Unravelling the secrets of Cu-based catalysts for C-H activation

Información del proyecto

CUBE

Identificador del acuerdo de subvención: 856446

DOI

10.3030/856446

Fecha de la firma de la CE 15 Noviembre 2019

Fecha de inicio 1 Mayo 2020

Fecha de finalización 31 Octubre 2026

Financiado con arreglo a

• EXCELLENT SCIENCE - European Research Council (ERC)

Coste total

€ 9 885 989,13

Aportación de la UE

€ 9 885 988,00

Coordinado por

UNIVERSITETET I OSLO
Norway

CORDIS proporciona enlaces a los documentos públicos y las publicaciones de los proyectos de los programas marco HORIZONTE.

Los enlaces a los documentos y las publicaciones de los proyectos del Séptimo Programa Marco, así como los enlaces a algunos tipos de resultados específicos, como conjuntos de datos y «software», se obtienen dinámicamente de OpenAIRE .

Publicaciones

Peer reviewed articles (32)

X-ray absorption and emission spectroscopy of N₂S₂ Cu(<scp>ii</scp>)/(<scp>iii</scp>) complexes

Autores: Blaise L. Geoghegan; Jessica K. Bilyj; Paul V. Bernhardt; Serena DeBeer; George E. Cutsail
Publicado en: Dalton Transactions, Edición 53, 2024, Página(s) 7828–7838, ISSN 1477-9226
Editor: Royal Society of Chemistry
DOI: 10.1039/d4dt00085d

Structural Elucidation, Aggregation, and Dynamic Behaviour of N,N,N,N-Copper(I) Schiff Base Complexes in Solid and in Solution: A Combined NMR, X-ray Spectroscopic and Crystallographic Investigation

Autores: Isabelle Gerz, Dr. Sergio Augusto Venturinelli Jannuzzi, Dr. Knut T. Hylland, Dr. Chiara Negri, Dr. David S. Wragg, Dr. Sigurd Øien-Ødegaard, Prof. Mats Tilset, Prof. Unni Olsbye, Prof. Serena DeBeer, Prof. Mohamed Amedjkouh
Publicado en: European Journal of Inorganic Chemistry, Edición 46, 2021, Página(s) 4762-4775, ISSN 1099-0682
Editor: Wiley-VCH GmbH
DOI: 10.1002/ejic.202100722

Expanding the catalytic landscape of metalloenzymes with lytic polysaccharide monooxygenases

Autores: Munzone A, Eijsink VGH, Berrin JG, Bissaro B
Publicado en: Nature Reviews Chemistry, Edición Volume 8, February 2024, 2024, Página(s) 106-119, ISSN 2397-3358
Editor: Nature Springer
DOI: 10.1038/s41570-023-00565-z

Modulation of [CuOH/O]⁺ Properties in [2,2′-Bipyridine]₂ Homoleptic Complexes through Substitution at the 6,6’ Position by Methyl Groups

Autores: Alessandro Damin; Matteo Bonomo; Barbara Centrella; Matteo Signorile; Claudia Barolo; Silvia Bordiga
Publicado en: ACS Omega, Edición Volume 9, Edición 14, 2024, Página(s) 16610−16620, ISSN 2470-1343
Editor: American Chemical Society
DOI: 10.1021/acsomega.4c00598

Exploring Ce(IV)-MOFs redox behavior for catalysis by spectroscopies

Autores: Valeria Finelli, Sergio Rojas-Buzo, Matteo Signorile, Francesca Bonino, Silvia Bordiga
Publicado en: Nano Materials Science, 2024, ISSN 2589-9651
Editor: Elsevier B.V.
DOI: 10.1016/j.nanoms.2024.11.001

Synthesis of a mixed-linker Ce-UiO-67 metal–organic framework

Autores: V. Finelli, G. Mastronardi, N. G. Porcaro, M. Signorile, F. Bonino, P. Á. Szilágyi, S. Bordiga
Publicado en: RSC Applied Interfaces, 2024, ISSN 2755-3701
Editor: Royal Society of Chemistry
DOI: 10.1039/d4lf00278d

Ancestral sequence reconstruction as a tool to study the evolution of wood decaying fungi

