c08814

Of Glasses and Crystals: Mitigating the Deactivation of CaO-Based CO2 Sorbents through Calcium Aluminosilicates

Autori: Maximilian Krödel, César Leroy, Sung Min Kim, Muhammad Awais Naeem, Agnieszka Kierzkowska, Yi-Hsuan Wu, Andac Armutlulu, Alexey Fedorov, Pierre Florian, and Christoph R. Müller
Pubblicato in: JACS Au, Numero 3 (11), 2023, Pagina/e 3111–3126, ISSN 2691-3704
Editore: Amercian Chemical Society
DOI: 10.1021/jacsau.3c00475

Photo-Switchable Nanoripples in Ti3C2Tx MXene

Autori: Mikhail Volkov, Elena Willinger, Denis A. Kuznetsov, Christoph R. Müller, Alexey Fedorov, Peter Baum
Pubblicato in: ACS Nano, Numero 15(9), 2021, Pagina/e 14071-14079, ISSN 1936-0851
Editore: American Chemical Society
DOI: 10.1021/acsnano.1c03635

Altering Oxygen Binding by Redox-Inactive Metal Substitution to Control Catalytic Activity: Oxygen Reduction on Manganese Oxide Nanoparticles as a Model System

Autori: Yi-Hsuan Wu, Harshit Mehta, Dr. Elena Willinger, Dr. Jodie A. Yuwono, Dr. Priyank V. Kumar, Dr. Paula M. Abdala, Dr. Anna Wach, Dr. Agnieszka Kierzkowska, Dr. Felix Donat, Dr. Denis A. Kuznetsov, Prof. Dr. Christoph R. Müller
Pubblicato in: Angewandte Chemie. International Edition, 62 (8), Numero 2, 2023, Pagina/e e202217186, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202217186

The structural evolution of Mo2C and Mo2C/SiO2 under dry reforming of methane conditions: morphology and support effects

Autori: Alexey Kurlov; Dragos Stoian; Ali Baghizadeh; Evgenia Kountoupi; Evgeniya B. Deeva; Marc Willinger; Paula M. Abdala; Alexey Fedorov; Christoph R. Müller
Pubblicato in: Catalysis Science & Technology, Numero 12 (18), 2022, Pagina/e 5620 - 5628, ISSN 2044-4753
Editore: Royal Society of Chemistry
DOI: 10.1039/d2cy00729k

Atomic-scale changes of silica-supported catalysts with nanocrystalline or amorphous gallia phases: implications of hydrogen pretreatment on their selectivity for propane dehydrogenation

Autori: Pedro Castro-Fernández, Alexander I. Serykh, Alexander V. Yakimov, Igor P. Prosvirin, Andrey V. Bukhtiyarov, Paula M. Abdala, Christophe Copéret, Alexey Fedorov and Christoph R. Müller.
Pubblicato in: Catalysis Science & Technology, Numero 12 (12), 2022, Pagina/e 3957 - 3968, ISSN 2044-4753
Editore: Royal Society of Chemistry
DOI: 10.1039/d2cy00074a

Prospects of MgO-based sorbents for CO2 capture applications at high temperatures

Autori: Felix Donat; Christoph Müller
Pubblicato in: Current Opinion in Green and Sustainable Chemistry, Numero 36, 2022, Pagina/e 100645, ISSN 2452-2236
Editore: Elsevier
DOI: 10.1016/j.cogsc.2022.100645

Atomic-Scale Structure and Its Impact on Chemical Properties of Aluminum Oxide Layers Prepared by Atomic Layer Deposition on Silica

Autori: Monu Kaushik, César Leroy, Zixuan Chen, David Gajan, Elena Willinger, Christoph R. Müller, Franck Fayon, Dominique Massiot, Alexey Fedorov, Christophe Copéret, Anne Lesage, Pierre Florian
Pubblicato in: Chemistry of Materials, Numero 33(9), 2021, Pagina/e 3335-3348, ISSN 0897-4756
Editore: American Chemical Society
DOI: 10.1021/acs.chemmater.1c00516

Deciphering the structural dynamics in molten salt–promoted MgO-based CO2 sorbents and their role in the CO2 uptake

Autori: Margarita Rekhtina, Maximilian Krödel, Yi-Hsuan Wu, Agnieszka Kierzkowska, Felix Donat, Paula M. Abdala, and Christoph R. Müller
Pubblicato in: Science Advances, 9 (26), Numero 14, 2023, Pagina/e eadg5690, ISSN 1864-5631
Editore: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1126/sciadv.adg5690

Probing the Local Structure of Na in NaNO₃-Promoted, MgO-Based CO₂ Sorbents via X-ray Absorption Spectroscopy

