Descrizione del progetto
Strati esterni funzionalizzati conferiscono ai nanocristalli di rame un potere catalitico smisurato
Tra le modalità più efficaci di riduzione della CO2 atmosferica vi sono la sua cattura e la conversione catalitica in sostanze chimiche utili. La riduzione elettrochimica della CO2 può aiutarci a immagazzinare l’elettricità rinnovabile in eccesso nei legami dei combustibili liquidi a base di carbonio e delle sostanze chimiche di rilevanza industriale. È una proposta vantaggiosa per tutti, che permette di ridurre la CO2 generando sostanze chimiche utili e facendo affidamento su fonti di energia rinnovabile. Tuttavia, deve affrontare sfide legate alla selettività, attività e stabilità basse degli elettrocatalizzatori in soluzioni acquose. Il progetto SURFCAT, finanziato dall’UE, sta sviluppando nuovi approcci per modificare i nanocristalli di rame, catalizzatore d’elezione, per superare questi ostacoli e stimolare la commercializzazione di questo importante processo per chiudere il ciclo del carbonio, proteggere l’ambiente e fornire combustibili e sostanze chimiche.
Obiettivo
With an expanding population and finite fossil fuel resources, society faces several major challenges regarding energy and the environment. SURFCAT seeks to address these issues by making advances in the electrochemical carbon-dioxide reduction-reaction (CO2RR), which converts carbon dioxide into hydrocarbon fuels using renewable electrical energy. Whilst copper is the only metal able to produce hydrocarbons in the CO2RR, modifications to pure, bulk copper are required in order to bypass its intrinsic limitations. Copper nanocrystals (CuNCs) offer enhanced activity and selectivity for single products in the CO2RR, yet there is a need to improve these materials further. SURFCAT strives to take advantage of surface modification in order to deliver these improvements. SURFCAT will go beyond the state-of-the-art by modifying the surfaces of CuNCs with functional organic ligands. The objectives of the research will be to: 1) synthesise new organic molecules, judiciously designed to influence favourable interactions between the CuNCs and carbon dioxide; 2) synthesise hybrid CuNCs, consisting of a metallic, nanocrystalline core and a functional ligand shell; 3) study and optimise the electrocatalytic performance of these novel materials; and 4) use spectroscopy and computational modelling to understand their mode of action and offer insight into the role of functional ligands on catalyst surfaces. These objectives will be achieved by combining the applicant’s expertise in steering catalysis through ligand design with the host laboratory’s expertise in nanocrystal synthesis and electrocatalysis. SURFCAT is perfectly aligned with the MSCA Work Programme, combining unique skills and knowledge from both the applicant and the host laboratory. Through training during his time at EPFL, the applicant will develop professional, language and teaching skills on top of his research efforts, in order to become a mobile and World-leading researcher.
Campo scientifico
- natural scienceschemical scienceselectrochemistry
- natural scienceschemical sciencescatalysiselectrocatalysis
- natural scienceschemical sciencesorganic chemistryhydrocarbons
- engineering and technologynanotechnologynano-materialsnanocrystals
- engineering and technologyenvironmental engineeringenergy and fuels
Programma(i)
Argomento(i)
Meccanismo di finanziamento
MSCA-IF-EF-ST - Standard EFCoordinatore
1015 Lausanne
Svizzera