Autores: Iván Ayuso-Fernández; Gonzalo Molpeceres; Susana Camarero; Francisco Javier Ruiz-Dueñas; Angel T. Martínez
Publicado en: Frontiers in Fungal Biology, Edición Volume 3, article 1003489, 2022, ISSN 2673-6128
Editor: Frontiers Media S.A.
DOI: 10.3389/ffunb.2022.1003489

Electrochemical Monitoring of Heterogeneous Peroxygenase Reactions Unravels LPMO Kinetics

Autores: Lorenz Schwaiger; Florian Csarman; Hucheng Chang; Ole Golten; Vincent G. H. Eijsink; Roland Ludwig
Publicado en: ACS Catalysis, Edición Volume14, January 2024, 2024, Página(s) 1205−1219, ISSN 2155-5435
Editor: American Chemical Society
DOI: 10.1021/acscatal.3c05194

Mutational dissection of a hole hopping route in a lytic polysaccharide monooxygenase (LPMO)

Autores: Ivan Ayuso-Fernández, Tom Z. Emrich-Mills, Julia Haak, Ole Golten, Kelsi R. Hall, Lorentz Schwaiger, Trond S. Moe, Anton A. Stepnov, Roland Ludwig, Georg E. Cutsail III, Morten Sørlie, Åsmund Kjendseth Røhr, Vincent G. H. Eijsink
Publicado en: Nature Communications, Edición Volume 15, Article 3975, May 2024, 2024, ISSN 2041-1723
Editor: Nature Publishing Group
DOI: 10.1038/s41467-024-48245-w

Copper(II)-Oxyl Formation in a Biomimetic Complex Activated by Hydrogen Peroxide: The Key Role of Trans-Bis(Hydroxo) Species

Autores: Ning Cao, Abril C. Castro, David Balcells, Unni Olsbye, Ainara Nova
Publicado en: Inorganic Chemistry, Edición 63, 2024, Página(s) 23082-23094, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01948

Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes

Autores: Blaise L. Geoghegan; Yang Liu; Sergey Peredkov; Sebastian Dechert; Franc Meyer; Serena DeBeer; George E. Cutsail
Publicado en: Journal of the American Chemical Society, Edición Volume 144, issue 6, January 2022, 2022, Página(s) 2520–2534, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.1c09505

Copper Pairing in the Mordenite Framework as a Function of the CuI/CuII Speciation

Autores: Gabriele Deplano, Dr. Andrea Martini, Dr. Matteo Signorile, Dr. Elisa Borfecchia, Dr. Valentina Crocellà, Prof. Stian Svelle, Prof. Silvia Bordiga
Publicado en: Angewandte Chemie, Edición 49, 2021, Página(s) 25891-25896, ISSN 1521-3757
Editor: Wiley-VCH GmbH
DOI: 10.1002/anie.202109705

Partial oxidation of cyclohexene over histidine-modified Cu-UiO-66 under aerobic conditions

Autores: Erlend Aunan, Valeria Finelli, Sebastian Prodinger, Ning Cao, Beatrice Garetto, Gabriele Deplano, Peter Ng’ang’a Njoroge, Matteo Signorile, Elisa Borfecchia, Karl Petter Lillerud, Ainara Nova, Silvia Bordiga, Unni Olsbye
Publicado en: Journal of Catalysis, Edición 438, 2024, Página(s) 115722, ISSN 0021-9517
Editor: Academic Press
DOI: 10.1016/j.jcat.2024.115722

Impact of the copper second coordination sphere on catalytic performance and substrate specificity of a bacterial LPMO

Autores: Kelsi R. Hall, Maja Mollatt, Zarah Forsberg, Ole Golten, Lorenz Schwaiger, Roland Ludwig, Iván Ayuso-Fernández, Vincent G.H. Eijsink, Morten Sørlie
Publicado en: ACS Omega, Edición Volume 9, May 2024, 2024, Página(s) 23040-23052, ISSN 2470-1343
Editor: American Chemical Society
DOI: 10.1021/acsomega.4c02666

Titration of Cu(I) Sites in Cu-ZSM-5 by Volumetric CO Adsorption

Autores: Gabriele Deplano, Matteo Signorile, Valentina Crocellà, Natale Gabriele Porcaro, Cesare Atzori, Bjørn Gading Solemsli, Stian Svelle, and Silvia Bordiga*
Publicado en: ACS Applied Materials & Interfaces, Edición Volume 14, Edición 18, April 2022, 2022, Página(s) 21059–21068, ISSN 1944-8244
Editor: American Chemical Society
DOI: 10.1021/acsami.2c03370