Autori: Rekhtina, Margarita; Bugaev, Aram; Dunstan, Matthew T.; Dal Pozzo, Alessandro; Nadjafi, Manouchehr; Borca, Camelia; Huthwelker, Thomas; Abdala, Paula Macarena; Müller, Christoph R.
Pubblicato in: Chemistry of Materials, Numero 35 (23), 2023, Pagina/e 10060-10069, ISSN 0897-4756
Editore: American Chemical Society
DOI: 10.3929/ethz-b-000645595

Uncovering selective and active Ga surface sites in gallia–alumina mixed-oxide propane dehydrogenation catalysts by dynamic nuclear polarization surface enhanced NMR spectroscopy

Autori: Pedro Castro-Fernández, Monu Kaushik, Zhuoran Wang, Deni Mance, Evgenia Kountoupi, Elena Willinger, Paula M. Abdala, Christophe Copéret, Anne Lesage, Alexey Fedorov, Christoph R. Müller
Pubblicato in: Chemical Science, Numero 12(46), 2021, Pagina/e 15273 - 15283, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d1sc05381g

Structure of Na Species in Promoted CaO-Based Sorbents and Their Effect on the Rate and Extent of the CO2 Uptake

Autori: Maximilian Krödel, Lorenz Abduly, Manouchehr Nadjafi, Agnieszka Kierzkowska, Alexander Yakimov, Alexander H. Bork, Felix Donat, Christophe Copéret, Paula M. Abdala, Christoph R. Müller
Pubblicato in: Advanced Functional Materials, 2023, Pagina/e 2302916, ISSN 1616-301X
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/adfm.202302916

Uncovering the CO2 Capture Mechanis of NaNO3-Promoted MgO by O-18 Isotope Labeling

Autori: Landuyt, Annelies; Kumar, Priyank V.; Yuwono, Jodie A.; Bork, Alexander H.; Donat, Felix; id_orcid0000-0002-3940-9183; Abdala, Paula M.; Müller, Christoph R.
Pubblicato in: JACS Au, 2 (12), Numero 1, 2022, Pagina/e 2731-2741, ISSN 2691-3704
Editore: American Chemical Society
DOI: 10.1021/jacsau.2c00461

Structure and Role of a Ga-Promoter in Ni-Based Catalysts for the Selective Hydrogenation of CO2 to Methanol

Autori: Nora K. Zimmerli; Lukas Rochlitz; Stefano Checchia; Christoph R. Müller; Christophe Copéret; Paula M. Abdala
Pubblicato in: JACS Au, Vol 4, Iss 1, Pp 237-252 (2024), Numero 4, 2024, ISSN 2691-3704
Editore: American Chemical Society
DOI: 10.1021/jacsau.3c00677

Effect of molten sodium nitrate on the decomposition pathways of hydrated magnesium hydroxycarbonate to magnesium oxide probed by in situ total scattering

Autori: Margarita Rekhtina; Alessandro Dal Pozzo; Dragos Stoian; Andaç Armutlulu; Felix Donat; Maria Valeria Blanco; Zhu-Jun Wang; Marc Willinger; Alexey Fedorov; Paula M. Abdala; Christoph R. Müller
Pubblicato in: Nanoscale, Numero 12(31), 2020, Pagina/e 16462 - 16473, ISSN 2040-3364
Editore: Royal Society of Chemistry
DOI: 10.1039/d0nr01760d

Hydrogen dissociation sites on indium-based ZrO2-supported catalysts for hydrogenation of CO2 to methanol

Autori: Athanasia Tsoukalou, Alexander I. Serykh, Elena Willinger, Agnieszka Kierzkowska, Paula M. Abdala, Alexey Fedorov, Christoph R. Müller
Pubblicato in: Catalysis Today, Numero vol 387, 2021, Pagina/e 38-46, ISSN 0920-5861
Editore: Elsevier BV
DOI: 10.1016/j.cattod.2021.04.010

Bulk and surface transformations of Ga2O3 nanoparticle catalysts for propane dehydrogenation induced by a H2 treatment

Autori: Pedro Castro-Fernández, Deni Mance, Chong Liu, Paula Macarena Abdala, Elena Willinger, Aurelio A. Rossinelli, Alexander I. Serykh, Evgeny A. Pidko, Christophe Copéret, Alexey Fedorov, Christoph R. Müller
Pubblicato in: Journal of Catalysis, Numero 408, 2022, Pagina/e 155-164, ISSN 0021-9517
Editore: Academic Press
DOI: 10.1016/j.jcat.2022.02.025