Cation-induced speciation of port-size during mordenite zeolite synthesis

Autores: Sebastian Prodinger; Izar Capel Berdiell; Tomas Cordero-Lanzac; Odd Reidar Bygdnes; Bjørn Gading Solemsli; Karoline Kvande; Bjørnar Arstad; Pablo Beato; Unni Olsbye; Stian Svelle
Publicado en: Journal of Materials Chemistry A, Edición Volume 11, 2023, Página(s) 21884–21894, ISSN 2050-7488
Editor: Royal Society of Chemistry
DOI: 10.1039/d3ta03444e

Reducibility of Cu-zeolites and stability of Cu+ monocarbonyl adducts: Qualitative and quantitative relationships from MCR-XAS and DFT

Autores: Gabriele Deplano; Matteo Signorile; Cesare Atzori; Davide Salusso; Elisa Borfecchia; Valentina Crocellà; Silvia Bordiga
Publicado en: Catalysis Today, Edición Volume 427, 114403,, 2023, ISSN 0920-5861
Editor: Elsevier BV
DOI: 10.1016/j.cattod.2023.114403

A Conserved Second Sphere Residue Tunes Copper Site Reactivity in Lytic Polysaccharide Monooxygenases

Autores: Kelsi R. Hall; Chris Joseph; Iván Ayuso-Fernández; Ashish Tamhankar; Lukas Rieder; Rannei Skaali; Ole Golten; Frank Neese; Åsmund K. Røhr; Sergio A. V. Jannuzzi; Serena DeBeer; Vincent G. H. Eijsink; Morten Sørlie
Publicado en: Journal of the American Chemical Society, Edición Volume 145, pages 18888-18903, August 2023, 2023, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.3c05342

Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts.

Autores: Chiara Negri; Andrea Martini; Gabriele Deplano; Kirill A. Lomachenko; Ton V. W. Janssens; Elisa Borfecchia; Gloria Berlier; Silvia Bordiga
Publicado en: Physical Chemistry Chemical Physics, Edición 23, 2021, Página(s) 18322-18337, ISSN 1463-9084
Editor: The Royal Society of Chemistry
DOI: 10.1039/d1cp01754c

Integrated Experimental and Theoretical Investigation of Copper Active Site Properties of a Lytic Polysaccharide Monooxygenase from Serratia marcescens

Autores: Alessia Munzone, Manon Pujol, Ashish Tamhankar, Chris Joseph, Ievgen Mazurenko, Marius Réglier, Sergio A. V. Jannuzzi, Antoine Royant, Giuseppe Sicoli, Serena DeBeer, Maylis Orio, A. Jalila Simaan, and Christophe Decroos
Publicado en: Inorganic Chemistry, Edición Volume 63, Edición 24, 2024, Página(s) 11063-11078, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c00602

Lytic polysaccharide monooxygenases: enzymes for controlled and site-specific Fenton-like chemistry

Autores: B. Bissaro & V.G.H. Eijsink
Publicado en: Essays in Biochemistry, Edición Mar 18;Volume 67, issue 3, March 2023, 2023, Página(s) 575-584, ISSN 0071-1365
Editor: Portland Press, Ltd.
DOI: 10.1042/ebc20220250

Reductants fuel lytic polysaccharide monooxygenase activity in a pH-dependent manner

Autores: Ole Golten, Iván Ayuso-Fernández, Kelsi R. Hall, Anton A. Stepnov, Morten Sørlie, Åsmund Kjendseth Røhr, Vincent G. H. Eijsink
Publicado en: FEBS Letters, Edición Volume 597, Edición 10, 2023, Página(s) 1363-1374, ISSN 0014-5793
Editor: Elsevier BV
DOI: 10.1002/1873-3468.14629

Understanding C–H activation in light alkanes over Cu-MOR zeolites by coupling advanced spectroscopy and temperature-programmed reduction experiments

Autores: Karoline Kvande; Beatrice Garetto; Gabriele Deplano; Matteo Signorile; Bjørn Gading Solemsli; Sebastian Prodinger; Unni Olsbye; Pablo Beato; Silvia Bordiga; Stian Svelle; Elisa Borfecchia
Publicado en: Chemical Science, Edición August 2023, volume 14, 2023, Página(s) 9704–9723, ISSN 2041-6520
Editor: Royal Society of Chemistry
DOI: 10.1039/d3sc01677c

A multi-technique approach to unveil the redox behaviour and potentiality of homoleptic CuI complexes based on substituted bipyridine ligands in oxygenation reactions

Autores: Barbara Centrella; Gabriele Deplano; Alessandro Damin; Matteo Signorile; Mariagrazia Tortora; Claudia Barolo; Matteo Bonomo; Silvia Bordiga
Publicado en: Dalton Transactions, Edición Edición 51, July 2022, 2022, Página(s) 14439-14451, ISSN 1477-9234
Editor: The Royal Society of Chemistry
DOI: 10.1039/d2dt01234k

"The ""life-span"" of lytic polysaccharide monooxygenases (LPMOs) correlates to the number of turnovers in the reductant peroxidase reaction"

Autores: Kuusk S, Eijsink VGH, Väljamäe P.
Publicado en: Journal of Biological Chemistry, Edición Volume 299, Edición 9, Article 105094, Sep 2023, 2023, ISSN 1083-351X
Editor: Elsevier BV
DOI: 10.1016/j.jbc.2023.105094

Reactivity of methoxy species towards methylation and oligomerization in Cu-zeolite systems

Autores: Bjørn Gading Solemsli, Izar Capel Berdiell, Sebastian Prodinger, Karoline Kvande, Gabriele Deplano, Unni Olsbye, Pablo Beato, Silvia Bordiga, Stian Svelle
Publicado en: Catalysis Today, Edición Volume 436, Article 114729, 2024, ISSN 0920-5861
Editor: Elsevier BV
DOI: 10.1016/j.cattod.2024.114729

Towards a unified understanding of the copper sites in particulate methane monooxygenase: an X-ray absorption spectroscopic investigation

Autores: George E. Cutsail; Matthew O. Ross; Amy C. Rosenzweig; Serena DeBeer
Publicado en: Chemical Science, Edición 12, 2021, Página(s) 6194-6209, ISSN 2041-6539
Editor: The Royal Society of Chemistry
DOI: 10.1039/d1sc00676b

Assessing the Influence of Zeolite Composition on Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-CHA DeNO_<i>x</i> Catalysts by Machine Learning-Assisted X-ray Absorption Spectroscopy

Autores: Andrea Martini; Chiara Negri; Luca Bugarin; Gabriele Deplano; Reza K. Abasabadi; Kirill A. Lomachenko; Ton V. W. Janssens; Silvia Bordiga; Gloria Berlier; Elisa Borfecchia
Publicado en: The Journal of Physical Chemistry Letters, Edición Volume 13, Edición 26, July 2022, 2022, Página(s) 6164-6170, ISSN 1948-7185
Editor: American Chemical Society
DOI: 10.1021/acs.jpclett.2c01107

Enabling a bioinspired <i>N</i>,<i>N</i>,<i>N</i>-copper coordination motif through spatial control in UiO-67: synthesis and reactivity

Autores: Isabelle Gerz; Erlend S. Aunan; Valeria Finelli; Mouhammad Abu Rasheed; Gabriele Deplano; Rafael Cortez S. P.; Inga L. Schmidtke; David S. Wragg; Matteo Signorile; Knut T. Hylland; Elisa Borfecchia; Karl Petter Lillerud; Silvia Bordiga; Unni Olsbye; Mohamed Amedjkouh
Publicado en: Dalton Transactions, Edición Volume 53, 2024, Página(s) 8141-8153, ISSN 1477-9226
Editor: Royal Society of Chemistry
DOI: 10.1039/d3dt03096b

Visible light-exposed lignin facilitates cellulose solubilization by lytic polysaccharide monooxygenases

Autores: Eirik G. Kommedal; Camilla F. Angeltveit; Leesa J. Klau; Iván Ayuso-Fernández; Bjørnar Arstad; Simen G. Antonsen; Yngve Stenstrøm; Dag Ekeberg; Francisco Gírio; Florbela Carvalheiro; Svein J. Horn; Finn Lillelund Aachmann; Vincent G. H. Eijsink
Publicado en: Nature Communications, Edición Volume 14, article 1063, 2023, 2023, Página(s) 1-12, ISSN 2041-1723
Editor: Nature Publishing Group
DOI: 10.1038/s41467-023-36660-4

<i>In situ</i> H₂O₂ Generation by Choline Oxidase and Its Application in Amino Polysaccharide Degradation by Coupling to Lytic Polysaccharide Monooxygenase

Autores: Nam‐Hai Hoang; Ole Golten; Zarah Forsberg; Vincent G. H. Eijsink; Michael Richter
Publicado en: ChemBioChem, Edición Volume 16, article e202300363, May 2023, 2023, ISSN 1439-4227
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/cbic.202300363

Influence of ion mobility on the redox and catalytic properties of Cu ions in zeolites

Autores: Signorile, Matteo; Borfecchia, Elisa; Bordiga, Silvia; Berlier, Gloria
Publicado en: Chemical Science, Edición Edición 35, August 2022, 2022, Página(s) 10238-10250, ISSN 2041-6520
Editor: Royal Society of Chemistry
DOI: 10.1039/d2sc03565k

Thesis and dissertations (15)

Coupling of the organic linkers and their simultaneous integration in a missing linker UiO-66 

Autores: Laura Sypalyte
Publicado en: 2024
Editor: University of Oslo

Cu-based catalysts for C-H bond activation

Autores: Gabriele Deplano
Publicado en: 2023
Editor: University of Turin

Synthesis and Characterization of Metal Organic Frameworks Containing Bio inspired Cu-centers

Autores: Erlend Solbakken Aunan
Publicado en: 2024
Editor: University of Oslo

Mimicking the active site of Lytic Polysaccharides Monooxygenases (LPMO) enzymes for catalysisSynthesis and Characterization

Autores: Atiqa Ambrin Ansar
Publicado en: 2023
Editor: University of Oslo

Exploring the potential role of lytic polysaccharide monooxygenases from Bacillus licheniformis and Bacillus spizizenii in endospore germination

Autores: Ingeborg Langeby Korsane
Publicado en: 2024
Editor: NMBU

Synthesis of bioinspired bidentate N-ligands and their incorporation into UiO-67

Autores: Ingeborg Tangevold
Publicado en: 2024
Editor: University of Oslo

Investigating the role of aromatic core residues in protecting against oxidative damage in lytic polysaccharide monooxygenase SmAA10A

Autores: Moe, Trond
Publicado en: 2022
Editor: NMBU

The Impact of a Structurally Conserved Second Sphere Residue in Lytic Polysaccharide Monooxygenase Catalysis

Autores: Skaali, Rannei
Publicado en: 2022
Editor: NMBU

Bioinspired Copper Complexes for Incorporation into UiO-67

Autores: Isabelle Gerz
Publicado en: Edición Volume 2022, Edición 2536, 2022
Editor: University of Oslo

Synthesis and structural characterization of heteroleptic dipyridophenazine–based [Cu(N^N)(P^P)]+ complexes

Autores: Melchizedek Amoakwah
Publicado en: 2023
Editor: University of Oslo

Characterization of Zr-MOF containing anchored Cu species for C-H bond activation

Autores: Giuseppe Mastronardi
Publicado en: 2023
Editor: University of Turin

The roles of conserved second sphere residues in lytic polysaccharide monooxygenase catalysis

Autores: Mollatt, Maja
Publicado en: 2022
Editor: NMBU

Investigating the role of aromatic core residues in protecting against oxidative damage in lytic polysaccharide monooxygenase SmAA10A

Autores: Moe, Trond
Publicado en: 2023
Editor: NMBU

Synthesis and characterization of Ce/Zr mixed cluster Metal-Organic Frameworks UiO-67 as catalysts for the partial oxidation of cyclohexene

Autores: Federico Panagini
Publicado en: 2024
Editor: University of Turin

A multi-technique approach aimed at developing new Cu-based catalysts for C-H activations: from design, synthesis and characterization to evaluation of their performance

Autores: Barbara Centrella
Publicado en: 2024
Editor: University of Turin